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Interfacial Adhesion between Polyurethane Resin and Ultra-high-molecular-weight Polyethylene Fiber with Plasma Treatment and Low-concentration Polyurethane Coating

UHMWPE 섬유의 플라즈마 처리와 저농도 Polyurethane(PU) 코팅을 통한 PU 수지와의 계면접착성 연구

  • Choi, Ji Beom (Department of Applied Organic Materials Engineering, Chungnam National University) ;
  • Kang, Eun Hye (Department of Applied Organic Materials Engineering, Chungnam National University) ;
  • Lee, Pil Gyu (Department of Applied Organic Materials Engineering, Chungnam National University) ;
  • Lee, Jae Min (Department of Applied Organic Materials Engineering, Chungnam National University) ;
  • Kim, Jong Hee (Research Institute for Applied Chemistry and Biological Engineering) ;
  • Lee, Jee Eun (Agency for Defense Development) ;
  • Lee, Seung Goo (Department of Applied Organic Materials Engineering, Chungnam National University)
  • 최지범 (충남대학교 유기응용재료공학과) ;
  • 강은혜 (충남대학교 유기응용재료공학과) ;
  • 이필규 (충남대학교 유기응용재료공학과) ;
  • 이재민 (충남대학교 유기응용재료공학과) ;
  • 김종희 (바이오응용화학연구소) ;
  • 이지은 (국방과학연구소) ;
  • 이승구 (충남대학교 유기응용재료공학과)
  • Received : 2022.02.02
  • Accepted : 2022.02.22
  • Published : 2022.02.28

Abstract

In this study, the interfacial adhesion between polyurethane (PU) resin and ultra-high-molecular-weight polyethylene (UHMWPE) fiber, which was coated with low-concentration PU after plasma treatment, was investigated. First, the UHMWPE fiber was treated with nitrogen plasma. Subsequently, it was coated with extremely low-concentration PU resin for improving its interfacial adhesion with the PU resin. The effects of plasma treatment and low-concentration PU coating were analyzed using XPS, FTIR-ATR, SEM, and AFM. Furthermore, the interfacial shear strength between the plasma-treated UHMWPE fiber and PU resin was measured using the microdroplet test. Consequently, the interfacial adhesion was improved by the low-concentration PU coating after the plasma treatment, due to the increase in mechanical interlocking and molecular diffusion of PU resin.

Keywords

Acknowledgement

이 연구는 국방과학연구소 민군협력진흥원 민군겸용기술개발사업(과제번호: G2519CM50810001)의 지원으로 수행된 연구이며, 이에 감사드립니다.

References

  1. S. I. Moon and J. Jang, "The Effect of the Oxygen-plasma Treatment of UHMWPE Fiber on the Transverse Properties of UHMWPE-fiber/vinylester Composites", 1999, 59, 487-493.
  2. S. G. Lee, J. I. Yuck, C. W. Joo, and T. J. Kang, "Effect of the Oxygen Plasma Treatments on the Surface Morphology of the Ultra-high Molecular Weight Polyethylene Fiber", J. Korean Fiber Soc., 1996, 33, 376-385.
  3. S. G. Lee, D. C. Kim, and T. J. Kang, "The Effect of Oxygen Plasma Treatment on the Physico-Chemical Properites and Interfacial Strength of UHMWPE Fibers", J. Korean Fiber Soc., 1997, 34, 459-465.
  4. J. S. Won, H. Y. Choi, J. J. Yoo, H. N. Choi, D. K. Young, and S. G. Lee, "Interfacial Adhesion Properites of Oxygen Plasma Treated Polyketone Fiber with Natural Rubber", J. Adhesion and Interface, 2012, 13, 45-50. https://doi.org/10.17702/jai.2012.13.1.045
  5. S. J. Seop, "Polyurethane Materials for Coating", The Rubber Society of Korea, 1992, 27, 39-45.
  6. S. H. Yoo, H. J. Song, and C. K. Kim, "Surface Treatment of Silica Nanoparticles and the Characteristics of Their Composites with Thermoplastic Polyurethane Elastomer", Polymer(Korea), 2012, 36, 721-726.
  7. T. Zhang, Y. Zhao, H. Li, and B. Zhang, "Effect of Polyurethane Sizing on Carbon Fibers Surface and Interfacial Adhesion of Fiber/polyamide 6 Composites", J. Appl. Polym., 2018, 135, 46111. https://doi.org/10.1002/app.46111
  8. T. S. Lee, B. S. Kim, H. N. Choi, K. Y. Lee, and S. G. Lee, "Interfacial Adhesion Properties of Plasma Treated Aramid Fiber with Chloroprene Rubber", Text. Sci. Eng., 2010, 47, 205-211.
  9. A. Vesel and M. Mozetic, "Modification of PET Surface by Nitrogen Plasma Treatment", J. Phys.: Conference Series, 2008, 100, 1-4. https://doi.org/10.1113/jphysiol.1941.sp003922
  10. I. Bertoti, M. Mohai, and K. Laszlo, "Surface Modification of Graphene and Graphite by Nitrogen Plasma: Determination of Chemical State Alterations and Assignments by Quantitative X-ray Photoelectron Spectroscopy", ScienceDirect, 2015, 84, 185-196.
  11. I. Junkar, A. Vesel, U. Cvelbar, M. Mozetic, and S. Strnad, "Influence of Oxygen and Nitrogen Plasma Treatment on Polyethyleneterephthalate (PET) Polymers", Vaccum, 2010, 84, 83-85.
  12. M. K. Sim and S. D. Seul, "Surface Modification of Polymeric Material Using Atmospheric Plasma", Polymer(Korea), 2008, 32, 433-439.
  13. E. Abdel-Fattah and M. Alshaer, "Polyimide Surface Modification Using He-H2O Atmospheric Pressure Plasma Jet-Discharge Power Effect", Coatings, 2020, 662, 1-11.