Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Electrocaloric Effect in Emerging Fluorite-Structure Ferroelectrics

새로운 플루오라이트 구조 강유전체의 Electrocaloric Effect

  • Yang, Kun (School of Materials Science and Engineering, Pusan National University) ;
  • Park, Ju Yong (School of Materials Science and Engineering, Pusan National University) ;
  • Lee, Dong Hyun (School of Materials Science and Engineering, Pusan National University) ;
  • Park, Min Hyuk (School of Materials Science and Engineering, Pusan National University)
  • 양건 (부산대학교 재료공학부) ;
  • 박주용 (부산대학교 재료공학부) ;
  • 이동현 (부산대학교 재료공학부) ;
  • 박민혁 (부산대학교 재료공학부)
  • Received : 2020.07.27
  • Accepted : 2020.08.21
  • Published : 2020.09.27
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Abstract

The electrocaloric effect can be observed in pyroelectric materials based on conversion between electrical and thermal energy, and can be utilized for the future environment-friendly refrigeration technology. Especially, a strong electrocaloric effect is expected in materials in which field-induced phase transition can be achieved. Emerging fluorite-structure ferroelectrics such as doped hafnia and zirconia, first discovered in 2011, are considered the most promising materials for next-generation semiconductor devices. Besides application of fluorite-structure ferroelectrics for semiconductor devices based on their scalability and CMOS-compatibility, field-induced phase transition has been suggested as another interesting phenomenon for various energy-related applications such as solid-state cooling with electrocaloric effect as well as energy conversion/storage and IR/piezoelectric sensors. Especially, their giant electrocaloric effect is considered promising for solid-state-cooling. However, the electrocaloric effect of fluorite-structure oxides based on field-induced phase transition has not been reviewed to date. In this review, therefore, the electrocaloric effect accompanied by field-induced phase transition in fluorite-structure ferroelectrics is comprehensively reviewed from fundamentals to potential applications.

Keywords

References

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