청정기술 (Clean Technology)

  • 제26권2호
  • /
  • Pages.116-121
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  • 2020
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  • 1598-9712(pISSN)
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  • 2288-0690(eISSN)
한국청정기술학회 (The Korean Society of Clean Technology)
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폐 전지로부터 재활용 과정을 통한 란타넘, 네오디뮴 회수에 관한 연구

A Study on the Recovery of Lantanum and Neodymium from Waste Battery Through the Recycling Process

  • 투고 : 2020.06.09
  • 심사 : 2020.06.24
  • 발행 : 2020.06.30
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초록

본 연구에서는 유가금속 회수를 한 전기차 폐배터리 부산물의 재활용에 관하여 연구하였다. 폐배터리 부산물에는 희토류들이 남아있으나, 부산물의 형태로는 소재로서의 가치가 없기에 정제과정을 거쳐 희토류 산화물로 회수하였다. 희토류침전분말 형태의 부산물을 30% 수산화나트륨을 이용하여 가공이 편한 수산화물로 변환한 뒤, 옥살산의 용해도 차이를 이용하여 남아 있는 불순물을 정제한 뒤, D2EHPA (Di-(2-ethylhexyl) phosphoric acid)를 사용하여 이트륨을 분리하였다. 과망가니즈산 칼륨을 이용하여 세륨을 분리 후, PC88A (2-ethylhexylphosphonic acid mono-2-ethylhexyl ester)를 사용하여 란타넘과 네오디뮴을 분리하였다. 그 후 800 ℃의 온도에서 소성하여 란타넘, 네오디뮴 산화물로 재생하는 방법을 확인하였다.

In this paper, the recycling of waste Ni-MH battery by-products for electric vehicle is studied. Although rare earths elements still exist in waste Ni-MH battery by-products, they are not valuable as materials in the form of by-products (such as an insoluble substance). This study investigates the recovering of rare earth oxide for solvent extraction A/O ratio, substitution reaction, and reaction temperature, and scrubbing of the rare earth elements for high purity separation. The by-product (in the form of rare earth elements insoluble powder) is converted into hydroxide form using 30% sodium hydroxide solution. The remaining impurities are purified using the difference in solubility of oxalic acid. Subsequently, Yttrium is isolated by means of D2EHPA (Di-[2-ethylhexyl] phosphoric acid). After cerium is separated using potassium permanganate, lanthanum and neodymium are separated using PC88A (2-ethylhexylphosphonic acid mono-2-ethylhexyl ester) and it is calcinated at a temperature of 800 ℃. As a result of the physical and chemical measurement of the calcined lanthanum and neodymium powder, it is confirmed that the powder is a microsized porous powder in an oxide form of 99.9% or more. Rare earth oxides are recovered from Ni-MH battery by-products through two solvent extraction processes and one oxidation process. This study has regenerated lanthanum and neodymium oxide as a useful material.

키워드

참고문헌

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