한국분말재료학회지 (Journal of Powder Materials)

  • 제27권2호
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  • Pages.146-153
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  • 2020
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  • 2799-8525(pISSN)
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  • 2799-8681(eISSN)
한국분말재료학회 (*구 분말야금학회) (The Korean Powder Metallurgy & Materials Institute)
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이가 양이온 금속 친환 및 유기 첨가제를 이용하여 분무열분해법으로 제조된 Y2O3:Eu3+ 적색 형광체의 휘도 개선

Photoluminescence Enhancement of Y2O3:Eu3+ Red Phosphor Prepared by Spray Pyrolysis using Aliovalent Cation Substitution and Organic Additives

  • 민병호 (공주대학교 화학공학부) ;
  • 정경열 (공주대학교 화학공학부)
  • Min, Byeong Ho (Department of Chemical Engineering, Kongju National University) ;
  • Jung, Kyeong Youl (Department of Chemical Engineering, Kongju National University)
  • 투고 : 2020.04.13
  • 심사 : 2020.04.20
  • 발행 : 2020.04.28
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초록

The co-doping effect of aliovalent metal ions such as Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ on the photoluminescence of the Y2O3:Eu3+ red phosphor, prepared by spray pyrolysis, is analyzed. Mg2+ metal doping is found to be helpful for enhancing the luminescence of Y2O3:Eu3+. When comparing the luminescence intensity at the optimum doping level of each Mg2+ ion, the emission enhancement shows the order of Zn2+ ≈ Ba2+ > Ca2+ > Sr3+ > Mg2+. The highest emission occurs when doping approximately 1.3% Zn2+, which is approximately 127% of the luminescence intensity of pure Y2O3:Eu3+. The highest emission was about 127% of the luminescence intensity of pure Y2O3:Eu3+ when doping about 1.3% Zn2+. It is determined that the reason (Y, M)2O3:Eu3+ has improved luminescence compared to that of Y2O3:Eu3+ is because the crystallinity of the matrix is improved and the non-luminous defects are reduced, even though local lattice strain is formed by the doping of aliovalent metal. Further improvement of the luminescence is achieved while reducing the particle size by using Li2CO3 as a flux with organic additives.

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참고문헌

  1. Q. Tan, J. Li and X. Zeng: Crit. Rev. Env. Sci. Technol., 45 (2015) 749. https://doi.org/10.1080/10643389.2014.900240
  2. X. Hou, S. Zhou, Y. Li and W. Li: J. Alloys Compd., 494 (2010) 382. https://doi.org/10.1016/j.jallcom.2010.01.054
  3. T. Ji, H. Jiang and F. Chen: J. Alloys Compd., 502 (2010) 180. https://doi.org/10.1016/j.jallcom.2010.04.139
  4. H.-S. Kim and I.-K. Park: J. Phys. Chem. Solids, 117 (2018) 188. https://doi.org/10.1016/j.jpcs.2018.02.045
  5. A. Yousif, B. H. Abas, S. Som, N. J. Shivaramu and H. C. Swart: Mater. Res. Bull., 124 (2020) 110752. https://doi.org/10.1016/j.materresbull.2019.110752
  6. Q.-Q. Zhu, P.-F. Yang, Z.-Y. Wang and P.-C. Hu: J. Eur. Ceram. Soc., 40 (2020) 2426. https://doi.org/10.1016/j.jeurceramsoc.2020.02.005
  7. H. S. Yoo, W. B. Im, S. W. Kim, B. W. Kwon and D. Y. Jeon: J. Lumin., 130 (2010) 153. https://doi.org/10.1016/j.jlumin.2009.08.005
  8. W. Liu, Y. Wang, M. Zhang and Y. Zhang: Mater. Lett., 96 (2013) 42. https://doi.org/10.1016/j.matlet.2012.12.104
  9. L. Gao, G. Wang, H. Zhu, W. Zhou and G. Ou: Mater. Res. Bull., 70 (2015) 876. https://doi.org/10.1016/j.materresbull.2015.06.013
  10. K. Y. Jung, Y. C. Kang and Y.-K. Park: J. Ind. Eng. Chem., 14 (2008) 224. https://doi.org/10.1016/j.jiec.2007.09.011
  11. J. S. Cho, K. Y. Jung, Y. Y. Son and Y. C. Kang: RSC Adv., 4 (2014) 62965. https://doi.org/10.1039/C4RA09225B
  12. B. H. Min and K. Y. Jung: RSC Adv., 7 (2017) 44759. https://doi.org/10.1039/C7RA08620B
  13. B. H. Min and K. Y. Jung: RSC Adv., 9 (2019) 20002. https://doi.org/10.1039/C9RA03941D
  14. K. Park, H. Kim and D. A. Hakeen: Dyes Pigm., 136 (2017) 70. https://doi.org/10.1016/j.dyepig.2016.08.022
  15. L. Li and H.-Y. Wu: J. Alloys Compd., 702 (2017) 106. https://doi.org/10.1016/j.jallcom.2017.01.255
  16. K. Y. Jung, H. W. Lee, Y. C. Kang, S. B. Park and Y. S. Yang: Chem. Mater., 17 (2005) 2729. https://doi.org/10.1021/cm050074f
  17. Y. X. Pan and G. K. Liu: J. Lumin., 131 (2011) 465. https://doi.org/10.1016/j.jlumin.2010.11.014
  18. G. B. Nair, A. Kumar, H. C. Swart and S. J. Dhoble: Ceram. Int., 45 (2019) 21709. https://doi.org/10.1016/j.ceramint.2019.07.171
  19. X. Vendrell, D. Yadav, R. Raj and A. R. West: J. Eur. Ceram. Soc., 39 (2019) 1532. https://doi.org/10.1016/j.jeurceramsoc.2018.12.002
  20. L. Sun, C. Qian, C. Liao, X. Wang and C. Yan: Solid State Commun., 119 (2001) 393. https://doi.org/10.1016/S0038-1098(01)00247-2
  21. H. Liang, Y. Zheng, G. Chen, L. Wu, Z. Zhang and W. Cao: J. Alloys Compd., 509 (2011) 409. https://doi.org/10.1016/j.jallcom.2010.09.044
  22. R. Debnath and A. N. A. Ghosh: Chem. Phys. Lett., 27 (2007) 324.
  23. A. L. Patterson: Phys. Rev., 56 (1939) 978. https://doi.org/10.1103/PhysRev.56.978
  24. G. K. Williamson and W. H. Hall: Acta Metall., 1 (1953) 22. https://doi.org/10.1016/0001-6160(53)90006-6
  25. C. H. Lee, K. Y. Jung, J. G. Choi and Y. C. Kang: Mater Sci. Eng. B, 116 (2005) 59. https://doi.org/10.1016/j.mseb.2004.09.016