DOI QR코드

DOI QR Code

연신비와 첨가제 CaCO3가 PE 모노필라멘트의 물성에 미치는 영향

Effects of Draw Ratio and Additive CaCO3 Content on Properties of High-Performance PE Monofilament

  • Park, Eun-Jeong (HAESUNG ENTERPRISE CO., LTD) ;
  • Kim, Il-Jin (Korea Institute of Footwear and Leather Technology) ;
  • Lee, Dong-Jin (Korea Institute of Footwear and Leather Technology) ;
  • Kim, Jung-Soo (Korea Institute of Footwear and Leather Technology) ;
  • Lee, Young-Hee (Dept. of Organic Material Science and Engineering, Pusan National University)
  • 투고 : 2021.03.17
  • 심사 : 2021.04.23
  • 발행 : 2021.04.30

초록

The effect of draw ratio (8, 10, 12, 14 times) and additive CaCO3 content (0, 0.5, 1.0, 1.5, 2.0, and 3.0 wt%) on the properties of high-performance PE monofilament was investigated in this study. As the draw ratio increased (8-14 times), the melting enthalpy (ΔHf), crystallinity, specific gravity, and tensile strength increased significantly. However, the draw ratio had little effect on the melting temperature (Tm) and crystallization temperature (Tc). The seawater fastness (stain and fade) of the hydrophobic PE monofilament prepared in this study showed an excellent grade of 4-5 in all draw ratios. To investigate the effect of the additive CaCO3 content on the properties of high-performance PE monofilament, the draw ratio was fixed at 14 times. It was found that the tensile strength of the PE monofilament sample containing 0.5 wt% of CaCO3 was much greater compared to the sample without CaCO3, but the elongation of the sample containing 0.5 wt% of CaCO3 was much less than the sample with 0 wt% CaCO3. However, in the case of the sample containing more than 0.5 wt% CaCO3, the tensile strength slightly decreased and the elongation slightly increased as the CaCO3 content increased. The seawater fastness (stain and fade) of the hydrophobic PE monofilament showed excellent grades of 4-5, regardless of the amount of additives. From the above results, it was found that the maximum draw ratio of 14 times with an additive of 0.5 wt% CaCO3 are the optimal conditions for manufacturing high-performance marine fusion materials with various fineness (denier) with high strength and low elongation.

키워드

과제정보

본 연구는 산업통상자원부의 해양융복합소재산업화사업(과제번호:10053826)으로 수행된 연구 결과임.

참고문헌

  1. Beak, K. W., Lee, S. G., Lee, J. H., Choi, K. Y., & Weon, J. I. (2009). Quantitative evaluation of scratch behavior for polymeric materials. Polymer, 33(4), 273-283.
  2. Breue, F. W., Haaf, F., & Stabenow, J. (1977). Stress whitening and yielding mechanism of rubber-modified PVC. Journal of Macromolecular Science Part B Physics, 14, 387-417. doi:10.1080/00222347708212908
  3. Cherry, B. W., & Hin, T. S., J. I. (1981). Stress whitening in polyethylene. Polymer, 22, 1610-1612. https://doi.org/10.1016/0032-3861(81)90372-4
  4. Flory, J. F., Goksoy M., & Hearle J. W. S. (1987). Abrasion resistance of polymeric fibers in marine conditions. International Conference on Polymeric Fibers in a Marine Environment, 2nd, London, England, pp. 194-204.
  5. Gaechter, R., & Mueller, H. (1985). Plastic additives handbook - Stabilizer, processing aids, plasticizers, fillers, reinforcements, colorants for thermoplastics. New York: Hanser Pub.Hanser Pub.
  6. Grigoriadou, I., Paraskevopoulos, K., Chrissafis, K., Pavlidou, E., Stamkopolos, T.-G., & Bikiafis, D. (2011), Effect of different nanoparticles on HDPE UV stability. Polymer Degradation and Stability, 96, 151-163. doi:10.1016/j.polymdegradstab.2010.10.001
  7. Hitachi High-Tech Science Corporation. (1986). DSC measurement of polyethylene-The correlation of polyethylene density and melting. Tokyo: Hitachi High-Tech Science Corporation.
  8. Kang, D. H., Choi, J. H., Jang, K. H., Hong, C. H., & Park, W. H. (2017). Measurement and prediction of the effect of number and denier of HDPE fibers on creep behavior. Textile Science and Engineering, 54(2), 94-99. doi:10.12772/TSE.2017.54.094
  9. Korea Textile Development Institute. (2006). Future textile materials. Daegu.
  10. Kwon, Y. Y., & Kim, M. H. (2015). Industry and trends of marine convergence materials. Fiber Technology and Industry, 19(1), 37-53.
  11. Lee, E. J., Lee, C. W., & Kim, J. Y. (2010). Study on abrasion resistance of mooring ropes. Textile Coloration and Finishing, 22, 373-378. doi:10.5764/TCF.2010.22.4.373
  12. Mark, H. F. & Gaylord N. G. (1967) Encyclopedia of polymer science and technology. Volume 6 N. M. Bikales, N. M.(Ed). Plastics, resins, rubbers, fibers. New York: Interscience publishers a division of John Wiley & Sons, Inc.
  13. Ryu, Y. S., Seo, M. K., Park, E. J., Bae J. Y., Lee, Y. H., & Kim, H. D. (2017). Effect of draw ratio on the properties of metallocenecatalyzed high density polyethylene monofilaments for mooring rope. Textile Science and Engineering, 54(1), 44-53. doi:10.12772/TSE.2017.54.044
  14. The Korean Fiber Society. (1996). Man-made Fibers. Seoul: Hyungsel.
  15. Vasile, C. (2000). Handbook of polyolefins(2nd ed.), New York: Marcel Dekker.
  16. Vasile, C. & Pascu, M. (2005). Practical guide to polyethylene. UK: RAPRA Technol. Press.
  17. Vlasblom, M. P., Boesten, J., Leite, S., & Davies, P. (2012). Development of HMPE fiber for permanent deep water offshore mooring. Offshore Technology Conference (OTC 23333), Houston, Texas, USA. 1-15. doi:10.4043/23333-MS
  18. Wunderlich, B. (1990). Thermal analysis. USA: Academic Press.