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Analysis of Chemical Compounds of Gaseous and Particulate Pollutants from the Open Burning of Agricultural HDPE Film Waste

  • Kim, Tae-Han (Department of Green Smart City, Sangmyung University) ;
  • Choi, Boo-Hun (Department of Environmental Resources, Sangmyung University) ;
  • Kook, Joongjin (Department of Information Security Engineering, Sangmyung University)
  • 투고 : 2021.11.18
  • Accepted : 2021.12.09
  • Published : 2021.12.31

Abstract

Background and objective: Illegal open-air incineration, which is criticized as a leading source of air pollutants among agricultural activities, currently requires constant effort and attention. Countries around the world have been undertaking studies on the emission of heavy metal substances in fine dust discharged during the incineration process. A precise analytical method is required to examine the harmful effects of particulate pollutants on the human body. Methods: In order to simulate open-air incineration, the infrastructure needed for incineration tests complying with the United States Environmental Protection Agency (EPA) Method 5G was built, and a large-area analysis was conducted on particulate pollutants through automated scanning electron microscopy (SEM)-energy-dispersive X-ray spectroscopy (EDS). For the test specimen, high-density polyethylene (HDPE) waste collected by the DangJin Office located in Choongcheongnam-do was used. To increase the identifiability of the analyzed particles, the incineration experiment was conducted in an incinerator three times after dividing the film waste into 200 g specimens. Results: Among the metal particulate matters detected in the HDPE waste incineration test, transition metals included C (20.8-37.1 wt%) and O (33.7-37.9 wt%). As for other chemical matters, the analysis showed that metal particulate matters such as metalloids, alkali metals, alkaline earth metals, and transition metals reacted to C and C-O. Si, a representative metalloid, was detected at 14.8-20.8 wt%, showing the highest weight ratio except for C and O. Conclusion: In this study, the detection of metal chemicals in incinerated particulate matters was effectively confirmed through SEM-EDS. The results of this study verified that HDPE waste adsorbs metal chemicals originating from soil due to its own properties and deterioration, and that when incinerated, it emits particulate matters containing transition metals and other metals that contribute to the excessive production and reduction of reactive oxygen species.

Keywords

Acknowledgement

This work was carried out with the support of "Cooperative Research Program For Agriculture Science and Technology Development (Project No.PJ014283022021)" Rural Development Administration, Republic of Korea.

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