Journal of Urban Science (도시과학)

Urban Science Institute (인천대학교 도시과학연구원)
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Effects of carbonation on hydration characteristics of ordinary Portland cement at pre-curing condition

  • Kim, Gwang Mok (한국지질자원연구원 광물자원연구본부)
  • Published : 2022.12.15
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Abstract

Raman spectroscopy is effective to investigate functional groups via molecular vibration. The technique offers the structural information of compounds including subtle changes in the chemical composition of local atomic coordination without critical damage. Thus, the effect of carbonation on the hydration characteristics of Portland cement under pre-curing conditions for carbonation was investigated via Raman spectroscopy in the present study. Gaseous CO2 was injected within 60 seconds, and the reaction time was varied from 0 minute to 90 minutes. The test results indicated that the Ca/Si ratio of C-S-H reduced immediately after mixing and then the C-S-H with a relatively high Ca/Si ratio coexisted as the reaction time increased. The calcium carbonates formed in the present study included calcite and amorphous calcium carbonates. The test results via Raman spectroscopy provide valuable information about the carbonation characteristics of OPC under pre-curing conditions for carbonation.

Keywords

Acknowledgement

This work was supported by Korea Institute of Energy Technology Evaluation and Planning(KETEP) grant funded by the Korea government(MOTIE)(20212010200080, In-situ carbonation technology development using CO2 emissions from cement industry).

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