DOI QR코드

DOI QR Code

Room Temperature Hydrogen Gas Sensor using Pd/Carbon Nanotubes Buckypaper

팔라듐/탄소나노튜브 버키페이퍼를 이용한 상온감지 수소가스 센서

  • Han, Maeum (School of Electronic and Electrical Engineering, Kyungpook National University) ;
  • Kim, Jae Keon (Department of Sensor and Display Engineering, Graduate School, Kyunpook National University) ;
  • Kim, Yeongsam (School of Electronic and Electrical Engineering, Kyungpook National University) ;
  • Jung, Dong Geon (Safety-System R&D Group, Korea Institute of Industrial Technology (KITECH)) ;
  • Kong, Seong Ho (School of Electronic and Electrical Engineering, Kyungpook National University) ;
  • Jung, Daewoong (Safety-System R&D Group, Korea Institute of Industrial Technology (KITECH))
  • 한마음 (경북대학교 전자전기공학부) ;
  • 김재건 (경북대학교센서및디스플레이공학과) ;
  • 김영삼 (경북대학교 전자전기공학부) ;
  • 정동건 (한국생산기술연구원 안전시스템연구그룹) ;
  • 공성호 (경북대학교 전자전기공학부) ;
  • 정대웅 (한국생산기술연구원 안전시스템연구그룹)
  • Received : 2020.10.20
  • Accepted : 2020.11.25
  • Published : 2020.11.30

Abstract

In this paper, we report the sensing performance of H2 gas sensors composed of Pd/carbon nanotube (CNT) buckypaper at room temperature. The CNT buckypaper was made using a simple filtration process and subsequently deposited with Pd as the sensing material. The sensitivity of the sensor increased with respect to the gas concentration. To investigate the effect of Pd thickness, Pd layers of different thickness were deposited on the buckypaper, and the response of the sensor was evaluated. The proposed sensor exhibits excellent sensing properties with optimized Pd thickness at room temperature (25℃). Pd nanoparticles significantly impact the sensitivity and selectivity of the sensor because of the spillover effect. In addition, the sensor is highly suitable for bendable and wearable devices owing to its structural flexibility.

Keywords

References

  1. J. S. Noh, J. M. Lee, and W. Lee, Low-dimensional palladium nanostructures for fast and reliable hydrogen gas detection, Sensors, Vol. 11, pp. 825-851, 2011. https://doi.org/10.3390/s110100825
  2. R. Chen, X. Ruan, W. Liu, and C. Stefanini, "A reliable and fast hydrogen gas leakage detector based on irreversible cracking of decorated palladium nanolayer upon aligned polymer fibers, Int. J. Hydrog. Energy, Vol. 40, pp. 746-751, 2015. https://doi.org/10.1016/j.ijhydene.2014.11.026
  3. S. H. Lim, B. Radha, J. Y. Chan, M. S. M. Saifullah, G.U. Kulkarni, and G.W. Ho, "Flexible palladium-based H2 sensor with fast response and low leakage detection by nanoimprint lithography, ACS Appl. Mater. Interfaces, Vol. 5, pp. 7274-7281, 2013. https://doi.org/10.1021/am401624r
  4. D. Sett and D. Basak, "Highly enhanced H2 gas sensing characteristics of Co:ZnO nanorods and its mechanism, Sens. Actuators B, Vol. 243, pp. 475-483, 2017. https://doi.org/10.1016/j.snb.2016.11.163
  5. A. Gupta, S. S. Pandey, M. Nayak, A. Maity, S. B. Majumder, and S. Bhattacharya, "Hydrogen sensing based on nanoporous silica-embedded ultra dense ZnO nanobundles, RSC Adv., Vol. 4, pp. 7476-7482, 2014. https://doi.org/10.1039/c3ra45316b
  6. N. S. A. Eom, H. B. Cho, Y. Song, W. Lee, T. Sekino, and Y. H. Choa, "Room-temperature H2 gas sensing characterization of graphene-doped porous silicon via a facile solution dropping method, Sensors, Vol. 17, No. 12, pp. 2750(1)-2750(7), 2017. https://doi.org/10.3390/s17122750
  7. Y. Seekaew, A. Wisitsoraat, D. Phokharatkul and C. Wongchoosuk, Room temperature toluene gas sensor based on TiO2 nanoparticles decorated 3D graphene-carbon nanotube nanostructures, Sens. Actuators B, Vol. 279, pp. 69-78, 2019. https://doi.org/10.1016/j.snb.2018.09.095
  8. D. Jung and M. Han and G. S. Lee, Gas sensor using a multi-walled carbon nanotube sheet to detect hydrogen molecules, Sens. Actuators, Vol. 211, pp. 51-54, 2014. https://doi.org/10.1016/j.sna.2014.03.005
  9. R. Afrin and N.A. Shah, "Room temperature gas sensors based on carboxyl and thiol functionalized carbon nanotubes buckypapers, Diam. Relat. Mater., Vol. 60, pp. 42-49, 2015. https://doi.org/10.1016/j.diamond.2015.10.010
  10. J. DeGraff, R. Liang, M. Q. Le, J. Capsal, F. Ganet, and P. Cottinet, "Printable low-cost and flexible carbon nanotube buckypaper motion sensors, Mater. Des,, Vol. 133, pp. 47-53, 2017. https://doi.org/10.1016/j.matdes.2017.07.048
  11. J. Sippel-Oakley, H. Wang, B.S. Kang, S. Wu, F. Ren, A. G. Rinzler, and S. J. Pearton, "Carbon nanotube films for room temperature hydrogen sensing, Nanotechnology, Vol. 16, pp. 2218-2221, 2005. https://doi.org/10.1088/0957-4484/16/10/040
  12. A. Katoch, S.W. Choi, H.W. Kim, and S. S. Kim, "Highly sensitive and selective H2 sensing by ZnO nanofibers and the underlying sensing mechanism, J. Hazard. Mater., Vol. 286, pp. 229-235, 2015. https://doi.org/10.1016/j.jhazmat.2014.12.007
  13. S. Majumdar, P. Nag, and P. S. Devi, "Enhanced performance of CNT/SnO2 thick film gas sensors towards hydrogen, Mater. Chem. Phys., Vol. 147, pp. 79-85, 2014. https://doi.org/10.1016/j.matchemphys.2014.04.009
  14. T. C. Lin and B. R. Huang, "Palladium nanoparticles modified carbon nanotube/nickel composite rods (Pd/CNT/Ni) for hydrogen sensing, Sens. Actuators B, Vol. 162, pp. 108-113, 2012. https://doi.org/10.1016/j.snb.2011.12.044
  15. S. C. Kang, J. S. Im, and Y. Lee, "Hydrogen sensing property of porous carbon nanofibers by controlling pore structure and depositing Pt catalyst", Appl. Chem. Eng., Vol. 22, No. 3, pp. 243-248, 2011.
  16. T. Y. Chung, C. S. Tsao, H. P. Tseng, C. H. Chen, and M. S. Yu, "Effects of oxygen functional groups on the enhancement of the hydrogen spillover of Pd-doped activated carbon", J. Colloid Interface Sci., Vol. 441, pp. 98-105, 2015. https://doi.org/10.1016/j.jcis.2014.10.062
  17. E. H. Espinosa, R. Lonescu, B. Chambon, C. Sotter, E. Bittencourt, C. A. Felten, J. Pireaux, X. Correig, and E. Llobet, "Hybrid metal oxide and multiwall carbon nanotube films for low temperature gas sensing", Sens. Actuator B, Vol. 207, pp. 137-142, 2007.
  18. C. Ndaya, N. Javahiraly, and A. Brioude, "Recent advances in palladium nanoparticles-based hydrogen sensors for leak detection", Sensors., Vol. 19, pp. 4478(1)- 4478(41), 2019.
  19. M. Chung, D. Kim, D. Seo, T. Kim, H. Im, H. Lee, J. Yoo, S. Hong, T. Kang, and Y. Kim, "Flexible hydrogen sensors using graphene with palladium nanoparticle decoration", Sens. Actuator B, Vol. 169, pp. 387-392, 2012. https://doi.org/10.1016/j.snb.2012.05.031