Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Use of Capparis decidua Extract as a Green Inhibitor for Pure Aluminum Corrosion in Acidic Media

  • Al-Bataineh, Nezar (College of Pharmacy, Al Ain University) ;
  • Al-Qudah, Mahmoud A. (Department of Chemistry, Faculty of Science, Yarmouk University) ;
  • Abu-Orabi, Sultan (Department of Chemistry, Faculty of Science, Yarmouk University) ;
  • Bataineh, Tareq (Department of Chemistry, Faculty of Science, Yarmouk University) ;
  • Hamaideh, Rasha S. (Department of Chemistry, Faculty of Science, Yarmouk University) ;
  • Al-Momani, Idrees F. (Department of Chemistry, Faculty of Science, Yarmouk University) ;
  • Hijazi, Ahmed K. (Department of Chemistry, Faculty of Science, Jordan University of Science and Technology)
  • Received : 2021.09.15
  • Accepted : 2021.10.11
  • Published : 2022.02.28
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Abstract

The aim of this paper is to study corrosion inhibition of Aluminum with Capparis decidua extract. The study was performed in a 1.0 M solution of hydrochloric acid (HCl) and was monitored both by measuring mass loss and by using electrochemical and polarization methods. A scanning electron microscopy (SEM) technique was also applied for surface morphology analysis. The results revealed high inhibition efficiency of Capparis decidua extract. Our data also determined that efficiency is governed by temperature and concentration of extract. Optimum (88.2%) inhibitor efficiency was found with maximum extract concentration at 45 o C. The results also showed a slight diminution of aluminum dissolution when the temperature is low. Based on the Langmuir adsorption model, Capparis decidua adsorption on the aluminum surface shows a high regression coefficient value. From the results, the activation enthalpy (∆H#) and activation entropy (∆S#) were estimated and discussed. In conclusion, the study clearly shows that Capparis decidua extract acted against aluminum corrosion in acidic media by forming a protective film on top of the aluminum surface.

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References

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