Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
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Fast and Soft Functionalization of Carbon Nanotube with -SO3H, -COOH, -OH Groups for Catalytic Hydrolysis of Cellulose to Glucose

  • Lusha, Qin (School of Materials Science and Engineering, Pusan National University) ;
  • Lee, Sungho (School of Materials Science and Engineering, Pusan National University) ;
  • Li, Oi Lun (School of Materials Science and Engineering, Pusan National University)
  • Received : 2020.05.07
  • Accepted : 2020.06.18
  • Published : 2020.06.30
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Abstract

Herein, sulfonated carbon nanotubes (CNT) have been prepared in dilute sulfuric acid (H2SO4) via a novel sulfonation approach based on gas-liquid interfacial plasma (GLIP) at room temperature. The sulfonic acid groups and total acid groups densities of CNT after GLIP treatment in 2 M H2SO4 for 45 min can reach to 0.53 mmol/g and 3.64 mmol/g, which is higher than that of sulfonated CNT prepared under 0.5 M / 1 M H2SO4. The plasma sulfonated CNT has been applied as catalysts for the conversion of microcrystalline cellulose to glucose. The effect of hydrolysis temperature and hydrolysis time on the conversion rate and product distribution have been discussed. It demonstrates that the total conversion rate of cellulose increasing with hydrolysis temperature and hydrolysis time. Furthermore, the GLIP sulfonated CNT prepared in 2 M H2SO4 for 45 min has shown high catalytic stability of 85.73 % after three cycle use.

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References

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