공업화학 (Applied Chemistry for Engineering)

  • 제33권5호
  • /
  • Pages.523-531
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  • 2022
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  • 1225-0112(pISSN)
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  • 2288-4505(eISSN)
한국공업화학회 (The Korean Society of Industrial and Engineering Chemistry)
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Influence of Urea Precursor on the Electrochemical Properties of Ni-Co-based Metal Organic Framework Electrodes for Supercapacitors

  • Jung, Ye Seul (School of Chemical Engineering, Pusan National University) ;
  • Jung, Yongju (Department of Applied Chemical Engineering, Korea University of Technology and Education) ;
  • Kim, Seok (School of Chemical Engineering, Pusan National University)
  • 투고 : 2022.07.21
  • 심사 : 2022.08.27
  • 발행 : 2022.10.10
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초록

A NiCo-metal organic framework (MOF) electrode, prepared using urea as a surfactant, was synthesized using a one-pot hydrothermal method. The addition of urea to the NiCo-MOF creates interstitial voids and an ultra-thin nanostructure in the NiCo-MOF, which improves its charge transfer performance. We obtained the optimal metal to surfactant ratio to achieve the best specific capacitance. The NiCo-MOF was employed as the working electrode material in a three-electrode system. Field emission scanning electron microscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy were employed to characterize the microstructures and morphologies of the composites. Cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy curves were employed to quantify the electrochemical properties of the electrodes in a 6 M KOH electrolyte.

키워드

과제정보

This work was supported by a 2-Year Research Grant of Pusan National University.

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