DOI QR코드

DOI QR Code

Fire and Explosion Hazards and Safety Management Measures of Waste Plastic-to-Pyrolysis Oil Conversion Process

폐플라스틱 열분해 유화 공정의 화재·폭발 위험성 및 안전관리 방안

  • Dong-Hyun Seo (Occupational Safety Research Bureau, OSHRI, KOSHA) ;
  • Yi-Rac Choi (Occupational Safety Research Bureau, OSHRI, KOSHA) ;
  • Jin-Ho Lim (Busan Metropolitan Office, KOSHA) ;
  • Ou-Sup Han (Occupational Safety Research Bureau, OSHRI, KOSHA)
  • Received : 2023.07.05
  • Accepted : 2023.09.18
  • Published : 2023.09.25

Abstract

The number of fire and explosion accidents caused by pyrolysis oil and gas at waste plastic pyrolysis plants is increasing, but accident status and safety conditions have not been clearly identified. Therefore, the aim of the study was to identify the risks of the waste plastic pyrolysis process and suggest appropriate safety management measures. We collected information on 19 cases of fire and explosion accidents that occurred between 2010 and 2021 at 26 waste plastic pyrolysis plants using the Korea Occupational Safety and Health Agency (KOSHA) database and media reports. The mechanical, managerial, personnel-related, and environmental problems within a plant and problems related to government agencies and the design, manufacturing, and installation companies involved with pyrolysis equipment were analyzed using the 4Ms of Machines, Management, Man, and Media, as well as the System-Theoretic Accident Model and Processes (STAMP) methodology for seven accident cases with accident investigation reports. Study findings indicate the need for establishing legal and institutional support measures for waste plastic pyrolysis plants in order to prevent fire and explosion accidents in the pyrolysis process. In addition, ensuring safety from the design and manufacturing stages of facilities is essential, as are measures that ensure systematic operations after the installation of safety devices.

Keywords

References

  1. Czajczynska, D., Anguilano, L., Ghazal, H., Krzyzynska, R., Reynolds, A.J., Spencer, N., and Jouhara, H., 2017, "Potentials of pyrolysis processes in the waste management sector", Therm. Sci. Eng. Prog., 3, 171-197. https://doi.org/10.1016/j.tsep.2017.06.003
  2. Miandad, R., Barakat, M.A., Aburiazaiza, Asad S., Rehan, M., and Nizami, A.S., 2016, "Catalytic pyrolysis of plastic waste: A review", Process Saf. Environ., 102, 822-838. https://doi.org/10.1016/j.psep.2016.06.022
  3. BASF, 2023, "Life cycle assessment (LCA) for chemcycling", https://www.basf.com/kr/en/who-we-are/ sustainability/we-drive-sustainable-solutions/circular-economy/mass-balance-approach/chemcycling/lca-for-chemcycling.html.
  4. Quantis, 2020, "Chemical recycling: Greenhouse gas emission reduction potential of an emerging waste management route", Cefic, https://cefic.org/app/uploads/2020/12/CEFIC_Quantis_report_final.pdf.
  5. Ministry of Environment (MOE), 2021, "Waste plastic pyrolysis reactor circular economy, carbon neutrality leading", 2021.06.21., http://me.go.kr/home/web/board/read.do?boardMasterId=1&boardId=1460570&menuId=286.
  6. Ministry of Environment (MOE), 2020, "Establishment of plastic lifecycle reduction and recycling measures", 2020.12.24., https://me.go.kr/home/web/board/read.do?boardMasterId=1&boardId=1420640&menuId=286.
  7. Korea Occupational Safety and Health Agency (KOSHA), 2007, "4M risk assessment procedure and method", 2020. 12.24., https://www.kosha.or.kr/kosha/data/shipbuildingb_a.do?mode=download&articleNo=80035&attachNo=60174.
  8. Leveson, N.G., 2019, "Cast Handbook: How to learn more from incidents and accidents", 6-35, http://sunnyday.mit.edu/CAST-Handbook.pdf.
  9. Small and Medium Business Administration (SMBA), 2013, "Waste to energy industry road map", Accessed 3 February 2023, http://bizhospital.co.kr/04_info/knowhow_view.php?no=202&start=0&key=%BF%A1%B3%CA%C1%F6&keyfield=subject.
  10. Nho, N.S., and Lee, K.W., 2021, "Domestic trends in the field of thermochemical recycling of waste plastics", Bulletin of the KSNRE, 1(2), 6-12, https://www.ksnre.or.kr/upload/newsletter/2021-2/#page=8.
  11. Korea Industrial Education Institute (KIEI), 2023, "Seminar on Waste plastic chemical recycling trends and R&D cases and commercialization of 2023".
  12. Cho, J.H., Shin, D.W., and Kim, Y.H., 2022, "Waste plastic pyrolysis promotion conditions and policy tasks", Korea Environment Institute, https://library.kei.re.kr/search/i-discovery/741916?index=5.
  13. Korea Occupational Safety and Health Agency (KOSHA), 2021, "Chemical accident case study, Waste pyrolysis oil production process fire accident", Major Accident Prevention Bureau, 314, https://www.kosha.or.kr/kosha/data/screening_e.do?mode=download&articleNo=423373&attachNo=239227.
  14. Ministry of Employment and Labor (MOEL), 2022, "Analysis of occupational accident status in 2021", https://www.moel.go.kr/policy/policydata/view.do?bb s_seq=20221201394.
  15. Gebre, S.H., Sendeku, M.G., and Bahri, M., 2021, "Recent trends in the pyrolysis of non-degradable waste plastics", ChemistryOpen, 10(12), 1202-1226. https://doi.org/10.1002/open.202100184
  16. Han, O.S., Lee, J.S., Seo, D.H., Oh, S.H., and Park, H.J., 2019, "Fire and explosion risk assessment of sub-bituminous coal dust for thermal power generation", OSHRI KOSHA, https://oshri.kosha.or.kr/oshri/professional-Business/dangerEvaluationReport.do?mode=download&articleNo=422470&attachNo=238774.
  17. Korea Occupational Safety and Health Agency (KOSHA), 2022, "Technical Guidelines for Determining Explosiveness of Mixed Gases and Calculating Lower Explosive Limits", KOSHA Guide P-179-2022, https://kosha.or.kr/extappKosha/kosha/guidance/fileDownload.do?sfhlhTchnlgyManualNo=P-179-2022&fileOrdrNo=2.
  18. KOSHA MSDS, Accessed 5 June 2022, https://msds.kosha.or.kr.
  19. Eze, W.U., Umunakwe, R., Obasi, H.C., Ugbaja, M.I., Uche, C.C., and Madufor, I.C., 2021, "Plastics waste management: A review of pyrolysis technology", Clean Technologies and Recycling, 1(1), 50-69. https://doi.org/10.3934/ctr.2021003
  20. Shin, D.H., Nho, N.S., Kim, S.S., Kim, K.H., and Jeon, S.G., 2010, "A review on R&D and commercialization of oil recovery from waste plastics by pyrolysis", J. of Korean Inst. of Resour. Recycl., 19(1), 3-12.
  21. Arabiourrutia, M., Elordi, G., Lopez, G., Borsella, E., Bilbao, J., and Olazar, M., 2012, "Characterization of the waxes obtained by the pyrolysis of polyolefin plastics in a conical spouted bed reactor", JAAP, 94, 230-237. https://doi.org/10.1016/j.jaap.2011.12.012
  22. Choi, S.K., Choi, Y.S., Jeong, Y.W., Han, S.Y., and Nguyen, Q.V., 2022, "Analysis on the pyrolysis characteristics of waste plastics using plug flow reactor model", New. Renew. Energy, 18(4), 12-21. https://doi.org/10.7849/ksnre.2022.0037
  23. University of Seoul (UOS), 2010, "An impact separator for removing wax produced in the pyrolysis process", KR Patent No. 10-0994244, November 8, 2010.
  24. Eco Creation, "Pyrolysis oil wax", Accessed 6 June 2022, http://ecocreation-in.com/technic-article-2/?pageid=&mod=document&uid=37.
  25. Korea University News Paper (KUNEWS), "Catch valuable trash in the era of high oil prices. Pyrolysis oil technology, extracting fuel oil from waste, is very useful", 2007. 05.13., http://www.kunews.ac.kr/news/articleView.html?idxno=9878.
  26. Shin, D.H., Kim, D.C., Nho, N.S., Lee, K.W., Woo, J.K., Kim, K.H., and Jeon, S.G., 2006, "A process development of continuous liquefaction of polymer wastes", KIER, http://img.kisti.re.kr/originalView/originalView.jsp?url=/tr_img/2010202/trko200800003102.pdf.
  27. Korea Occupational Safety and Health Agency (KOSHA), 2012, "Technical guidelines for safety management of operation and work of chemical processes and facilities", KOSHA Guide P-69-2012, https://www.kosha.or.kr/extappKosha/kosha/guidance/fileDownload.do?sfhlhTchnlgyManualNo=P-69-2012&fileOrdrNo=3.