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Preparation and Characterization of transparent electrode based on polymer/metal oxide composite via electrospinning

전기 방사를 이용한 고분자/금속산화물 복합소재 기반의 투명전극 제조 및 특성 분석

  • 강혜주 (대진대학교 에너지공학부) ;
  • 정현택 (대진대학교 에너지공학부)
  • Received : 2021.11.30
  • Accepted : 2021.12.23
  • Published : 2021.12.30

Abstract

We have confirmed that optimized transmittance and surface resistance by electrospinning time, also the fabricated transparent electrode composed of silver nanofiber with excellent electrical, optical and mechanical performances is showed applicability to next generation flexible displays such as solar cells, displays, and touch screens. → We have confirmed the optimized transmittance and surface resistance by electrospinning time Also the fabricated transparent electrode composed of silver nanofiber with excellent electrical, optical and mechanical performances showed applicability to next generation flexible displays such as solar cells, displays, and touch screens.

본 연구는 나노섬유를 제조하는데 빠르고 효과적인 전기방사법을 이용하여 PVA(Polyvinyl alcohol)와 AgNO3를 혼합하여 제조한 용액을 금속산화물 기반 나노 섬유로 이루어진 투명 전극을 제조하고 그 특성을 분석하였다. PVA/AgNO3 혼합 용액을 전기방사법을 이용하여 유리기판 위에 나노섬유 구조체 형태로 방사하여 250 ℃에서 2 시간 동안 열처리 과정을 통해 전기 전도성이 향상된 은나노 섬유 기반 투명 전극을 제조하였다. 제조된 투명전극은 four-point probe 장비를 이용하여 전기적 특성을 분석하였으며, UV - Vis spectrophotometer 를 이용하여 제조된 투명전극의 투과도를 확인하였다. 또한, Scanning Electron Microscopy (SEM)과 Energy Dispersive Spectrometer(EDS)를 통해 은 나노 섬유의 표면 특성과 성분을 확인하였다. 이러한 분석들을 통해, 전기 방사 시간에 따른 면 저항과 투과도의 최적화된 조건을 확인할 수 있었으며, 은 나노 섬유로 이루어진 투명 전극은 전기적, 광학적, 기계적 특성이 우수하여 태양전지, 디스플레이, 터치스크린과 같은 차세대 유연 디스플레이에 적용 가능성을 보여주었다.

Keywords

References

  1. J. Y. Hyeon, J. M. Choi, Y. S. Park, J. H. Kang, J. H. Sok, "Characteristics of Electrospun Ag Nanofibers for Transparent Electrodes", Journal of the Korean Vacuum Society, Vol 22. Issue 3, pp. 156-161, (2013) https://doi.org/10.5757/JKVS.2013.22.3.156
  2. M. H. Chung, S. Y. Kim, D. H. Yoo, J. H. Kim, "Materials and Characteristics of Emerging Transparent Electrodes", Applied Chemistry for Engineering, Vol 25. No. 3. pp. 242-248, (2014) https://doi.org/10.14478/ACE.2014.1013
  3. D. S. Hecht, L. Hu, G. Irvin, "Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures", Advanced Materials, Vol 23, No 13, pp. 1482-1513 (2011) https://doi.org/10.1002/adma.201003188
  4. Y. B. Shin, Y. H. Ju, J. W. Kim, "Technical Trends of Metal Nanowire-Based Electrode", Journal of the Microelectronics and Packaging Society, Vol. 26, No.4, pp. 15 - 22, (2019)
  5. M. Marus, A. Hubarevich, R. Lim, H. Huang, A. Smirnov, H. Wang, W. Fan, and X. Sun, "Effect of silver nanowire length in a broad range on optical and electrical properties as a transparent conductive film," Opt. Mater, Vol 7, No. 3, pp. 1105-1112 (2017) https://doi.org/10.1364/OME.7.001105
  6. Y. Sun, Y. Xia, "Large-Scale Synthesis of Uniform Silver Nanowires Through a Soft, Self-Seeding, Polyol Process", Advanced Materials, Vol 14, No. 11, pp. 833-837 (2002) https://doi.org/10.1002/1521-4095(20020605)14:11<833::AID-ADMA833>3.0.CO;2-K
  7. C. H. Liu, X. Yu, "Silver nanowire-based transparent, flexible, and conductive thin film", Nanoscale Res Lett, Vol 6, No. 1, p. 75 (2011) https://doi.org/10.1186/1556-276x-6-75
  8. J. V. Groep, P. Spinelli, A. Polman, "Transparent Conducting Silver Nanowire Networks", Nano Lett, Vol 12, No. 6, pp. 3138-3144 (2012) https://doi.org/10.1021/nl301045a
  9. R. Gopal, S. Kaur, Z. Ma, C. Chan, S. Ramakrishna, T. Matsuura, J. Mem, "Electrospun nanofibrous filtration membrane", Journal of Membrane Science, Vol. 281, No 1-2, pp. 581-586 (2006) https://doi.org/10.1016/j.memsci.2006.04.026
  10. S. J. Choi, L. Persano, A. Camposeo, J. S. Jang, W. T. Koo, S. J. Kim, H. J. Cho, I. D. Kim, D. Pisignano, "Electrospun Nanostructures for High Performance Chemiresistive and Optical Sensors", Macromolecular Materials and Engineering, Vol. 302, No. 8, 1600569 (2017) https://doi.org/10.1002/mame.201600569
  11. J. W. Jung, C. L. Lee, S. Yu, I. D. Kim, "Electrospun nanofibers as a platform for advanced secondary batteries: a comprehensive review", Vol. 4, No. 3, pp. 703-750 (2016) https://doi.org/10.1039/C5TA06844D
  12. K. R. Yoon, J. W. Jung, I. D. Kim, "Recent Progress in 1D Air Electrode Nanomaterials for Enhancing the Performance of Nonaqueous Lithium-Oxygen Batteries", ChemNanoMat, Vol. 2, No. 7, pp. 616-634 (2016) https://doi.org/10.1002/cnma.201600137
  13. H. S. Ryu, J. S. Park, "Effects of Electrospinning Parameters on the Fiber Formation and Application", Transactions of the Korean hydrogen and new energy, Vol 29, No. 1, pp. 71-80, (2018)
  14. C. S. Ki, D. H. Baek, K. D. Gang, K. H. Lee, I. C. Um, Y. H. Park, "Characterization of gelatin nanofiber prepared from gelatin-formic acid solution", Polymer, Vol. 46, No. 14, pp. 5094-5102, (2005) https://doi.org/10.1016/j.polymer.2005.04.040
  15. J.-Y. Hyeon, J.-M. Choi, Y.-S. Park, J. Kang, and J. Sok, "Characteristics of Electrospun Ag Nanofibers for Transparent Electrodes," Journal of the Korean Vacuum Society, Vol. 22, No. 3, pp. 156-161, (2013) https://doi.org/10.5757/JKVS.2013.22.3.156
  16. H. Wu, L. Hu, M.W. Rowell, D. Kong, J.J. Cha, J.R. McDonough, J. Zhu, Y. Yang, M.D. McGehee, Y. Cui, "Electrospun Metal Nanofiber Webs as High-Performance Transparent Electrode", Nano Lett, Vol. 10, No. 10, pp. 4242-4248, (2010) https://doi.org/10.1021/nl102725k