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CSC 기반 저탄소 콘크리트 2차제품 제조를 위한 OPC 페이스트의 촉진탄산화 특성에 관한 실험적 연구

Experimental Study on Accelerated Carbonation Characteristics of OPC Paste for CSC-Based Low Carbon Precast Concrete Products

  • 윤준태 ;
  • 김영진 ;
  • 심상락 ;
  • 류동우
  • Yoon, Jun-Tae (Kyung Sung Concrete Industries) ;
  • Kim, Young-Jin (Department of Architectural Engineering, Daejin University) ;
  • Sim, Sang-Rak (Department of Architectural Engineering, Daejin University) ;
  • Ryu, Dong-Woo (Department of Architectural Engineering, Daejin University)
  • 투고 : 2024.02.07
  • 심사 : 2024.05.13
  • 발행 : 2024.06.20

초록

본 연구에서는 500℃·hr의 증기양생을 실시한 OPC 페이스트에 대하여 1atm 20% 농도의 CO2와 5atm 99% 농도의 고농도 CO2 조건 하의 촉진 탄산화의 영향평가를 수행하였다. 이를 위하여 XRD, FT-IR을 통한 화학적 분석과 SEM, 압축강도 측정을 통한 물리적 특성 분석을 실시하였다. 그 결과 CO2 20% 농도의 상압 탄산화를 수행하는 경우 뚜렷한 내부 조직구조 치밀화 및 압축강도 증진 효과를 관찰할 수 있었고, CO2 99% 농도의 5atm 가압 탄산화를 실시할 경우 표면조직구조가 빠르게 치밀해지며 CO2 확산침투율이 크게 떨어지게 되어 압축강도 등 유의미한 수준의 물리적 특성 개선이 일어날 정도의 탄산화를 진행할 수 없었다.

This study investigated the impact of accelerated carbonation on Ordinary Portland Cement(OPC) paste that had undergone steam curing at 500℃·hr. Two carbonation environments were examined: atmospheric carbonation(1atm, 20% CO2) and pressurized carbonation(5atm, 99% CO2). Chemical analysis using X-ray diffraction(XRD) and Fourier-Transform Infrared spectroscopy(FT-IR) were conducted, along with physical characterization via scanning electron microscopy(SEM) and compressive strength testing. Results indicated that atmospheric carbonation with 20% CO2 concentration significantly densified the internal microstructure of the OPC paste, leading to enhanced compressive strength. Conversely, pressurized carbonation at 5atm with 99% CO2 concentration resulted in rapid densification of the surface structure, which hindered CO2 diffusion into the sample. This limited the extent of carbonation and prevented the improvement of physical properties.

키워드

과제정보

This experiment research had been conducted under the financial support provided by the R&D program(Development of calcium silicate cement and cement products, RS-2023-00155521) of KEIT.

참고문헌

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