Nuclear Engineering and Technology

Korean Nuclear Society (한국원자력학회)
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Thermal transport study in actinide oxides with point defects

  • Resnick, Alex (Kennesaw State University, Department of Mechanical Engineering) ;
  • Mitchell, Katherine (Kennesaw State University, Department of Mechanical Engineering) ;
  • Park, Jungkyu (Kennesaw State University, Department of Mechanical Engineering) ;
  • Farfan, Eduardo B. (Kennesaw State University, Department of Mechanical Engineering) ;
  • Yee, Tien (Kennesaw State University, Department of Mechanical Engineering)
  • Received : 2018.10.25
  • Accepted : 2019.03.14
  • Published : 2019.06.25
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Abstract

We use a molecular dynamics simulation to explore thermal transport in oxide nuclear fuels with point defects. The effect of vacancy and substitutional defects on the thermal conductivity of plutonium dioxide and uranium dioxide is investigated. It is found that the thermal conductivities of these fuels are reduced significantly by the presence of small amount of vacancy defects; 0.1% oxygen vacancy reduces the thermal conductivity of plutonium dioxide by more than 10%. The missing of larger atoms has a more detrimental impact on the thermal conductivity of actinide oxides. In uranium dioxide, for example, 0.1% uranium vacancies decrease the thermal conductivity by 24.6% while the same concentration of oxygen vacancies decreases the thermal conductivity by 19.4%. However, uranium substitution has a minimal effect on the thermal conductivity; 1.0% uranium substitution decreases the thermal conductivity of plutonium dioxide only by 1.5%.

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References

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