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습윤/건조 반복 작용이 고흡수율 폴리머를 함유한 시멘트계 재료의 자기치유에 미치는 영향

Effect of Cyclic Wetting-drying on Self-healing of Cementitious Materials Containing Superabsorbent Polymers

  • 홍근태 (중앙대학교 토목공학과) ;
  • 최성철 (중앙대학교 건설환경플랜트공학과)
  • Hong, Geuntae (Department of Civil and Environmental Engineering, Chung-Ang University) ;
  • Choi, Seongcheol (Department of Civil and Environmental Engineering, Chung-Ang University)
  • 투고 : 2020.02.13
  • 심사 : 2020.03.09
  • 발행 : 2020.03.30

초록

이 연구에서는 고흡수율 폴리머(SAPs)를 포함하는 시멘트계 재료의 자기치유에 대한 습윤/건조 반복 작용의 영향을 실험적으로 평가하였다. 매 주기마다 SAP 함량을 변수로 하는 시멘트 페이스트 시편을 균열 이후 1시간 동안 습윤 조건에 노출시키고(흡수율시험 및 투수시험 진행), 47시간 동안 건조 조건에 노출시켰다. 흡수율시험 결과 SAP 미혼입 시편, SAP 0.5%, SAP 1.0%, SAP 1.5% 혼입 시편의 균열을 통한 흡수율이 각각 1주기 대비 8주기 이후 22.9%, 36.8%, 42.8%, 46.3% 감소한 것으로 나타났다. 또한, 투수시험 결과 모든 시편의 균열을 통한 물 유출량은 습윤/건조 주기에 따라 점차 감소하였으며, 특히 SAP 함량이 증가할수록 유량 감소율은 증가하였다. 또한, X-ray CT 분석을 통해 균열 내 SAPs의 유입수에 의한 팽윤 거동이 확인되었다. 실험 결과는 SAPs가 유입수를 흡수하여 팽윤함에 따라 유효 균열폭이 감소될 수 있고, SAPs는 흡수한 물을 건조 조건에서 주변 균열부에 공급함에 따라 치유 생성물의 형성을 촉진시킬 수 있음을 나타낸다. 이 연구의 결과는 SAPs의 혼입이 균열의 수밀성을 증가시킴에 따라 시멘트계 재료의 자기치유 성능을 향상시킬 수 있음을 나타낸다.

In this study, the effect of cyclic wetting-drying on the self-healing of cementitious materials containing superabsorbent polymers (SAPs) were experimentally evaluated. In each cycle, cracked cement paste specimens containing various SAP dosages were exposed to wet conditions for 1 h, during which the capillary water absorption tests and water flow tests were conducted, and then exposed to dry conditions for 47 h. The capillary water absorption test results showed that the sorptivity values of the specimen without SAPs, SAP 0.5%, SAP 1.0%, and SAP 1.5% specimens were decreased by approximately 22.9%, 36.8%, 42.8%, and 46.3%, respectively, after 8 cycles. In addition, the water flow test results showed that the amount of water runoff through the cracks of all cracked specimens gradually decreased over wet/dry cycles, especially the reduction ratio of the amount of water runoff increased with increasing SAP dosage. Furthermore, the swelling behavior of SAPs in cracks by in gress water was con firmed via X-ray computed tomography (CT) analysis. These results indicate that the effective crack width can be reduced as SAPs absorb water and swell, while the water absorbed in SAPs can be released to crack surfaces under dry conditions, further promoting healing product formation. This study demon strates that the in corporation of SAPs can in crease the water tightness of cracks, thereby improving the self-healing efficiency of cementitious materials.

키워드

참고문헌

  1. ASTM C1585. (2004). Test Methods for Measurement of Rate of Absorption of Water by Hydraulic Cement Concretes, ASTM International, PA, USA.
  2. Hong, G.T., Choi, S.C. (2017). Rapid self-sealing of cracks in cementitious materials incorporating superabsorbent polymers, Construction and Building Materials, 143, 366-375. https://doi.org/10.1016/j.conbuildmat.2017.03.133
  3. Hong, G.T., Choi, S.C. (2018). Modeling rapid self-sealing of cracks in cementitious materials using superabsorbent polymers, Construction and Building Materials, 164, 570-578. https://doi.org/10.1016/j.conbuildmat.2018.01.017
  4. Hong, G.T., Song, C.W., Choi, S.C. (2020). Autogenous healing of early-age cracks in cementitious materials by superabsorbent polymers, Materials 13(3), 690. https://doi.org/10.3390/ma13030690
  5. Hong, G.T., Song, C.W., Park, J.S., Choi, S.C. (2019). Hysteretic behavior of rapid self-sealing of cracks in cementitious materials incorporating superabsorbent polymers, Construction and Building Materials, 195, 187-197. https://doi.org/10.1016/j.conbuildmat.2018.11.075
  6. Huang, H., Ye, G., Damidot, D. (2013). Characterization and quantification of self-healing behaviors of microcracks due to further hydration in cement paste, Cement and Concrete Research, 52, 71-81. https://doi.org/10.1016/j.cemconres.2013.05.003
  7. Jensen, O.M., Hansen, P.F. (2001). Water-entrained cement-based materials: I. Principles and theoretical background, Cement and Concrete Research, 31(4), 647-654. https://doi.org/10.1016/S0008-8846(01)00463-X
  8. Kim, D.J., Park, K.N. (2004). Swelling and mechanical properties of superporous hydrogels of poly(acrylamide-co-acrylic acid)/polyethylenimine interpenetrating polymer networks, Polymer, 45(1), 189-196. https://doi.org/10.1016/j.polymer.2003.10.047
  9. Mechtcherine, V., Reinhardt, H.W. (2012). Application of super absorbent polymers (SAP) in concrete construction, State-of-the-art Report of the RILEM TC 225-SAP, Springer, Heidelberg, Germany.
  10. Monnig, S., Lura, P. (2007). Superabsorbent polymers-an additive to increase the freeze-thaw resistance of high strength concrete, C.U. Grosse (Ed.), Advances in Construction Materials, Berlin Heidelberg, Berlin, 351-358.
  11. Peppas, N.A., Bures, P., Leobandung, W.S., Ichikawa, H. (2000). Hydrogels in pharmaceutical formulations, European Journal of Pharmaceutics and Biopharmaceutics, 50(1), 27-46. https://doi.org/10.1016/S0939-6411(00)00090-4
  12. Shim, Y.W., Hong, G.T., Choi, S.C. (2018). Autogenous Healing of Early-Age Cementitious Materials Incorporating Superabsorbent Polymers Exposed to Wet/Dry Cycles, Materials, 11(12), 2476. https://doi.org/10.3390/ma11122476
  13. Springenschmid, R. (1998). Prevention of Thermal Cracking in Concrete at Early Ages, E&FN Spon: New York, USA.