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Investigation of the Electrochemical Characteristics of Electropolished Super Austenite Stainless Steel with Seawater Temperature

전해연마한 슈퍼오스테나이트 스테인리스강의 해수온도에 따른 전기화학적 특성 연구

  • Hyun-Kyu Hwang (Graduate school, Mokpo national maritime university) ;
  • Seong-Jong Kim (Division of marine engineering, Mokpo national maritime university)
  • 황현규 (목포해양대학교 대학원) ;
  • 김성종 (목포해양대학교 기관시스템공학부)
  • Received : 2023.01.04
  • Accepted : 2023.01.13
  • Published : 2023.06.30

Abstract

Electropolishing technology uses an electrochemical reaction and improves surface roughness, glossiness, and corrosion resistance. In this investigation, electropolishing was performed to improve the corrosion resistance of super austenitic stainless steel. As a result of electropolishing, surface roughness (0.16 ㎛) was improved by about 76.5% compared to mechanical polishing (0.68 ㎛). In addition, the electropolished surface was smooth because the average and variance values of the depth histogram were small. Tafel analysis was performed after a potentiodynamic polarization experiment with seawater temperature, and the microstructure was compared and analyzed. The corrosion current density at 30 ℃, 60 ℃, and 90 ℃ was reduced by 0.083 ㎂/cm2, 0.296 ㎂/cm2, and 0.341 ㎂/cm2, respectively. Pitting occurred in the mechanical polished specimen at 30 ℃, but partial intergranular corrosion was observed in the electropolished specimen, and pitting occurred predominantly at both 60 ℃ and 90 ℃. In addition, the damage depths of the electropolished specimen were shallower than those of mechanical polishing at 30 ℃ and 60 ℃, but the opposite result was seen at 90 ℃.

Keywords

References

  1. N. Rajendran, S. Rajeswari, Evaluation of mercaptoazoles as corrosion inhibitors in simulated Sulphur dioxide scrubber environments, Anti-Corrosion Methods and Materials, 42, 13 (1995). Doi: http://dx.doi.org/10.1108/eb007360
  2. B. S. Phull, W. L. Mathay and R. W. Ross, Corrosion Resistance of Duplex and 4-6% Mo-Containing Stainless Steels in FGD Scrubber Absorber Slurry Environments, NACE CORROSION, 578 (2000).
  3. M. S. Kim and J. A. Jeong, Corrosion Behavior of Carbon Steel in Diluted Sulfuric Acid based on Seawater, Corrosion Science and Technology, 18, 78 (2019). Doi: https://doi.org/10.14773/CST.2019.18.3.78
  4. S. D. Lee, J. M. Lee, C. Y. Kang, J. H. Kim and D. H. Lee, Proc. '04 Journal of Power System Engineering Conf., pp. 172 - 179, Journal of Power System Engineering (2004). http://www.dbpia.co.kr/journal/articleDetail?nodeId=NODE01026180
  5. M. Qian, J. N. DuPont, Microsegregation-related pitting corrosion characteristics of AL-6XN superaustenitic stainless steel laser welds, Corrosion Science, 52, 3548-3553 (2010). Doi: https://doi.org/10.1016/j.corsci.2010.07.007
  6. J. L. Cardoso, A. L. S. N. Cavalcante, R. C. A. Vieira, and P. D. Lima-Neto, M. J. G. D. Silva, Pitting corrosion resistance of austenitic and superaustenitic stainless steels in aqueous medium of NaCl and H2SO4, Journal of Materials Research, 31, 1755 (2016). Doi: https://doi.org/10.1557/jmr.2016.198
  7. K. H. Jung, S. J. Kim, Experiment Investigation for Design on the Sensitization-Dependent Passivation Characteristics of AL-6XN in 3.5% NaCl Solution, Journal of Nanoscience and Nanotechnology, 21, 3984 (2021). Doi: https://doi.org/10.1166/jnn.2021.19219
  8. S. H. Kim, S. G Lee, S. G. Choi, E. S. Lee, S. B Choi and C. H. Lee, A Study on the Characteristics of Micro Electropolishing for Stainless Steel, The International Journal of Advanced Manufacturing Technology, 85, 2313 (2016). Doi: https://doi.org/10.1007/s00170-015-8041-y
  9. E. S. Lee, Machining Characteristics of the Electropolishing of Stainless Steel (STS316L), The International Journal of Advanced Manufacturing Technology, 16, 591 (2000). Doi: https://doi.org/10.1007/s001700070049
  10. S. J. Lee and J. J. Lai, The effects of electropolishing (EP) process parameters on corrosion resistance of 316L stainless steel, Journal of Materials Processing Technology, 140, 206 (2003). Doi: https://doi.org/10.1016/S0924-0136(03)00785-4
  11. H. K. Hwang, S. J. Kim, Optimization of electropolishing process using taguchi robust design for UNS N08367 in mixed solution of sulfuric acid and phosphoric acid, Coatings, 13, 312 (2023). Doi: https://doi.org/10.3390/coatings13020312
  12. S. M. Lee, B. M. Kwon, and K. Park, Flow characteristics according to internal structure of square wet scrubber, Journal of the Korean Society of Marine Engineering, 43, 1 (2019). Doi: https://doi.org/10.5916/jkosme.2019.43.1.1
  13. Chi-Cheng Lin, Chi-Chang Hu, Electropolishing of 304 stainless steel: Surface roughness control using experimental design strategies and a summarized electropolishing model, Electrochimica Acta, 53, 3356 (2008). Doi: https://doi.org/10.1016/j.electacta.2007.11.075
  14. B. Chatterjee, Science and Industry of Electropolishing, Jahrbuch Oberfl achentechnik, 71, 71 (2015). https://www.researchgate.net/publication/286359930_Science_and_Industry_of_Electropolishing
  15. M. Qian, J. N. DuPont, Microsegregation-related pitting corrosion characteristics of AL-6XN superaustenitic stainless steel laser welds, Corrosion Science, 52, 3548 (2010). Doi: https://doi.org/10.1016/j.corsci.2010.07.007
  16. E. L. Smith, A. P. Abbott and K. S Ryder, Deep Eutectic Solvents (DESs) and Their Applications, Chemical Reviews, 114, 11060 (2014). Doi: https://doi.org/10.1021/cr300162p
  17. M. A. Karim, J. H. Bae, D. H. Kam, C. Kim, and Y. D. Park, Critical Influence of Rivet Head Height on Corrosion Performance of CFRP/Aluminum Self-Piercing Riveted Joints, Corrosion Science and Technology, 18, 92 (2019). Doi: https://doi.org/10.14773/CST.2019.18.3.92
  18. G. T. Burstein and P. C. Pistorius, Surface Roughness and the Metastable Pitting of Stainless Steel in Chloride Solutions, CORROSION, 51, 380 (1995). Doi: https://doi.org/10.5006/1.3293603
  19. Sara Al Saadi, YongsunYi, PyungyeonCho, Changheui Jang and PhilipBeeley, Passivity breakdown of 316L stainless steel during potentiodynamic polarization in NaCl solution, Corrosion Science, 111, 720 (2016). Doi: https://doi.org/10.1016/j.corsci.2016.06.011
  20. Marcio Schwaab and Jose Carlos Pinto, Optimum reference temperature for reparameterization of the Arrhenius equation. Part 1: Problems involving one kinetic constant, Chemical Engineering Science, 62, 2750 (2007). Doi: https://doi.org/10.1016/j.ces.2007.02.020
  21. Guangdong Han, Zhanpeng Lu, Xiangkun Ru, Junjie Chen, Qian Xiao, Yongwu Tian, Improving the oxidation resistance of 316L stainless steel in simulated pressurized water reactor primary water by electropolishing treatment, Journal of Nuclear Materials, 467, 194 (2015). Doi: https://doi.org/10.1016/j.jnucmat.2015.09.029
  22. M. A. Kappes, Localized corrosion and stress corrosion cracking of stainless steels in halides other than chlorides solutions: a review, The Journal Corrosion Reviews, 38, 1 (2020). Doi: https://doi.org/10.1515/corrrev-2019-0061
  23. Y. Han, E. Han, Q. Peng, W. Ke, Effects of electropolishing on corrosion and stress corrosion cracking of Alloy 182 in high temperature water, Corrosion Science, 121, 1 (2017). Doi: https://doi.org/10.1016/j.corsci.2017.03.004
  24. J. P. James, F. Bocher, J. R. Scully, Effect of Braze Clearance on Localized Corrosion of a Superaustenitic Stainless Steel Brazed with a Ni-Based Alloy (Ni-22Cr-6.3Si3.8P), CORROSION, 62, 511 (2009). Doi: https://doi.org/10.5006/1.3319155
  25. G. Latha and Rajeswari, Pitting and crevice corrosion behaviour of superaustenitic stainless steels in sea water cooling systems, Journal Corrosion Review, 18, 1 (2000). Doi: https://doi.org/10.1515/CORRREV.2000.18.6.429
  26. I. Betova, M. Bojinov, T. Laitinen, K. Makela, P. Pohjanne, T. Saario, The transpassive dissolution mechanism of highly alloyed stainless steels: I. Experimental results and modelling procedure, Corrosion Science, 44, 2675 (2002). Doi: https://doi.org/10.1016/S0010-938X(02)00073-2
  27. R. T. Loto, Pitting corrosion evaluation of austenitic stainless steel type 304 in acid chloride media, Journal of Materials and Environmental Science, 4, 448 (2013). http://eprints.covenantuniversity.edu.ng/7366/