Journal of Industrial and Engineering Chemistry

  • Volume 68
  • /
  • Pages.129-139
  • /
  • 2018
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Significance of N-moieties in regulating the electrochemical properties of nano-porous graphene: Toward highly capacitive energy storage devices

  • Khan, Firoz (Smart Textile Convergence Research Group, Daegu Gyeongbuk Institute of Science and Technology (DGIST)) ;
  • Kim, Jae Hyun (Smart Textile Convergence Research Group, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
  • Received : 2018.04.11
  • Accepted : 2018.07.26
  • Published : 2018.12.25
⟨ Previous Next ⟩

Abstract

The effects of N doping concentration and dopant moieties on the electrochemical properties of nanoporous graphene and their dependence on annealing temperature are investigated. Four types of N moieties - amide, amine, graphitic-N, and oxidized-N - are obtained, which transformed into pyridinic-N and pyrrolic-N upon annealing. The diffusion coefficient (D') of the ions in the electrode is the maximum at $400^{\circ}C$ because of a high level of N doping, whereas the second highest D0 value is obtained at $700^{\circ}C$ owing to a high level of reduction and N doping. The highest specific capacitance is obtained for the sample annealed at $400^{\circ}C$.

Keywords

Acknowledgement

Supported by : Korea Institute of Energy Technology Evaluation and Planning, Ministry of Science, ICT and Future Planning

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