DOI QR코드

DOI QR Code

Evaluation of CO2 desorption efficiency of scrubber absorption system in Liquor Plant

주류공정 내 흡수시스템 CO2 탈리 효율 평가

  • 박일건 ((주)평화엔지니어링 연구원) ;
  • 박형준 ((주)평화엔지니어링 연구원) ;
  • 이준형 ((주)평화엔지니어링 연구원) ;
  • 김흥래 ((주)평화엔지니어링 연구원) ;
  • 이주열 ((주)애니텍 기술연구소)
  • Received : 2020.03.09
  • Accepted : 2020.04.28
  • Published : 2020.04.30

Abstract

In this study, amino acid salt absorbents were applied to remove and capture high concentrations of CO2 in liquor factories and regeneration performance was confirmed. In order to evaluate the effective treatment of the desorption process, two methods(Hot plate and Steam) were compared at the laboratory scale. As a result, hot plate and Steam. Hot plate methods regeneration efficiency was about 10% and Steam methods was about 60%. The Steam-Tower condition was evaluated by installing a 100㎥/min flow rate scrubber absorption system in the liquor factory. As a result, it was established that the absorbent flow rate was below 4L/min and the steam temperature was above 160℃. Finally regeneration performance was confirmed as 85.5%.

본 연구에서는 주류공장 내 고농도 CO2 제거 및 포집을 위해 L-alanine 흡수제를 적용하여 CO2 흡수, 탈리 효율을 평가 후 재생 성능을 확인하였다. 탈리공정의 효율적인 처리를 평가하기 위해 실험실 규모에서 Hot plate, Steam 두가지 탈리 방법을 비교하였으며 Hot plate는 약 10%, Steam의 경우 약 60%의 재생효율을 확인하였다. 따라서 주류공장 내 100㎥/min 실증화 규모에 Steam-Tower 탈리공정을 적용하여 최적조건을 평가한 결과 탈리 유량 4L/min 이하, Steam 온도 160℃ 이상, 탈리효율 85.5%로 확인할 수 있었다.

Keywords

References

  1. E. C. Jeon, J. H. Sa, "Development of $CO_2$ Emission Fator by Fuel and $CO_2$ analysis at Sub-bituminous Fired Power Plant.", Journal of Environmental Health Sciences, Vol.36, No.2, pp. 128-135, (2010).
  2. G. H. Mun, "KCRC ISSUE REPORT: Necessity and prospect of CCS", Korea Carbon Capture and Sequestration R&D Center, Vol.01, (2015).
  3. J. A. Lim, Y. I. Yoon, S. C. Nam, S. K. Jeong, "Post-combustion $CO_2$ capture with potassium L-lysine", Journal of the Korea Academia-Industrial Cooperation Society, Vol.14, No.9, pp. 4627-4634, (2013). https://doi.org/10.5762/KAIS.2013.14.9.4627
  4. M. Claude, "Prospects for $CO_2$ capture and storage", Energy Technology Analysis, pp. 27-36 (2016).
  5. M. Mike, "$CO_2$ Earth", U.S. National Oceanic and Atmospheric Administration Earth System Research Laboratory, (2015).
  6. K. Topfer, "Working Group III: 2. Greenhouse gas emission mitigation scenarios and implications", Intergovernmental Panel on Climate Change, (2001).
  7. J. H. Wee, J. I. Kim, I. S. Song, B. Y. Song, K. S. Choi, "Reduction of carbon-dioxide emission applying carbon capture and storage (CCS) technology to power generation and industry sectors in Korea." Journal of Korean Society of Environmental Engineers, Vol.30, No.9, pp. 961-972, (2008).
  8. J. W. Doe, W. G. Lim, H. K. Kang, I. H. Hwang, J. H. Ha, B. K. Na, "Study on Characteristics of Change in Calorific Value and Carbon Emission Factor of Domestic Petroleum Energy Source" Journal of the Korean Applied Science and Technology, Vol.34, No.4, pp. 1046-1057, (2017).
  9. J. K. Lim, "UNFCCC National Communication", Korea Energy Economics Institute, (2003).
  10. J. H. Ha, E. J. Jang, Y. C. Kwon, "A study on the performance evaluation and quality for power bio-fuel oil" Journal of the Korean Applied Science and Technology, Vol.32, No.3, pp. 588-598, (2015).
  11. J. R. Shin, S. H. Moon, J. K. Kim, J. S. Choi, Y. H. Lim, B. H. Park, J. Y. Lee, "Study on development of Smart ventilation system using a adsorbent for the removal of $CO_2$" Journal of the Korean Applied Science and Technology, Vol.32, No.3, pp. 578-582, (2015).
  12. S. D. Park, "CCS; Carbon Dioxide Capture. & Storage", Physics and High Technology, pp. 19-23 (2009).
  13. I. G. Park, Y. S. Park. "Evaluation of $CO_2$ Removal Efficiency in Liquor plant by scrubber." Journal of the Korean Applied Science and Technology, Vol.34, No.4, pp. 986-994, (2017).
  14. S. Shen, Y. Yang, Y. Wang, S. Ren, J. Han, "$CO_2$ absorption into aqueous potassium salts of lysine and proline: Density, viscosity and solubility of $CO_2$", Fluid Phase Equilibria, Vol.399, pp. 40-49 (2015). https://doi.org/10.1016/j.fluid.2015.04.021
  15. J. A. Lim, D. H. Kim, Y. Yoon, S. K. Jeong, K. T. Park, S. C. Nam, "Absorption of $CO_2$ into Aqueous Potassium Salt Solutions of L-Alanine and L-Proline", Energy and fuels, Vol.26, No.6, pp. 3910-3918, (2012). https://doi.org/10.1021/ef300453e
  16. H. Bosch, G. F. Versteeg, W. P. M. Van Swaaij, "Gas-liquid mass transfer with parallel reversible reactions-I. Absorption of $CO_2$ into solutions of sterically hindered amines", Chemical engineering science, Vol.44, No.11, pp. 2723-2734, (1989). https://doi.org/10.1016/0009-2509(89)85215-7
  17. P. M. M. Blauwhoff, G. F. Versteeg, W. P. M. Van Swaaij, "A Study on The Reaction Between CO, and Alkanolamines in Aqueous Solutions", Chemical engineering science, Vol.39, No.2, pp. 207-225, (1984). https://doi.org/10.1016/0009-2509(84)80021-4
  18. J. E. Crooks, J. P. Donnellan, "Kinetics and Mechanism of the Reaction between Carbon Dioxide and Amines in Aqueous Solution", Journal of the Chemical Society, Perkin Transactions 2, Vol.2, No.4, pp. 331-333, (1989).
  19. G. F. Versteeg, J. A. M. Kuipers, F. P. H. Van Beckum, W. P. M. Van Swaaij, "Mass transfer with complex reversible chemical reactions-I. Single reversible chemical reaction", Chemical Engineering Science, Vol.44, No.10, pp. 2295-2310, (1989). https://doi.org/10.1016/0009-2509(89)85163-2
  20. U. R. Aronu, A. Hartono, K. A. Hoff, H. F. Svendsen, "Kinetics of carbon dioxide absoprtion into aqueous amino acid salt: potassium salt of sarcosine solution", Industrial & engineering chemistry research, Vol.50, No.18, pp. 10465-10475, (2011). https://doi.org/10.1021/ie200596y
  21. J. Ren, L. W, B.-G. Li, "Preparation and $CO_2$ sorption/desorption of N-(3-aminopropyl) aminoethyl tributylphosphonium amino acid salt ionic liquids supported into porous silica particles", Industrial & engineering chemistry research, Vol.51, No.23, pp. 7901-7909, (2012). https://doi.org/10.1021/ie2028415
  22. J. S. Choi, J. G. Kim, J. H. Lee, Y. J. Chu, J. Y. Lee, B. H. Park, "Study of continuous regeneration of carbon dioxide sorbent using amino acid salt", Journal of the Korean Applied Science and Technology, Vol.34, No.4, pp. 947-953, (2017).