Membrane and Water Treatment

  • 제12권2호
  • /
  • Pages.75-82
  • /
  • 2021
  • /
  • 2005-8624(pISSN)
  • /
  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Extraction of La(III) by a nonionic microemulsion containing D2EHPA in hollow fiber contactor

  • Ou, Huilin (College of chemistry and Chemical Engineering, Guangxi University) ;
  • Gong, Fuzhong (College of chemistry and Chemical Engineering, Guangxi University) ;
  • Tang, Yanxia (College of chemistry and Chemical Engineering, Guangxi University) ;
  • Luo, Yan (Guangxi Zhuang Autonomous Region Center for Analysis and Test Research) ;
  • Liu, Liheng (College of chemistry and Chemical Engineering, Guangxi University)
  • 투고 : 2018.02.21
  • 심사 : 2021.04.01
  • 발행 : 2021.03.25
⟨ 이전 논문 다음 논문 ⟩

초록

This study aimed to prepare a W/O nonionic microemulsion system(MEs) consisting of OP-4[polyoxyethylene(4) nonylphenol], OP-7[polyoxyethylene(7) nonylphenol], 1-hexanol, D2EHPA, kerosene and HCl solution and applied to the extraction of La(III) from chloride aqueous solution within the polysulfone hollow fiber contactor (HFC),laboratory-scale experiments were carried out to investigate the recovery of La(III) using as-prepared microemulsion from the simulation wastewater containing La(III),Al(III) and Fe(III). The right weight ratio(Rs) of OP-4 to OP-7 was firstly confirmed through determination of the solubilization capacity of HCl solution(W0,HCl) in microemulsion, the effect of several factors such as the HCl concentration, temperature and effective extraction time on the extraction efficiency of La(III) was discussed. Results showed that the acceptable Rs was 4:6 to prepare the W/O MEs. The extraction yield of La(III) increased with the increasing of HCl concentration, temperature and effective extraction time and reaches to 97.3% while using five-stage modules. The recovery yield of La(III) from simulation La-bearing wastewater was 90.6%.

키워드

참고문헌

  1. Ahmad, A.L., Kusumastuti, A., Derek, C.J.C. and Ooi, B.S. (2011), "Emulsion liquid membrane for heavy metal removal: An overview on emulsion stabilization and destabilization", Chem. Eng. J., 171(3), 870-882. https://doi.org/10.1016/j.cej.2011.05.102.
  2. Ahmad, A.L., Buddin, M.M.H.S., Ooi, B.S. and Kusumastuti, A. (2016), "Cadmium removal from aqueous solution by emulsion liquid membrane (ELM): Influence of emulsion formulation on cadmium removal and emulsion swelling", Desalin. Water Treat., 57(58), 28274-28283. https://doi.org/10.1080/19443994.2016.1179674.
  3. Acharya, S., Mishra, S. and Misra, P.K. (2015), "Studies on extraction and separation of La(III) with DEHPA and PC88A in petrofin", Hydrometallurgy, 156(7), 12-16. https://doi.org/10.1016/j.hydromet.2015.05.005.
  4. Adya, V.C., Sengupta, A., Ansari, S. Mohapatra, P.K., Bhide, M.K. and Godbole, S.V. (2013), "Application of hollow fiber supported liquid membrane for the separation of americium from the analytical waste", J. Radioanal. Nucl. Chem., 295(2), 1023-1028. https://doi.org/10.1007/s10967-012-1921-9.
  5. Agarwal, S., Reis, M.T.A., Ismael, M.R.C. and Carvalho, J.M.R. (2015), "Extraction of Cu(II) with Acorga M5640 using hollow fibre liquid membrane", Chem. Papers, 69(5), 679-689. https://doi.org/10.1515/chempap-2015-0076.
  6. Alguacila, F.J., Garcia-Diaza, I., Lopeza, F. and Sastre, A.M. (2011), "Cobalt(II) membrane-extraction by DP-8R/Exxsol D100 using pseudo-emulsion based hollow fiber strip dispersion (PEHFSD) processing", Sep. Purif. Technol., 80(3), 467-472. https://doi.org/10.1016/j.seppur.2011.05.029.
  7. Anitha, M., Ambare, D.N., Singh, D.K., Singh, H. and Mohapatra, P.K. (2015), "Extraction of neodymium from nitric acid feed solutions using an emulsion liquid membrane containing TOPO and DNPPA a the carrier extractants", Chem. Eng. Res. Des., 98(6), 89-95. https://doi.org/10.1016/j.cherd.2015.04.011.
  8. Ansari, S.A., Kumari, N., Raut, D.R., Kandwal, P. and Mohapatra. P.K. (2016), "Comparative dispersion-free solvent extraction of Uranium(VI) and Thorium(IV) by TBP and dialkyl amides using a hollow fiber contactor", Sep. Purif. Technol., 159(8), 161-168. https://doi.org/10.1016/j.seppur.2016.01.004.
  9. Bieluszka, P., Zakrzewska, G., Chajduk, E. and Dudek, J. (2014), "Liquid-liquid extraction of Uranium(VI) in the system with a membrane contactor", J. Radioanal Nucl. Ch., 299(1), 611-619. https://doi.org/10.1007/s10967-013-2796-0.
  10. Biswas, S., Rupawate, V.H., Hareendran, K.N. and Roy, S.B. (2014), "Transport of U(VI) from sulphuric acid medium across supported liquid membrane (SLM) containing di-(2-ethylhexyl) phosphoric acid (D2EHPA)/n-dodecane as a carrier", J. Radioanal Nucl. Ch., 299(3), 1199-1207. https://doi.org/10.1007/s10967-013-2872-5.
  11. Berrama, T., Pareau, D. and Durand, G. (2015), "Batch and dynamic study of lactic acid extraction using emulsion liquid membrane", Membr. Water Treat., 6(4), 277-292. https://doi.org/10.12989/mwt.2015.6.4.277.
  12. Chen, J.H., Mai, L.T.T. and Hsu, K.C. (2017), "Cr (VI) separation by PolyHIPE membrane immobilized with Aliquat 336 by solvent-nonsolvent method", Membr. Water Treat., 8(6), 575-590. https://doi.org/10.12989/mwt.2017.8.6.575.
  13. Chen, L., Wu, Y., Dong, H., Meng, M., Li, C., Yan, Y. and Chen, J. (2018), "An overview on membrane strategies for rare earths extraction and separation", Sep. Purif. Technol., 197(3),70-85. https://doi.org/10.1016/j.seppur.2017.12.053.
  14. Dantas, T.N.C., Neto, M.H.L. and Neto, A.A.D. (2002), "Gallium extraction by microemulsions", Talanta, 56(6), 1089-1097. https://doi.org/10.1016/S0039-9140(01)00643-9.
  15. Dantas, T.N.C., Neto, A.A.D. and Moura, M.C.P.A. (2003), "Heavy metals extraction by microemulsions", Water Res., 37(11), 2709-2717. https://doi.org/10.1016/S0043-1354(03)00072-1.
  16. Das, D., Varshini, C.J.S. and Das, N. (2014), "Recovery of lanthanum(III) from aqueous solution using biosorbents of plant and animal origin: Batch and column studies", Miner. Eng., 69(12), 40-56. https://doi.org/10.1016/j.mineng.2014.06.013.
  17. Gao, S., Shen, X.H., Chen, Q.D. and Gao, H.C. (2012), "Solvent extraction of thorium(IV) using W/O microemulsion", Sci. China, 55(9), 1712-1718. https://doi.org/10.1007/s11426-012-4686-7.
  18. Guell, R., Antico, E., Salvado, V. and Fontas, C. (2008), "Efficient hollow fiber supported liquid membrane system for the removal and preconcentration of Cr(VI) at trace levels", Sep. Purif. Tech., 62(2), 389-393. https://doi.org/10.1016/j.seppur.2008.02.015.
  19. Innocenzi, V., Ferella, F., Michelis, I.D. and Veglio, F. (2015), "Treatment of fluid catalytic cracking spent catalysts to recover lanthanum and cerium: Comparison between selective precipitation and solvent extraction", J. Ind. Eng. Chem., 24, 92-97. https://doi.org/10.1016/j.jiec.2014.09.014.
  20. Juang, R.S. and Huang, I.P. (2000), "Hollow-fiber membrane extraction of Copper(II) from aqueous ethylenediaminetetraacetic acid solutions with Aliquat 336", J. Ind. Eng. Chem., 39(5), 1409-1415. https://doi.org/10.1021/ie9905153.
  21. Jie, F.P., Bai, Z.S. and Yang, X.Y. (2018), "Study on extraction of cobalt(II) by sodium laurate/pentan-1-ol/ heptane/NaCl microemulsion system", J. Radioanal. Nucl. Ch., 315(3), 581-593. https://doi.org/10.1007/s10967-017-5685-0.
  22. Larson, K., Raghuraman, B. and Wiencek, J. (1994), "Mass-transfer model of mercury removal from water via microemulsion liquid membranes", J. Ind. Eng. Chem. Res., 33(6), 1612-1619. https://doi.org/10.1016/0140-6701(95)96151-8.
  23. Lou, Z.N., Guo, C.F., Feng, X.D., Zhang, S.Q., Xing, Z.Q., Shan, W.J. and Xiong, Y. (2015), "Selective extraction and separation of Re (VII) from Mo (VI) by TritonX-100/N235/iso-amyl alcohol/n-heptane/NaCl microemulsion system", Hydrometallurgy, 157(10), 199-206. https://doi.org/10.1016/j.hydromet.2015.08.017.
  24. Lou, Z.N., Cui, X.R., Zhang, S.Q., Feng, X.D., Shan, W.J. and Xiong, Y. (2016), "Extraction of Re(VII) from hydrochloric acid medium by N263/TBP/n-heptane/NaCl microemulsion", Hydrometallurgy, 165(10), 329-335. https://doi.org/10.1016/j.hydromet.2016.01.004.
  25. Lu, W.J., Lu, Y.M., Liu, F., Shang, K., Wang, W. and Yang, Y.Z. (2011) "Extraction of gold(III) from hydrochloric acid solutions by CTAB/n-heptane/iso-amyl alcohol/Na2SO3 microemulsion", J. Hazard. Mater., 186(2-3), 2166-2170. https://doi.org/10.1016/j.hydromet.2016.01.004.
  26. Muthuraman, G., Sathya, M., Soniya, M. and Elumalai, S. (2013), "Recovery of Levafix brilliant red E-4BA and Levafix brilliant red E-6BA from aqueous solution by supported liquid membrane", Membr. Water Treat., 4(4), 277-291. https://doi.org/10.12989/mwt.2013.4.4.277.
  27. Nataliya, M.M., Stanislav, Y.L. and Eugeny, V.Y. (2018), "Leaching of metals with microemulsions containing bis-(2-ethyhexyl) phosphoric acid or tributylphosphate", Hydrometallurgy, 175(1), 278-284. https://doi.org/10.1016/j.hydromet.2017.12.012.
  28. Nguyen, V.T., Lee, J.C., Kim., M.S., Kim, S.K., Chagnes, A. and Cote, G. (2017), "Sustainable extraction and separation of precious metals from hydrochloric media using novel ionic liquid-in-water microemulsion", Hydrometallurgy, 171(8), 344-354. https://doi.org/10.1016/j.hydromet.2017.06.003.
  29. Ortiz, I., Román, F.S. and Galán, B. (2001). "Kinetics of the recovery of Cd from highly concentrated aqueous solutions by non-dispersive solvent extraction", Chem. Eng. J., 81(1-3), 129-136. https://doi.org/10.1016/S1385-8947(00)00167-4.
  30. Pabbya, A.K., Swainb, B. and Sastre, A.M. (2017), "Recent advances in smart integrated membrane assisted Liquid extraction technology", Chem. Eng. Process., 120(10), 27-56. https://doi.org/10.1016/j.cep.2017.06.006.
  31. Panda, R., Jha, M.K., Hait, J., Kumar, G., Singh, R.J. and Yoo, K.K. (2016), "Extraction of lanthanum and Neodymium from leach liquor containing rare earth metals (REMs)", Hydrometallurgy, 165(10), 106-110. https://doi.org/10.1016/j.hydromet.2015.10.019.
  32. Shen, F., Smith, K.H., Cook, S., Kentish, S.E., Perera, J.M., Bowser, T. and Stevens, G.W. (2009), "Phenol recovery with tributyl phosphate in a hollow fiber membrane contactor: Experimental and model analysis", Sep. Purif. Technol., 69(1), 48-56. https://doi.org/10.1016/j.seppur.2009.06.024.
  33. Tong, Y., Han, L. and Yang, Y. (2012), "Microemulsion extraction of Gold(III) from hydrochloric acid medium using ionic liquid as surfactant and extractant", J. Ind. Eng. Chem. Res., 51(50) 16438-16443. https://doi.org/10.1021/ie301644t.
  34. Sribudda, D., Wannachod, T., Ramakul, P., Pancharoen, U. and Phatanasri, S. (2016), "Separation of mercury and arsenic from produced water via hollow fiber contactor: Kinetic and mass transfer analysis", Kor. J. Chem. Eng., 33(1), 197-206. https://doi.org/10.1007/s11814-015-0130-y.
  35. Yadav, K.K., Anitha, M., Singh, D.K. and Kain, V. (2018), "NdFeB magnet recycling: Dysprosium recovery by non-dispersive solvent extraction employing hollow fibre membrane contactor", Sep. Purif. Technol., 194(4), 265-271. https://doi.org/10.1016/j.seppur.2017.11.025.
  36. Yang, Y.Z., Zhu, T., Xia, C.B., Xin, X.M., Liu, L. and Liu, Z.Y. (2018), "Study on the extraction of cobalt and nickel from NH4SCN solution by Winsor II microemulsion system", Sep. Purif. Technol., 60(2), 174-179. https://doi.org/10.1016/j.seppur.2007.08.006.
  37. Zheng, Y., Fang, L.Y., Yan, Y., Lin, S.J., Liu, Z.H. and Yang, Y.Z. (2016), "Extrction of palladium(II) ionic liquid-based microemulsion system from chloride medium", Sep. Purif. Technol., 169(10), 289-295. https://doi.org/10.1016/j.seppur.2016.06.022.
  38. Zhu, T., Yang, Y.Z., Liu, Z.Y. and Xia, C.B. (2006), "Extraction of cobalt by CTMAB-pentanol-heptane-HCl Winsor II microemulsion systems", J. Radioanal. Nucl. Ch., 267(2), 401-406. https://doi.org/10.1007/s10967-006-0062-4.