유연 OLED 디스플레이의 기계적 안정성을 위한 제로 스트레스 봉지막 설계

Design of Zero-Stress Encapsulation for Mechanical Stability of Flexible OLED Displays

  • Jeong, Eun Gyo (Department of Clothing and Textiles, Chonnam National University)
  • 투고 : 2022.02.09
  • 심사 : 2022.03.25
  • 발행 : 2022.03.31

초록

In this paper, a study was conducted on encapsulation technology for high mechanical stability of flexible displays. First, unlike conventional encapsulation barrier that exclude cracks as much as possible for low water vapor transmission rate (WVTR), mechanical properties were improved by using a defect suppression mechanism introduced with crack arresters. The zero-stress encapsulation barrier optimizes the residual stress of the thin film based to improve the internal mechanical stability. The zero-stress encapsulation barrier was applied to the organic light emitting diodes (OLEDs) to confirm its characteristics and lifetime. Due to improved internal mechanical stability, it has a longer lifetime more than 35% compared to conventional encapsulation technologies. As the zero-stress encapsulation barrier proposed in this study does not require additional deposition process, it is not difficult to apply it. Based on various advantages, it is expected to play an important role in flexible displays.

키워드

과제정보

이 논문은 전남대학교 학술연구비(과제번호: 2021-24360) 지원에 의하여 연구되었음.

참고문헌

  1. Neugebauer, H., Brabec, C. J., Hummelen, J. C., Janssen, R. A. J., and Sariciftci, N. S., "Stability studies and degradation analysis of plastic solar cell materials by FTIR spectroscopy," Synthetic metals, 102(1-3), pp. 1002-1003, (1999). https://doi.org/10.1016/S0379-6779(98)01184-9
  2. Bazaka, K., and Jacob, M. V., "Post-deposition ageing reactions of plasma derived polyterpenol thin films," Polymer Degradation and Stability, 95(6), pp. 1123-1128, (2010). https://doi.org/10.1016/j.polymdegradstab.2010.02.014
  3. Jorgensen, M., Norrman, K., and Krebs, F. C., "Stability/degradation of polymer solar cells," Solar energy materials and solar cells, 92(7), pp. 686-714, (2008). https://doi.org/10.1016/j.solmat.2008.01.005
  4. Jeranko, T., Tributsch, H., Sariciftci, N. S., and Hummelen, J. C., "Patterns of efficiency and degradation of composite polymer solar cells," Solar Energy Materials and Solar Cells, 83(2-3), pp. 247-262, (2004). https://doi.org/10.1016/j.solmat.2004.02.028
  5. Grossiord, N., Kroon, J. M., Andriessen, R., and Blom, P. W., "Degradation mechanisms in organic photovoltaic devices," Organic Electronics, 13(3), pp. 432-456, (2012). https://doi.org/10.1016/j.orgel.2011.11.027
  6. Lin, Y. Y., Chang, Y. N., Tseng, M. H., Wang, C. C., & Tsai, F. Y., "Air-Stable flexible organic light-emitting diodes enabled by atomic layer deposition," Nanotechnology, 26(2), p. 024005, (2014). https://doi.org/10.1088/0957-4484/26/2/024005
  7. Choi, J.-H., Kim, Y.-M., Park, Y.-W., Park, T.-H., Jeong, J.-W., Choi, H.-J., Song, E.-H., Lee, J.-W., Kim, C.-H., and Ju, B.-K., "Highly conformal SiO2/Al2O3 nanolaminate gas-diffusion barriers for large-area flexible electronics applications," Nanotechnology, 21(47), p. 475203, (2010). https://doi.org/10.1088/0957-4484/21/47/475203
  8. Seo, S. W., Jung, E., Chae, H., and Cho, S. M., "Optimization of Al2O3/ZrO2 nanolaminate structure for thin-film encapsulation of OLEDs." Organic Electronics, 13(11), pp. 2436-2441, (2012). https://doi.org/10.1016/j.orgel.2012.07.007
  9. Han, Y. C., Kim, E., Kim, W., Im, H. G., Bae, B. S., and Choi, K. C., "A flexible moisture barrier comprised of a SiO2-embedded organic-inorganic hybrid nanocomposite and Al2O3 for thin-film encapsulation of OLEDs." Organic Electronics, 14(6), pp. 1435-1440, (2013). https://doi.org/10.1016/j.orgel.2013.03.008
  10. Han, Y. C., Jang, C., Kim, K. J., Choi, K. C., Jung, K., and Bae, B. S., "The encapsulation of an organic light-emitting diode using organic-inorganic hybrid materials and MgO," Organic electronics, 12(4), pp. 609-613, (2011). https://doi.org/10.1016/j.orgel.2011.01.007
  11. Kim, E., Han, Y., Kim, W., Choi, K. C., Im, H. G., and Bae, B. S., "Thin film encapsulation for organic light emitting diodes using a multi-barrier composed of MgO prepared by atomic layer deposition and hybrid materials," Organic Electronics, 14(7), pp. 1737-1743, (2013). https://doi.org/10.1016/j.orgel.2013.04.011
  12. Ramsteiner, F., Jaworek, T., Weber, M., and Forster, S., "Scratch resistance and embrittlement of coated polymers," Polymer testing, 22(4), pp. 439-451, (2003). https://doi.org/10.1016/S0142-9418(02)00125-3
  13. Norrman, K., Larsen, N. B., and Krebs, F. C., "Lifetimes of organic photovoltaics: combining chemical and physical characterisation techniques to study degradation mechanisms." Solar energy materials and solar cells, 90(17), pp. 2793-2814, (2006). https://doi.org/10.1016/j.solmat.2006.04.009
  14. Griffith, Alan Arnold. "VI. The phenomena of rupture and flow in solids." Philosophical transactions of the royal society of london. Series A, containing papers of a mathematical or physical character, 221(582-593), pp. 163-198 (1921).
  15. Bartlett, Jamison L., and Xiaodong Li. "An overview of residual stresses in metal powder bed fusion." Additive Manufacturing, 27, pp. 131-149, (2019). https://doi.org/10.1016/j.addma.2019.02.020