Journal of Industrial and Engineering Chemistry

  • 제67권
  • /
  • Pages.99-108
  • /
  • 2018
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
한국공업화학회 (The Korean Society of Industrial and Engineering Chemistry)
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DOI QR코드

DOI QR Code

Thiadiazole-thione surfactants: Preparation, flotation performance and adsorption mechanism to malachite

  • Huang, Yaoguo (College of Chemistry and Chemical Engineering, Central South University) ;
  • Liu, Guangyi (College of Chemistry and Chemical Engineering, Central South University) ;
  • Liu, Jun (College of Chemistry and Chemical Engineering, Central South University) ;
  • Yang, Xianglin (College of Chemistry and Chemical Engineering, Central South University) ;
  • Zhang, Zhiyong (College of Chemistry and Chemical Engineering, Central South University)
  • 투고 : 2018.05.14
  • 심사 : 2018.06.22
  • 발행 : 2018.11.25
⟨ 이전 논문 다음 논문 ⟩

초록

In this paper, novel thiadiazole-thione surfactants including 5-heptyl-1,3,4-thiadiazole-2-thione (HpSDT), 5-phenyl-1,3,4-thiadiazole-2-thione (PSDT) and 5-(2-hydroxyphenyl)-1,3,4-thiadiazole-2-thione (HPhSDT) were synthesized and originally introduced as collectors in froth flotation. Microflotation tests showed that HpSDT exhibited better flotation response to malachite than PSDT and HPhSDT, as well as excellent flotation selectivity against quartz. The contact angle results inferred that the hydrophobization intensity of these collectors toward malachite was in the order as HpSDT> PSDT> HPhSDT. ${\zeta}$-potential recommended a chemisorption of HpSDT on malachite surfaces. FTIR deduced that cupric or cuprous atoms might bond with the S and N atoms of HpSDT to form a conjugated ring. XPS further gave an additional evidence that HpSDT-Cu(I) complexes were produced on malachite surfaces via combining surface Cu atoms with HpSDT's N and S atoms, with reducing surface Cu(II) to Cu (I). The tighter orientation arrangement on malachite and stronger hydrophobicity rendered HpSDT to possess better flotation affinity toward malachite than PSDT and HPhSDT.

키워드

과제정보

연구 과제 주관 기관 : National Natural Science Foundation of China

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