Figure 1. Cure characteristics of silica compounds.
Figure 2. Stress-strain curves of silica compounds.
Figure 3. Tan δ curves as a function of temperature.
Table 1. Formulation for the ESBR Polymerization [gr]
Table 2. Formulation of the Compounds [phr]
Table 3. Mixing Procedure of the Silica Filled Compounds
Table 4. Characteristics of Raw Polymers
Table 5. Cure Characteristics of Silica Compounds
Table 6. TotaL Crosslink Density of Silica Compounds
Table 7. Mechanical Properties of Silica Compounds
Table 8. DIN Abrasion Loss of Silica Compounds
Table 9. Viscoelastic Properties of Silica Compounds
참고문헌
- A. Ciesielski, "An introduction to rubber technology", Ed. by A. Ciesielski, Rapra Publishing, United Kingdom, 1999.
- K. W. Lim, S. C. Ji, K. Y. Jung, T. J. Kim, and B. J. Lee, "Advanced Synthetic Technology for High Performance Energy Tire Tread Rubber", Elast. and Compos., 44, 3 (2009).
- J. H. Park, C. S. Lee, and H. H. Park, "A Study on the Characteristics of IR/CR Rubber Blends by Surface Treatment with Chlorine", J. of the Korean Chem. Society, 54, 6 (2010).
- K. Y. Jin, C. W. Nah, M. H. Lee, and K. U. Jeong, "Emerging Technologies of Elastomers", Elast. and Compos 43, 2 (2008).
- E. J. Blok, P. H. Sandstrom, W. Hsu, and A. F. Halasa, U.S. Patent No. 5,994,448 (1999).
- T. Fujimaki and N. Oshima, U.S. Patent No. 4,866,131 (1989).
- D. A. Joyner, J. W. Kang, T. Hashimoto, K. Yuto, and B. L. Stuck, U.S. Patent No. 5,272,203 (1993).
- D. Alexander, "High-performance handling for street or track", ed. by D. Alexander, p. 6-16, Motorbooks International, Minneapolis, 2013.
- B. Rampana, D. Tirelli, U. Kuhlmann, C. Cherif, C. Paul, R. A. Torun, and O. Diestel, U.S. Patent No. 8,640,753 (2014).
- B. L. Kim, U.S. Patent Application No. 14/750,914 (2017).
- R. Shishoo, "Textile advances in the automotive industry", ed. by R. Shinshoo, p. 3-17, CRC press, New York, 2008.
- A. Roberts, "Lubrication studies of smooth rubber contacts", The Physics of Tire Traction. ed. by F. H. Donald and L. B. Alan, p. 179-196, Springer, Boston, MA, 1974.
- K. Grosch, "The rolling resistance, wear and traction properties of tread compounds", Rubber Chem. Technol., 69, 3 (1996). https://doi.org/10.5254/1.3538383
- R. Peterson, C. Eckert, and C. Carr, "Tread compound effects in tire traction", The Physics of Tire Traction. ed. by F. H. Donald and L. B. Alan, p. 223-239, Springer, Boston, MA, 1974.
- K. W. Hwang, W. Kim, B. K. Ahn, H. S. Mun, E. H. Yu, D. H. Kim, G. C. Ryu, and W. H. Kim "Effect of surfactant on the physical properties and crosslink density of silica filled ESBR compounds and carbon black filled compounds" Elast. and Compos., 53, 2 (2018).
- W. Kim, B. K. Ahn, H. S. Mun, E. H. Yu, K. W. Hwang, and W. H. Kim, "Evaluation of BR Blending Methods for ESBR/silica Wet Masterbatch Compounds", Elast. and Compos., 52, 4 (2017).
- K. D. Pyo and C. C. Park, "A Study on the friction and antiabrasion properties of rubber blends for shoes outsole", Elast. and Compos., 46, 4 (2011).
- R. N. Kienle, E. S. Dizon, T. J. Brett, and C. F. Eckert, "Tread wear and wet skid resistance of butadiene-styrene elastomers and blends", Rubber Chem. and Technol., 44, 4 (1971).
- A. G. Veirh, "A review of important factors affecting treadwear", Rubber Chem. and Technol., 65, 3 (1992).
-
A. G. Veirh, "Tire treadwear: The joint influence of
$T_g$ , tread composition and environmental factors. A proposed 'two-mechanism' theory of treadwear", Polym. Testing 7, 3 (1987). - A. N. Gent and C. T. R. Pulford, "Mechanisms of rubber abrasion", J. of Appl. Polym. Sci., 28, 3 (1983).
- J. Zhao and G. N. Ghebremeskel, "A review of some of the factors affecting fracture and fatigue in SBR and BR vulcanizates", Rubber Chem. and Technol., 74, 3 (2001).
- A. J. Marzocca, S. Cerveny, and J. M. Mendez, "Some considerations concerning the dynamic mechanical properties of cured styrene-butadiene rubber/polybutadiene blends", Polym. Int., 49, 2 (2000).
- P. Corish, "Fundamental studies of rubber blends", Rubber Chem. Technol., 40, 2 (1967).
- N. Yoshimura and K. Fujimoto, "Structure of vulcanized and unvulcanized SBR/BR blends", Rubber Chem. Technol., 42, 4 (1969).
- I. A. Amraee, A. Katbab, and S. Aghafarajollah, "Qualitative and quantitative analysis of SBR/BR blends by thermogravimetric analysis", Rubber Chem. Technol., 69, 1 (1996).
- M. Inai, S. Aizawa, and M. Ito, "Phase control of BR/SBR blends by silica particles", e-J. of Soft Materials, 3 (2007).
- A. Diaz-Barrios and E. Paredes, "Studies of interaction in silica/styrene-butadiene copolymers", J. of Appl. Polym. Sci., 27, 11 (1982).
- D. Cai, K. Yusoh, and M. Song, "The mechanical properties and morphology of a graphite oxide nanoplatelet/polyurethane composite", Nanotechnol. 20, 8 (2009).
- A. J. Marzocca, S. Cerveny, and J. M. Mendez, "Some considerations concerning the dynamic mechanical properties of cured styrene-butadiene rubber/polybutadiene blends", Polym. Int., 49, 2 (2000).
- R. S. Clough and J. L. Koenig, "Solid-state carbon-13 NMR studies of vulcanized elastomers. VII. Sulfur-vulcanized cis-1, 4 polybutadiene at 75.5 MHz", Rubber Chem. and Technol., 62, 5 (1989).
- S. R. Smith and J. L. Koenig, "Solid-state carbon-13 NMR studies of vulcanized elastomers. IX. TMTD-vulcanized cis-1, 4-polybutadiene at 75.5 MHz", Rubber Chem. and Technol., 65, 1 (1992).
- M. A. Mansilla, A. R. Garraza, L. Silva, W. Salgueiro, C. Macchi, A. J. Marzocca, and A. Somoza, "Evolution of the free volume and glass transition temperature with the degree of cure of polybutadiene rubbers", Polym. Testing, 32, 4 (2013).
- M. Akiba and A. S. Hashim, "Vulcanization and crosslinking in elastomers", Progress in Polym. Sci., 22, 3 (1997).
- S. Mihara, "Reactive processing of silica-reinforced tire rubber: new insight into the time-and temperature-dependence of silica rubber interaction." (2009).
- Takino, H., et al. "Viscoelastic properties of elastomers and tire wet skid resistance", Rubber Chem. and Technol, 70, 4 (1997).
- Olabis, Olagoke, "Polymer-polymer miscibility", Elsevier, 2012.
- G. Severe and J. L. White, "Physical properties and blend miscibility of hydrogenated acrylonitrile-butadiene rubber", J. of Appl. Polym. Sci., 78, 8 (2000).
- M. Hara and J. A. Sauer, "Synergism in mechanical properties of polymer/polymer blends", J. of Macromolecular Sci., 38, 2 (1998).
- L. Nikiel, M. Gerspacher, H. Yang, and C. P. O'Farrell, "Filler dispersion, network density, and tire rolling resistance", Rubber Chem. Technol., 74, 2 (2001).
- K. H. Kim, J. Y. Lee, S. H. Lim, G. H. Kwag, H. J. Paik, and W. H. Kim, "Effect of the amounts of glycidyl methacrylate on the mechanical and dynamic properties of styrene-butadiene-glycidyl methacrylate terpolymer/silica composites", Compos. Inter., 23, 7 (2016).