Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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The Effect of Chemical Structure of Main Monomers and Cross-linking Monomers for Acrylic Co-polymers

  • Kang, Eun-Jin (Department of Textile System Engineering, Kyungpook National University) ;
  • Cheon, Ji-Yeon (Department of Textile System Engineering, Kyungpook National University) ;
  • Lee, Yoon-Gu (Department of Textile System Engineering, Kyungpook National University) ;
  • Choi, Jae-Hong (Department of Textile System Engineering, Kyungpook National University)
  • Received : 2022.03.28
  • Accepted : 2022.04.14
  • Published : 2022.06.30
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Abstract

In this research, the relationships between the chemical structures of 10 different acrylate monomers with 3 different cross-linking monomers were evaluated. The thermal stabilities of the prepared copolymers were evaluated by their weight-loss percentage through thermogravimetric analysis, and their glass-transition temperatures were analyzed using differential scanning calorimetry. Based on the results, some relationships between the chemical structures of the monomers and their properties were derived and are discussed herein.

Keywords

Acknowledgement

본 연구는 산업통상자원부의 전략핵심소재자립화기술개발사업(과제번호 : 20010403)에 의해 지원되어 수행되었으며 이에 감사 드립니다.

References

  1. A. Chroni, T. Mavromoustakos, and S. Pispas, "Nano assemblies from amphiphlic PnBA-b-POEGA copolymers as drug nanocarriers", Polymers, 13, 1164 (2021). https://doi.org/10.3390/polym13071164
  2. S. M. N. Donlucas etc., "Synthesis of poly(methacrylic acid-co-butyl acrylate) ethylacrylate) grafted on functionalized carbon nanotube nanocomposites for drug delivery", Polymers, 13, 533 (2021). https://doi.org/10.3390/polym13040533
  3. C. Liu, H. Qiao, G. Xu, Y. Liang, J. Yang, and J. Hu, "Phosphorous-nitrogen modification of epoxy grafted poly-acrylic resin: synergistic flame retardment effect", Polymers, 13, 2826 (2021). https://doi.org/10.3390/polym13162826
  4. C. V. C. Yilmaz, O. Yilmaz, and R. N. D. Nita Hu, "The effect of different soft core/hard shell ratios on the coating performance of acrylic copolymer latexes", Polymers, 13, 3521 (2021). https://doi.org/10.3390/polym13203521
  5. K. Bys, and W. Zajac etc., "Novel tough and transparent ultra-extensible nanocomposite elastomers based on poly(2-methoxyethylacrylate) and their switching between plastoelasticity and viscoelasticity", Polymers, 13, 4254 (2021). https://doi.org/10.3390/polym13234254
  6. Z. Shen, Y. Weng, Y. Zhang, C. Wang, A. Liu, and X. Li, "Liquid Crystal Elastomer-Based Soft Actuators", Polymers, 13, 936 (2021). https://doi.org/10.3390/polym13060936
  7. P. Cieciorski, P. W. Majewski, and E. Megiel, "New photoresponsive poly(meth)acrylates bearing azobenzene moieties obtained via ATRP polymerization exhibiting liquid-crystalline behavior", Polymers, 13, 2172 (2021). https://doi.org/10.3390/polym13132172
  8. C. G. F. Hernandez, M. A. C. Villegas, A. M. Martell, and A. D. Real, "Synthesis of a bio-degradable polymer of poly(sodium alginate/ethyl acrylate)", Polymers, 13, 504 (2021). https://doi.org/10.3390/polym13040504
  9. M. I. Penas etc., "How is rheology involved in 3D printing of phase-separated PVC-acrylate copolymers obtained by free radical polymerization", Polymers, 12, 2070 (2020). https://doi.org/10.3390/polym12092070
  10. M. Lee, J. Lee, J. Jang, C. Nah, and Y. I. Huh, "Fabrication and characterization of modified poly(2-hydroxyethyl methacrylate)(PHEMA) hydrogels by thermal/photo polymerization", Elastom. Compos., 54, 360 (2019).
  11. K. Wnuczek, A. Puszka, A. Klapiszewski, and B. Podkoscielna, "Preparation, thermal, and thermo-mechanical characterization of polymeric blends based on di(meth)acrylate monomers", Polymers, 13, 878 (2021). https://doi.org/10.3390/polym13060878
  12. J. Matzig, M. Drache, and S. Beuermann, "Self-initiated butyl acrylate polymerizations in bulk and in solution monitored by in-line techniques", Polymers, 13, 2021 (2021). https://doi.org/10.3390/polym13122021
  13. N. Rimdusit etc., "Radiation graft-copolymerization of ultrafine fully vulcanized powdered natural rubber: effects of styrene and acrylonitrile contents on thermal stability", Polymers, 13, 3447 (2021). https://doi.org/10.3390/polym13193447
  14. E. Y. Kozhunova, A. V. Plutalova, and E. V. Chernikova, "RAFT copolymerization of vinyl acetate and acrylic acid in the selective solvent", Polymers, 14, 555 (2022). https://doi.org/10.3390/polym14030555
  15. S. H. Han, E. J. Lee, and J. K. Choi, "Synthesis and properties of polybenzoxazole copolymers having nonlinear units", Elastom. Compos., 54, 323 (2019).
  16. X. X. Li, M. H. Sohn, and U. R. Cho, "Synthesis and properties of bio- thermoplastic polyurethanes with different isocyanate contents", Elastom. Compos., 54, 226 (2019).
  17. H. Jakob etc., "Peroxo compounds, Inorganic, Ullmann's Encyclopedia of Industrial Chemistry", Wiley-VCH, Weinheim, 2007.
  18. J. McMurry, "Organic Chemistry", 9th Ed., p. 79, Cengage Learning Asia Pte, Andover, 2016.