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Synthesis of Mesoporous Zeolite Y and Its Application for Adsorptive Removal of Heavy Metals (Mn2+, Fe2+)

메조 세공 제올라이트 Y 합성 및 이를 이용한 중금속(Mn2+, Fe2+)의 흡착

  • Received : 2018.11.19
  • Accepted : 2018.12.26
  • Published : 2018.12.31

Abstract

We studied a simple approach for synthesis of mesoporous Y(M-Y) from commercial zeolite Y precursors by treating of NaOH with $CH_3(CH_2)_{15}N(Br)(CH_3)_3$ as template. The physicochemical properties of the mesoporous zeolites Y were then analyzed using XRD, nitrogen full-isotherms at 77 K, SEM and TEM. The nitrogen adsorption-desorption analysis showed that surface area and pore diameter of synthesized mesoporous zeolite Y(M-Y) were $1072m^2/g$ and ~3.3 nm, respectively. And M-Y was applied for the removal of $Mn^{2+}$ and $Fe^{2+}$ from aqueous solution. This material, which introduces mesoporosity with zeolite Y character, displayed a superior adsorption capacity than commercial zeolite Y when used as an adsorbent for the removal of $Mn^{2+}$ and $Fe^{2+}$.

Keywords

References

  1. Bianchini, E., Fabbri, D., Rombola, A.G., Torri, C., Guerrini, F., Pistocchi, R., Calabria R., Massoli, P. (2017). Pyrolysis Of Spirulina and Zeolite Cracking over Hzsm-5. an Analytical Investigation on The Chemical Route of Bio-Oil From Cultivation to Combustion, J. Anal. Appl. Pyrolysis., 126, pp. 230-238. https://doi.org/10.1016/j.jaap.2017.06.004
  2. Gu, J., Zhang, Z., Ding, L., Huang, K., Xue, N., Peng, L., Guo, X., Ding, W. (2017). Platinum Nanoparticles encapsulated in HZSM-5 Crystals as an Efficient Catalyst for Green Production of -Aminophenol, Catal. Commun., 97, pp. 98-101. https://doi.org/10.1016/j.catcom.2017.04.028
  3. Rutkowska, M., Piwowarska, Z., Micek, E., Chmielarz, L. (2015). Hierarchical Fe-, Cu- and Co-Beta Zeolites obtained by Mesotemplate-free method. Part I: Synthesis and Catalytic Activity in $N_2O$ Decomposition, Micro. Meso. Mater., 209, pp. 54-65. https://doi.org/10.1016/j.micromeso.2014.10.011
  4. Calabrese, L., Bonaccorsi, L., Freni, A., Proverbio, E. (2017). Synthesis of SAPO-34 Zeolite filled Macrocellular foams for Adsorption Heat Pump Applications: A Preliminary Study, Appl. Therm. Engineer., 124, pp. 1312-1318. https://doi.org/10.1016/j.applthermaleng.2017.06.121
  5. Perez-Ramirez, J., Kapteijn, F., Groen, J.C., Domenech, A., Mul, G., Moulijn, J.A. (2003). Steam-activated FeMFI Zeolites. Evolution of Iron Species and Activity in Direct $N_2O$ Decomposition, J. Catal., 214, pp. 33-45. https://doi.org/10.1016/S0021-9517(02)00021-0
  6. Ivanova, I. I., Knyazeva, E. E. (2013). Micro-Mesoporous Materials obtained by Zeolite Recrystallization: Synthesis, Characterization and Catalytic Application, Chem. Soc. Rev., 42 (9), pp. 3671-3688. https://doi.org/10.1039/C2CS35341E
  7. Wang, S., Dou, T., Li, Y., Zhang, Y., Li, X., Yan, Z. (2005). A Novel Method for the Preparation of MOR/MCM-41 Composite Molecular, Catal. Commun., 6, pp. 87-91. https://doi.org/10.1016/j.catcom.2004.11.005
  8. Konnov, S. V., Ivanova, I. I., Ponomareva, O. A., Zaikovskii, V. I. (2012). Hydroisomerization of n-alkanes over Pt-modified Micro/Mesoporous Materials obtained by Mordenite Recrystallization, Micro. Meso. Mater., 164, pp. 222-231. https://doi.org/10.1016/j.micromeso.2012.08.017
  9. Kasyanov, I. A., Maerle, A. A., Ivanova, I. I., Zaikovskii, V. I. (2014). Towards Understanding of the Mechanism of Stepwise Zeolite Recrystallization into Micro/Mesoporous Materials, J. Mater. Chem. A., 2, pp. 16978-16988. https://doi.org/10.1039/C4TA03681F
  10. Pak, S. E., Park, C. G., Kang, G. N., Kim, Y. H. (2018). Mesoporosity Development in Zeolite beta by using Desilication and CTAB Assembly for Removal of $Mn^{2+}$, Desalin Water Treat., 123, pp. 203-210. https://doi.org/10.5004/dwt.2018.22683
  11. Li, Y., Zhang, W., Wang, X., Zhang, Y., Dou, T., Xie, K. (2008). Synthesis, Characterization, and Catalytic Properties of a Hydrothermally Stable Beta/MCM-41 Composite from Well-Crystallized Zeolite Beta, J. Porous Mater., 15(2), pp. 133-138. https://doi.org/10.1007/s10934-007-9113-7
  12. Chal, R., Cacciaguerra, T., Donk, S., Gerardin, C. (2010). Pseudomorphic Synthesis of Mesoporous Zeolite Y Crystals, Chem. Commun., 46, pp. 7840-7842. https://doi.org/10.1039/c0cc02073g
  13. Paixao, V., Carvalho, A. P., Rocha, J., Fernandes, A., Martins, A. (2010). Modification of MOR by Desilication Treatments: Structural, Textural and Acidic Characterization, Micro. Meso. Mater., 131, pp. 350-357. https://doi.org/10.1016/j.micromeso.2010.01.013
  14. Kim, M. H., Cho, I. H., Choi S. O., Choo S. T. (2014). Zeolites: Their Features as Pressure Swing Adsorbents and $CO_2$ Adsorption Capacity, J. Environ. Sci. Int., 23(5), pp. 943-962. https://doi.org/10.5322/JESI.2014.5.943
  15. Khan, A. Y., Mazyck, D. W. (2009). Adsorption of Manganese(II) Ions by EDTA-treated Activated Carbons, Ads. Sci & Techno., 27(2), pp. 167-175. https://doi.org/10.1260/026361709789625289