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역삼투압 농축수와 메타카올린을 사용한 친환경 시멘트의 개발

Development of Eco-friendly Cement using Reverse Osmosis Brine Water and Metakaolin

  • 투고 : 2021.05.28
  • 심사 : 2021.06.22
  • 발행 : 2021.06.30

초록

해수 담수화 플랜트에서 배출되는 농축수의 새로운 활용방안을 모색하기 위한 실험이다. 본 연구에서는 염화이온 고정화 효과가 뛰어난 메타카올린을 주요 결합재로 하고 활성화제로 10%와 20%의 산화칼슘을 치환하였다. 그리고 정수(tap-water; TW)와 농축수(reverse osmosis desalination water; RW)를 혼합수로 사용하였다. 실험결과 RW를 사용한 mixture는 TW 보다 더 높은 압축강도를 보였다. 또한 낮은 물-흡수율과 높은 밀도를 나타내었다. RW를 혼합수로 사용한 mixture에서는 Friedel's salt라는 수화반응물질을 관찰할 수 있었다. 강재의 부식문제를 고려한다면 RW는 무철근 콘크리트, 벽돌, 경계석 등의 제품에 적용할 수 있을 것으로 판단된다. 본 연구를 통해 RW의 해양 방출이외에 새로운 활용방안을 제시한 것에 의미 있다고 생각된다.

This is an experiment to complement new ways of using concentrated water discharged from the seawater desalination plant. In this study, metakaolin, which has excellent chloride ion immobilization effect, was used as the main binder, and 10% and 20% of calcium oxide were substituted with the activator. In addition, tap-water(TW) and reverse osmosis brine water(RW) were used as mixed water. As a result of the experiment, the mixture using RW showed higher compressive strength than TW. It also showed low water absorption and high density. In the mixture using RW as mixed water, a hydration reaction substance called Friedel's salt could be observed. Considering the corrosion problem of steel, RW is considered to be applicable to products such as non-reinforced concrete, brick, and curb stone. Through this study, it is thought that it is meaningful to propose a new application method other than the ocean release of RW.

키워드

과제정보

This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea Government(MOE)(NRF-2020R1I1A1A01056497)

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