Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Effects of Backbone Chemical Structure on Characteristics of Supramolecular Polymers Based on Hydrogen Bonding

수소결합을 기반한 초분자형 고분자에서 주쇄의 화학구조에 따른 특성 연구

  • Jang, Soon Ho (Department of Organic and Nano Engineering, Hanyang University) ;
  • Lee, Junhaeng (Department of Information Communication, Materials, and Chemistry Convergence Technology, Soongsil University) ;
  • Chung, Jae Woo (Department of Information Communication, Materials, and Chemistry Convergence Technology, Soongsil University) ;
  • Kim, Seong Hun (Department of Organic and Nano Engineering, Hanyang University)
  • 장순호 (한양대학교 유기나노공학과) ;
  • 이준행 (숭실대학교 정보통신.소재융합학과) ;
  • 정재우 (숭실대학교 정보통신.소재융합학과) ;
  • 김성훈 (한양대학교 유기나노공학과)
  • Received : 2018.06.30
  • Accepted : 2018.08.07
  • Published : 2018.08.31
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Abstract

In this study, the effects of a backbone chemical structure on the characteristics of supramolecular polymers based on 2-ureido-4[1H]-pyrimidinone (UPy) moiety with quadruple hydrogen bonding were investigated. The supramolecular polymers were easily synthesized via a UPy moiety functionalized oligomer with a molar mass of approximately 3,000 g/mol. The oligomers selected to form the supramolecular polymers included polytetramethylene glycol (PTMG), polycaprolactone diol (PCL), and polycarbonate diol (PC). The characteristics of the UPy moiety functionalized oligomer are highly dependent on the mobility of the backbone and the existence of the UPy cluster, which is formed by stacking between adjacent UPy dimers. The PC-based supramolecular polymers yielded higher UPy stacked crystals (induced by the UPy cluster) than the PTMG and PCL-based supramolecular polymers.

Keywords

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