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쌀 세척 및 취반 방법에 따른 isoprothiolane의 감소 효과

Reduction effects of isoprothiolane during rice washing and cooking

  • Myungheon Kim (Department of Food Engineering, Daegu University) ;
  • Mihyun Cho (Department of Food Engineering, Daegu University) ;
  • So Eun An (Department of Food Engineering, Daegu University) ;
  • Moo-Hyeog Im (Department of Food Engineering, Daegu University)
  • 투고 : 2023.06.07
  • 심사 : 2023.06.16
  • 발행 : 2023.06.30

초록

본 연구는 쌀의 세척 및 취반 방법에 따른 isoprothiolane 잔류량을 GC-µECD를 이용하여 분석하였다. 세척 전 현미 잔류량은 17.03 mg/kg이었으며, 도정 후 백미는 1.67 mg/kg이었다. 세척 방법에서 물의 비율과 세척 횟수에 따라 현미와 백미의 isoprothiolane 잔류량은 19.3-59.3 및 43.1-66.5%이었으며, 세척물 온도가 5-40℃ 증가할수록 현미는 56.6-63.1%, 백미는 67.1-74.9% 감소하였다. 세척 방법을 손으로 살살 휘젓거나 비비는 방법으로(A, B 및 C)로 달리하였을 때 현미의 농약 감소율은 63.1-71.6%, 백미는 75.4-87.4%이었다. 현미를 압력밥솥과 전기밥솥을 이용하여 즉시 취반하였을 때 농약은 78.4 및 78.5%, 백미의 경우 94.0 및 94.0%로 감소하였으며, 30분간 불린 후 취반하였을 때 잔류농약은 현미에서 83.4%, 백미는 95.8% 감소하였다. 따라서 현미와 백미의 잔류농약 감소를 위한 가장 효과적인 세척 및 취반 방법은 40℃ 물, 7배 물로 6회 (2, 3회 차는 손으로 비벼서 세척) 세척 후 30분간 물에 불리기이다. 밥솥의 종류에 관계없이 취반할 경우 현미는 평균 83.4%, 백미는 95.8% isoprothiolane이 효과적으로 제거되는 것을 확인하였다.

This study used gas chromatography combined with the microelectron capture detection method to determine the most effective washing and cooking methods for removing isoprothiolane from rice. The initial isoprothiolane concentrations in brown and polished rice, before washing, were 17.03 mg/kg and 1.67 mg/kg, respectively. Residual concentrations declined with more washing cycles (19.3-59.3% for brown rice; 43.1-66.5% for polished rice); and by increasing the temperature of the washing water from 5℃ to 40℃ (56.6-63.1% for brown rice; 67.1-74.9% for polished rice). Hand-washing samples using gentle stirring or harsh rubbing reduced pesticide concentrations by 63.1-71.6% for brown rice, versus 75.4-87.4% for polished rice. Reduction in isoprothiolane concentrations varied based on the rice cooker type and whether the rice was pre-soaked. Immediate cooking using an electric- or pressure-cooker showed 78.5% and 78.4% reduction in brown rice, compared with 94.0% and 94.0% for polished rice, respectively. Pre-cooking immersion for 30 min showed similar reductions of 83.4% and 83.4% in brown rice, versus 95.8% and 95.8% in polished rice. The results of this study suggest that the most effective method for removing residual isoprothiolane from both brown rice and polished rice was to wash six times (with vigorous rubbing during the 2nd and 3rd washing) in 7-fold water at 40℃, followed by immersion for 30 min before cooking. Regardless of the type of rice cooker, heating is sufficient to remove an average of 83.4% and 95.8% of isoprothiolane from brown rice and polished rice, respectively.

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과제정보

이 논문은 2020학년도 대구대학교 연구년 결과물로 제출됨.

참고문헌

  1. Cho M, IM MH. Residual characteristics of buprofezin during rice processing. Korean J Food Preserv, 29, 428-439 (2022) https://doi.org/10.11002/kjfp.2022.29.3.428
  2. Cho SK. A study on accelerated solvent extraction method for analysis of pesticides in rice (Oryza sativa L.) using gas chromatography. MS Thesis, Chonnam National University, Korea, p 1-5 (2006)
  3. CODEX Alimentraius Commission. Guidelines on Good Laboratory Practice in Residue Analysis (CAC/GL 40-1993). Food and Agriculture Organization, World Health Organization, Rome, Italy, p 24 (2003)
  4. Hajslova J. Pesticides. In: Environmental Contaminants in Food, Moffat CF, Whittle KJ (Editors), Sheffield Academic Press Ltd., Sheffield, UK, p 215-272.
  5. Han SH, Jo HB. Effect of storage temperature, washing and cooking on postharvest-treated pesticide residues in polished rice. J Fd Hyg Safety, 14, 9-16 (1999)
  6. Hwang LH, Kim AK, Jung BK, Lee JK, Shin JM, Park YH, Park HW, Kim MJ, Park KA, Yun ES, Kim MS. Removal of pesticides during washing and cooking of rice. J Fd Hyg Safety, 28, 31-35 (2013) https://doi.org/10.13103/JFHS.2013.28.1.031
  7. Jo SA, Kim EH, Kim KS, Kim JH, Park SG. Change of the concentration of pesticide residues in pepper powder by storage temperature and storage period. Korean J Pestic Sci, 13, 127-132 (2009)
  8. Kang NS, Kin SC, Kang YJ, Kim DH, Jang JW, Won S, Hyun JH, Kim DG, Rhee GS, Shin YM, Joung DY, Kim SY, Park JY, Kwon KS, Ji YG. Monitoring and exposure assessment of pesticide residues in domestic agricultural products. Korean J Pestici Sci, 19, 32-40 (2015) https://doi.org/10.7585/kjps.2015.19.1.32
  9. Kim HJ, Hwang KW, Sun JH, Lee TH, Jeong KS, Moon JK. Residual characteristics of insecticide flubendiamide in kale. J Appl Biol Chem, 65, 173-181 (2022) https://doi.org/10.3839/jabc.2022.023
  10. Kim HR, Kwon YH, Kim JH, Ahn BH. Quality analysis of diverse rice species for rice products. Korean J Food Sci Technol, 43, 142-148 (2011) https://doi.org/10.9721/KJFST.2011.43.2.142
  11. Kim HY, Jeon YH, Hwang JI, Kim JH, Ahn JW, Chung DH, Kim JE. Monitoring of pesitcide residues and risk assessment for cereals and leafy vegetables of certificated and general agricultural produts. Korean J Environ Agric, 30, 440-445 (2011) https://doi.org/10.5338/KJEA.2011.30.4.440
  12. Kim JA, Seo JA, Lee HS, Lim MH. Residual characteristics and processing factors of azoxystrobin during eggplant and lettuce processing. J Appl Biol Chem, 63, 51-60 (2020) https://doi.org/10.3839/jabc.2020.007
  13. Kim JY, Lee SM, Lee HJ, Chang MI, Kang NS, Kim NS, Kim HJ, Cho YJ, Jeong JY, Kim MK, Rhee GS. Monitoring and risk assessment of pesticide residues for circulated agricultural commodities in Koera-2013. Korea J Appl Biol Chem, 57, 235-242 (2014) https://doi.org/10.3839/jabc.2014.037
  14. Kim MJ, Lee KH, Kim HJ, Ko JY, Lee SK, Park HY, Sim EY, Oh SK, Lee CK, Woo KS. Quality and antioxidant characteristics of cooked rice influenced by the mixing rate of glutinous rice and ocoking methods. Korean J Crop Sci, 62, 96-104 (2017a) https://doi.org/10.7740/kjcs.2017.62.2.096
  15. Kim MJ, Lee KH, Ko JY, Kim HJ, Lee SK, Park HY, Sim EY, Cho DH, Oh SK, Woo KS. Effect of cooking methods on cooked and antioxidant characteristics of cooked mixed grain rice with added proso millet. Korean J Food Nutr, 30, 218-225 (2017b) https://doi.org/10.9799/ksfan.2017.30.2.218
  16. Kim MR, Na MA, Jung WY, Kim CS, Sun NK, Seo EC, Lee EM, Park YG, Byun JA, Eom JH, Jung RS, Lee JH. Monitoring of pesticide residues in special products. Korean J Pestic Sci, 12, 323-334 (2008)
  17. Kim NH, Lee MG, Lee SR. Elimination of phenthoate residues in the washing and cooking of polished rice. Korean J Food Sci Technol, 28, 490-496 (1996)
  18. Kim SH, Kim YA. The sensory properties and lipid contents of cooked rices depending on the variety and cooker. Korean J Soc Food Sci, 7, 1-6 (1991)
  19. Kim YH, Kim HN, Kim SS, Lee SR. Elimination of BHC residues in the polishing and cooking processes of brown rice. Korean J Food Sci Technol, 11, 18-25 (1979)
  20. Ko BS, Jeon TH, Jung KS, Lee SK. Removal effects of organic-phosphorus pesticide residue in lettuce by washing methods. Korean J Rural Med, 21, 159-171 (1996)
  21. Kwak SY, Lee SH, Jeong HR, Nam AJ, Sarker A, Kim HY, Lim CU, Cho HJ, Kim JE. Variation of pesticide residues in strawberries by washing and boiling processes. Korean J Environ Agric, 38, 281-290 (2019) https://doi.org/10.5338/KJEA.2019.38.4.38
  22. Kwon Hy, Kim Jb, Lee HD, Ihm YB, Kyung KS, Park IH, Choi J. Estimae of pesticide residues in tomato varieties using ratio of surface area to weight. Korean J Pestic Sci, 8, 30-37 (2004)
  23. Lee BD, Eun JB. Rice processing in food industry. Food Ind Nutr, 13, 1-8 (2008)
  24. Lee YJ, Park MK, Kim KY, Park EM, Kang HG, Lim JH, Cho WH, Kim YH, Lee SY, Yong KC, Yoon MH. Monitoring and safety assessment of pesticide resdiues and sulfur dioxide on functional rice products. J Food Hyg Saf, 32, 493-499 (2017) https://doi.org/10.13103/JFHS.2017.32.6.493
  25. Ministry of Food and Drug Safety (MFDS). Korean food standard Codex multiresidue method-2. Available from: http://various.foodsafetykorea.go.kr/fsd/#/. Accessed Apr. 28, 2023a.
  26. Ministry of Food and Drug Safety (MFDS). Pesticides MRLs in agricultural commodities. Available from: http://various.foodsafetykorea.go.kr/fsd/#/. Accessed Apr. 28, 2023b.
  27. Oh YJ, Hwamg IS, Park SW, Choi GH, Ryu SH, Kwon HY, Hwang ES, Kim JH, Lee HS. Effects of chlorine dioxide solution on reduction of pesticide residues in the apple and perilla leaf. Korean J Pestic Sci, 23, 135-145 (2019) https://doi.org/10.7585/kjps.2019.23.3.135
  28. Onouki E. Anythropology of Rice. Sohwa, Seoul, Korea, p 20-76 (2001)
  29. Park BJ, Choi JH, Kim CS, Im GJ, Oh BY, Shim JH. Volatilization of molinate in paddy rice ecosystem and its concsntration in air causing phytotxicity to chili pepper. Korean J Pestic Sci, 9, 70-80 (2005)
  30. Ro JH, Lim SJ, Jin YD, Kim Db, Choi GH, Kim SS, Lee HW, Park JH. Residue patterns of hexaconazole, tricyclazole, etofenprox and imidacloprid in polished and unpolished rice. Korean J Pestic Sci, 21, 324-331 (2017) https://doi.org/10.7585/kjps.2017.21.3.324
  31. Turner JA. The Pesticide Manual a World Compendium. 17th ed, BCPC, Alton, Hampshire, UK, p 6-1147 (2015)
  32. Wang Z, Huang J, Chen J, Li F. Effectiveness of dishwashing liquids in removing chlorothalonil and chlorpyrifos residues of from cherry tomatoes. Chemosphere, 92, 1022-1028 (2013) https://doi.org/10.1016/j.chemosphere.2013.03.039
  33. Yoon CH, Park WC, Kim JE, Kim CH. Remocal efficiency of pesticide residues on apples by ultrasonic cleaner. Korean J Environ Agric, 16, 255-258 (1997)
  34. You YH, Lee YS, Kwon HJ. Reduction factors of pesticides with different physicochemical properties under washing and cooking conditions. Korean J Food Sci Technol, 43, 537-543 (2011) https://doi.org/10.9721/KJFST.2011.43.5.537
  35. Zhao L, Ge J, Liu F, Jiang N. Effects of storage and processing on residue levels of chlorpyrifos in soybeans. Food Chem, 150, 182-186 (2014) https://doi.org/10.1016/j.foodchem.2013.10.124