Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Structural Properties of ZnS Nanoparticles by Hydrothermal Synthesis Process Conditions and Optical Properties of Ceramic

수열합성 공정 변화에 따른 ZnS 나노분말의 구조 특성과 소결체의 광학적 특성

  • Yeo, Seo-Yeong (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Kwon, Tae-Hyeong (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Kim, Chang-Il (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Yun, Ji-Sun (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Jeong, Young-Hun (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Hong, Youn-Woo (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Cho, Jeong-Ho (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Paik, Jong-Hoo (Electronic Convergence Materials Division, Korea Institute of Ceramic Engineering & Technology)
  • 여서영 (한국세라믹기술원 전자융합소재본부) ;
  • 권태형 (한국세라믹기술원 전자융합소재본부) ;
  • 김창일 (한국세라믹기술원 전자융합소재본부) ;
  • 윤지선 (한국세라믹기술원 전자융합소재본부) ;
  • 정영훈 (한국세라믹기술원 전자융합소재본부) ;
  • 홍연우 (한국세라믹기술원 전자융합소재본부) ;
  • 조정호 (한국세라믹기술원 전자융합소재본부) ;
  • 백종후 (한국세라믹기술원 전자융합소재본부)
  • Received : 2018.02.01
  • Accepted : 2018.03.19
  • Published : 2018.09.01
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Abstract

In this paper, the ZnS nanoparticles were synthesized according to the process conditions of hydrothermal synthesis. When the molar ratio of Zn to S was 1:1.2, it was confirmed that it had a cubic single phase and a high crystal phase. After the molar ratio is fixed, hydrothermal synthesis was conducted at $180^{\circ}C$ for 24, 36, 72 and 96 h in order to confirm the structural change with the change of hydrothermal synthesis times. As the hydrothermal synthesis times increased, the particle size increased. The hydrothermal synthesized particle size for 72 h was considered to be suitable for sintering. The ZnS ceramic had a density of 99.7% and an excellent transmittance of ~70% in the long-wavelength region.

Keywords

References

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