DOI QR코드

DOI QR Code

Behavior characteristics of hydrogen and its isotope in molten salt of LiF-NaF-KF (FLiNaK)

  • Zeng, Youshi (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Liu, Wenguan (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Liu, Wei (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Qian, Yuan (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Qian, Nan (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Wu, Xiaoling (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Huang, Yu (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Wu, Shengwei (Shanghai Institute of Applied Physics, Chinese Academy of Sciences) ;
  • Wang, Guanghua (Shanghai Institute of Applied Physics, Chinese Academy of Sciences)
  • Received : 2018.03.22
  • Accepted : 2018.10.08
  • Published : 2019.04.25

Abstract

Experimental studies to investigate the behaviors of hydrogen in molten FLiNaK (LiF-NaF-KF) have been conducted at $500-700^{\circ}C$. On the basis of previous studies, the diffusivity and solubility of hydrogen in FLiNaK have been revised, and the expressions can be correlated to the following Arrhenius equations: $D_{H2}=1.62{\times}10^{-5}{\exp}(-48.20{\times}10^3/Rg{\cdot}T) m^2/s]$ and $S_{H2}=1.03{\times}10^{-4}{\exp}(-14.96{\times}10^3/Rg{\cdot}T) [mol-H_2/m^3/Pa]$, respectively. The behavior characteristics of deuterium in FLiNaK were studied and compared with the hydrogen behaviors in FLiNaK. The results showed the behaviors of deuterium were consistence with the behaviors of hydrogen in FLiNaK. The difference between hydrogen and deuterium has not been observed upon the experimental research of the behavior characteristics of hydrogen and deuterium in FLiNaK, which suggested the results obtained here might apply equally to the behavior characteristics of tritium in FLiNaK.

Keywords

References

  1. S.R. Sherman, DOE Hydrogen Program: NHI System Interface and Support System, 2005, 2005 DOE H2 Annual Review, Project ID#PD31.
  2. X.W. Lyu, X.B. Xia, Z.H. Zhang, J. Cai, C.Q. Chen, Analysis of tritium production in a 2 MWliquid-fueled molten salt experiment reactor and its environmental impact, Nucl. Sci. Tech. 27 (2016) 78-84, https://doi.org/10.1007/s41365-016-0100-z.
  3. R.B. Briggs, Tritium in molten-salt reactors, React. Technol. 14 (4) (1971-1972) 335-342.
  4. Satoshi Fukada, Akio Morisaki, Hydrogen permeability through a mixed molten salt of LiF, NaF, and KF (Flinak) as a heat-transfer fluid, J. Nucl. Mater. 358 (2) (2006) 235-242, https://doi.org/10.1016/j.jnucmat.2006.07.011.
  5. T. Ohshima, M. Kondo, M. Tanaka, et al., Hydrogen transport in molten salt FLiNaK measured by solid electrolyte sensors with Pd electrode, Fusion Eng. Des. 85 (10) (2010) 1841-1846, https://doi.org/10.1016/j.fusengdes.2010.06.008.
  6. J. Yagi, A. Sagara, T. Nagasaka, et al., Hydrogen inventory control for vanadium by Ti metal power mixing in molten salt FLiNaK, Fusion Eng. Des. 124 (2017) 748-751, https://doi.org/10.1016/j.fusengdes.2017.04.093.
  7. H. Katsuta, K. Furukawa, Diffusivity and solubility of hydrogen in molten fluoride mixture (LiF-NaF-KF), J. Nucl. Mater. 71 (2) (1978) 375-376, https://doi.org/10.1016/0022-3115(78)90439-7.
  8. Youshi Zeng, Lin Du, Li Pi, et al., Permeability of hydrogen in molten salt FLiNaK (LiF-NaF-KF), Nucl. Tech. 38 (2) (2015), 020603, https://doi.org/10.11889/j.02533219.2015.hjs.38.020603.
  9. Y.S. Zeng, S.W. Wu, Y. Qian, et al., Apparatus for determining permeability of hydrogen isotopes in molten-salt, Nucl. Sci. Tech. 25 (4) (2014), 040602, https://doi.org/10.13538/j.1001-8042/nst.25.040602.
  10. Youshi Zeng, Shengwei Wu, Yuan Qian, et al., Permeation and diffusion behaviors of hydrogen and deuterium in molten FLiNaK, Nucl. Tech. 41 (1) (2018), 010601, https://doi.org/10.11889/j.0253-3219.2018.hjs.41.010601.
  11. S.A. Steward, Review of Hydrogen Isotope Permeability through Materials, Lawrence Livermore National Laboratory, 1983. UCRL-53441.