한국재료학회지 (Korean Journal of Materials Research)

  • 제31권6호
  • /
  • Pages.331-338
  • /
  • 2021
  • /
  • 1225-0562(pISSN)
  • /
  • 2287-7258(eISSN)
한국재료학회 (Materials Research Society of Korea)
권호 표지
DOI QR코드

DOI QR Code

Failure and Phase Transformation Mechanism of Multi-Layered Nitride Coating for Liquid Metal Injection Casting Mold

  • 투고 : 2021.04.30
  • 심사 : 2021.05.18
  • 발행 : 2021.06.27
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Ti-Al-Si target and Cr-Si target are sputtered alternately to develop a multi-layered nitride coating on a steel mold to improve die-casting lifetime. Prior to the multi-layer deposition, a CrN layer is developed as a buffer layer on the mold to suppress the diffusion of reactive elements and enhance the cohesive strength of the multi-layer deposition. Approximately 50 nm CrSiN and TiAlSiN layers are deposited layer by layer, and form about three ㎛-thickness of multi-layered coating. From the observation of the uncoated and coated steel molds after the acceleration experiment of liquid metal injection casting, the uncoated mold is severely eroded by the adhesion of molten metallic glass. On the other hand, the multi-layer coating on the mold prevents element diffusion from the metallic glass and mold erosion during the experiment. The multi-layer structure of the coating transforms the nano-composite structured coating during the acceleration test. Since the nano-composite structure disrupts element diffusion to molten metallic glass, despite microstructure changes, the coating is not eroded by the 1,050 ℃ molten metallic glass.

키워드

과제정보

This work was supported by the Center for Advanced Materials Processing (CAMP) of the 21st Century Frontier R&D Program (No. F00030492007-311006000115) funded by the Ministry of Knowledge Economy, Korea, and by the National Research Foundation of Korea (NRF) grant (No. 2010-0026981) funded by the Ministry of Education, Science, and Technology, Korea.

참고문헌

  1. A. Inoue, Acta Mater., 48, 279 (2000). https://doi.org/10.1016/S1359-6454(99)00300-6
  2. N. Nagendra, U. Ramamurty, T. T. Goh and Y. Li, Acta Mater., 48, 2603 (2000). https://doi.org/10.1016/S1359-6454(00)00052-5
  3. M. T. Nagata, J. G. Speer and D. K. Matlock, Scr. Mater., 44, 899 (2001). https://doi.org/10.1016/S1359-6462(00)00696-5
  4. C. Jeon, D. J. Ha, C. P. Kim and S. Lee, Metall. Mater. Trans. A, 43, 3663 (2012). https://doi.org/10.1007/s11661-012-1168-7
  5. P. Y. Lee, S. S. Hung, J. T. Hsieh, Y. L. Lin and C. K. Lin, Intermetallics, 10, 1277 (2002). https://doi.org/10.1016/S0966-9795(02)00154-1
  6. S. Y. Kim, E. S. Park, R. T. Ott, T. A. Lograsso, M. Y. Huh, D. H. Kim, J. Eckert and M. H. Lee, Sci. Rep., 5, 16540 (2015). https://doi.org/10.1038/srep16540
  7. J. Degmova, S. Roth, J. Eckert, H. Grahl and L. Schultz, Mater. Sci. Eng., A, 375-377, 265 (2004). https://doi.org/10.1016/j.msea.2003.10.023
  8. W. L. Johnson, JOM, 54, 40 (2002). https://doi.org/10.1007/BF02822619
  9. A. Inoue, Mater. Sci. Eng., A, 304-306, 1 (2001). https://doi.org/10.1016/S0921-5093(00)01551-3
  10. Y. H. Kim, K. R. Lim, W. T. Kim, D. H. Kim, Y. S. Choi and Y. S. Na, Res. Mater., 3, 100045 (2019). https://doi.org/10.1016/j.rinma.2019.100045
  11. J. Schroers, T. M. Hodges, G. Kumar, H. Raman, A. J. Barnes, Q. Pham and T. A. Waniuk, Mater. Today, 14, 14 (2011). https://doi.org/10.1016/S1369-7021(11)70018-9
  12. C. Mitterer, F. Holler, F. Ustel and D. Heim, Surf. Coat. Technol., 125, 233 (2000). https://doi.org/10.1016/S0257-8972(99)00557-5
  13. V. Nunes, F. J. G. Silva, M. F. Andrade, R. Alexandre and A. P. M. Baptista, Surf. Coat. Technol., 332, 319 (2017). https://doi.org/10.1016/j.surfcoat.2017.05.098
  14. S. Naimi and S. M. Hosseini, Adv. Mech. Eng., 7, 286071 (2015). https://doi.org/10.1155/2014/286071
  15. O. Knotek, F. Loffler, A. Schrey and B. Bosserhoff, Surf. Coat. Technol., 61, 133 (1993). https://doi.org/10.1016/0257-8972(93)90215-A
  16. O. Knotek, F. Loffler and B. Bosserhoff, Surf. Coat. Technol., 62, 630 (1993). https://doi.org/10.1016/0257-8972(93)90310-K
  17. V. K. W. Grips, V. E. Selvi, H. C. Barshilia and K. S. Rajam, Electrochim. Acta, 51, 3461 (2006). https://doi.org/10.1016/j.electacta.2005.09.042
  18. H. C. Barshilia and K. S. Rajam, Bull. Mater. Sci., 30, 607 (2007). https://doi.org/10.1007/s12034-007-0096-4
  19. B. Yang, L. Chen, K. K. Chang, W. Pan, Y. B. Peng, Y. Du and Y. Liu, Int. J. Refract. Met. Hard Mater., 35, 235 (2012). https://doi.org/10.1016/j.ijrmhm.2012.06.007
  20. M. Danek, F. Fernandes, A. Cavaleiro and T. Polcar, Surf. Coat. Technol., 313, 158 (2017). https://doi.org/10.1016/j.surfcoat.2017.01.053
  21. M. G. Faga, G. Gautier, R. Calzavarini, M. Perucca, E. A. Boot, F. Cartasegna and L. Settineri, Wear, 263, 1306 (2007). https://doi.org/10.1016/j.wear.2007.01.109
  22. W. Tillmann and M. Dildrop, Surf. Coat. Technol., 321, 448 (2017). https://doi.org/10.1016/j.surfcoat.2017.05.014
  23. H. C. Barshilia and K. S. Rajam, Surf. Coat. Technol., 155, 195 (2002). https://doi.org/10.1016/S0257-8972(02)00008-7
  24. E. J. Vinarcik, High Integ. Die Cast. Proc., p.161, John Wiley & Sons, Hoboken, New Jersey, USA (2003).
  25. R. Shivpuri and S. L. Semiatin, Fric. Lub. Wear Tech., p. 621, Mater. Park, OH, USA (1992).
  26. S. Maim and L. A. Norstrom, Met. Sci., 13, 544 (1979). https://doi.org/10.1179/030634579790438291
  27. B. Huang, W. Le, Y. Wang, X. Luo and Y. Yang, Appl. Surf. Sci., 464, 10 (2019). https://doi.org/10.1016/j.apsusc.2018.09.077
  28. A. A. Vereschaka, S. N. Grigoriev, N. N. Sitnikov, G. V. Oganyan and A. Batako, Surf. Coat. Technol., 332, 198 (2017). https://doi.org/10.1016/j.surfcoat.2017.10.027
  29. P. E. Hovsepian, A. P. Ehiasarian and U. Ratayski, Surf. Coat. Technol., 203, 1237 (2009). https://doi.org/10.1016/j.surfcoat.2008.10.033
  30. P. E. Hovsepian, A. P. Ehiasarian, A. Deeming and C. Schimpf, Vacuum, 82, 1312 (2008). https://doi.org/10.1016/j.vacuum.2008.03.064
  31. J. R. Roos, J. P. Celis, E. Vancoille, H. Veltrop, S. Boelens, F. Jungblut, J. Ebberink and H. Homberg, Thin Solid Films, 193-194, 547 (1990). https://doi.org/10.1016/S0040-6090(05)80064-1
  32. I. Tsutomu and S. Hiroshi, Thin Solid Films, 195, 99 (1991). https://doi.org/10.1016/0040-6090(91)90262-V
  33. Y. C. Chim, X. Z. Ding, X. T. Zeng and S. Zhang, Thin Solid Films, 517, 4845 (2009). https://doi.org/10.1016/j.tsf.2009.03.038