한국지하수토양환경학회지:지하수토양환경 (Journal of Soil and Groundwater Environment)

  • 제23권4호
  • /
  • Pages.48-59
  • /
  • 2018
  • /
  • 1598-6438(pISSN)
  • /
  • 2287-8831(eISSN)
한국지하수토양환경학회 (Korean Society of Soil and Groundwater Environment)
권호 표지
DOI QR코드

DOI QR Code

오염원 인근 토양 중 베릴륨(Be), 코발트(Co), 탈륨(Tl), 바나듐(V)의 농도분포 및 오염영향 평가

Evaluation of the Concentration Distribution and the Contamination Influences for Beryllium, Cobalt, Thallium and Vanadium in Soil Around the Contaminated Sources

  • Lee, Hong-gil (National Institute of Environmental Research) ;
  • Noh, Hoe-Jung (National Institute of Environmental Research) ;
  • Yoon, Jeong Ki (National Institute of Environmental Research) ;
  • Lim, Jong-hwan (Industrial Materials Testing Support Team, FITI Testing & Research Institute) ;
  • Lim, Ga-Hee (National Institute of Environmental Research) ;
  • Kim, HyunKoo (National Institute of Environmental Research) ;
  • Kim, Ji-in (National Institute of Environmental Research)
  • 투고 : 2018.07.10
  • 심사 : 2018.08.20
  • 발행 : 2018.08.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Beryllium (Be), cobalt (Co), thallium (Tl) and vanadium (V) are candidates of 21 priority soil pollutants in Korea. The distribution of their concentration in soils from three contamination sources including industrial, roadside and mining areas was investigated. Concentrations of the metals were evaluated quantitatively using pollution indices and the fractionation of metals was conducted using modified SM&T (Standards Measurements and Testing programme) sequential extraction. Concentrations of the metals for all samples from industrial and roadside soils were within the range of natural background levels, while some of Be in soils from abandoned mines exceeded that the range. Enrichment Factor (EF) and Nemerow Integrated Pollution Index (NIPI) for Be, Co, Tl and V showed that there are effects or possibilities of anthropogenic activities. Pollution Load Index (PLI) analyses indicated all investigated sites needed further monitoring. The results of sequential extractions indicated mobile fractions (F1+F2) of Be, Tl and V were below 30% except some of Co in soil, which implies their low mobility to neighboring environment media. Variable tools like sequential extraction, comparison with background/actual concentration and pollution indices, as well as aqua regia extraction should be considered when evaluating Be, Co, Tl, V in soil.

키워드

참고문헌

  1. Agency for Toxic Substances and Disease Registry (ATSDR), 2002, Toxicological profile for beryllium, US Department of Health and Human Services, Public Health Service, Atlanta, GA.
  2. Agency for Toxic Substances and Disease Registry (ATSDR), 2004, Toxicological profile for cobalt, US Department of Health and Human Services, Public Health Service, Atlanta, GA.
  3. Agency for Toxic Substances and Disease Registry (ATSDR), 1992, Toxicological profile for thallium, US Department of Health and Human Services, Public Health Service, Atlanta, GA.
  4. Agency for Toxic Substances and Disease Registry (ATSDR), 2012, Toxicological profile for vanadium, US Department of Health and Human Services, Public Health Service, Atlanta, GA.
  5. Bacon, J.R. and Davidson, C.M., 2008, Is there a future for sequential chemical extraction?, The Analyst, 133(1), 25-46. https://doi.org/10.1039/B711896A
  6. Bo ym, M. and Rajmund, A., 2015, The study of cobalt leaching from soils, sewage sludges and composts using a one-step extraction, Ochrona Srodowiska i Zasobw Naturalnych, 26(1), 1-6.
  7. Buet-Menard, P. and Chesselet, R., 1979, Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter, Earth Planet. Sci. Lett., 42(3), 399-411. https://doi.org/10.1016/0012-821X(79)90049-9
  8. Canadian Council of Ministers of the Environment (CCME), Canadian environmental quality guidelines, http://ceqg-rcqe.ccme.ca/en/index.html
  9. Cappuyns, V. and Swennen, R., 2014, Release of vanadium from oxidized sediments: insights from different extraction and leaching procedures, Environ. Sci. Pollut. Res., 21(3), 2272-2282. https://doi.org/10.1007/s11356-013-2149-0
  10. Carlon, C., D'Alessandro, M., and Swartjes, F., 2007, Derivation methods of soil screening values in Europe, EUR 22805-EN, In: a review and evaluation of national procedures towards harmonisation, European Commission, Joint Research Centre, Ispra, Italy.
  11. Chemical Abstracts Service (CAS), http://support.cas.org
  12. Chen, J.L., Shi, Z., and Zhu, Y.W., 2007, Assessment and mapping of environmental quality in agricultural soils of Zhejiang Province, China, J. Environ. Sci., 19, 50-54. https://doi.org/10.1016/S1001-0742(07)60008-4
  13. Frantz, G. and Carlson, R.M., 1987, Effects of rubidium, cesium and thallium on interlayer potassium release from transvall vermiculite, Soil Sci. Soc. Am. J., 51(2), 305-308. https://doi.org/10.2136/sssaj1987.03615995005100020008x
  14. International Agency for Research on Cancer (IARC), IARC monographs on the evaluation of carcinogenic risks for humans, Vol. 1-121, List of classifications, http://monographs.iarc.fr/ENG/Classification/latest_classif.php
  15. ISO 11466, 1995, ISO 11466 International standard, Soil quality - Extraction of trace elements soluble in aqua regia.
  16. ISO 22036, 2008, ISO 22036 International standard, Soil quality - Determination of trace elements in extracts of soil by inductively coupled plasma - atomic emission spectrometry (ICPAES).
  17. Jiang, X., Lu, W.X., Zhao, H.Q., Yang, Q.C., and Yang, Z.P., 2014, Potential ecological risk assessment and prediction of soil heavy-metal pollution around coal gangue dump, Nat. Hazards Earth Syst. Sci., 14(6), 1599-1610. https://doi.org/10.5194/nhess-14-1599-2014
  18. Kabata-Pendias, A., 2010, Trace elements in soils and plants, CRC Press, Boca Raton, FL.
  19. Kim, K.H., 1977, Geologic and fluid inclusion studies of Chongyang tungsten ore deposits, South Korea, J. Kor. Inst. Mining Geol., 10(1), 1-18.
  20. Korea Institute of Geoscience and Mineral Resources (KIGAM), Geography information System, http://mgeo.kigam.re.kr
  21. Korea Ministry of Land, Infrastructure and Transport (MOLIT), Traffic monitoring system, http://www.road.re.kr
  22. Korean Ministry of Environment (KMOE), 2016, Korean standard test method for soil pollution.
  23. Lee, J.H., Kim, D.J., and Ahn, B.K., 2015, Distributions and concentrations of thallium in Korean soils determined by single and sequential extraction procedures, Bull. Environ. Contam. Toxicol., 94(6), 756-763. https://doi.org/10.1007/s00128-015-1533-5
  24. Marshall, C.P. and Fairbridge, R.W., 1999, Encyclopedia of geochemistry, Kluwer Academic Publishers, London, UK.
  25. McLaren, R.G., Lawson, D.M., and Swift, R.S., 1986, Sorption and desorption of cobalt by soils and soil components, Eur. J. Soil Sci., 37(3), 413-426. https://doi.org/10.1111/j.1365-2389.1986.tb00374.x
  26. McLemore, V.T., 2010, Beryllium resources in New Mexico and adjacent Areas (Open-file Report OF-533), New Mexico, USA.
  27. Medved, J., Kalis, M., Hagarova, I, Matus, P., Bujods, M., and Kubova, J., 2008, Thallium fractionation in polluted environmental samples using a modified BCR three-step sequential extraction procedure and its determination by electrothermal atomic absorption spectrometry, Chem. Pap., 62(2), 168-175.
  28. Ministry of Housing, Spatial Planning and the Environment (VROM), 2009, Dutch soil remediation circular 2009, p.16-19.
  29. National Institute of Environmental Research(NIER), 2007, A study for the selection of priority substances in soil - selecting method and applicabiliity.
  30. National Institute of Environmental Research (NIER), 2008, Assessment of soil contamination by new soil contaminants.
  31. National Institute of Environmental Research (NIER), 2009, Assessment of soil contamination by new soil contaminants.
  32. National Institute of Environmental Research (NIER), 2010, Assessment of soil contamination by new soil contaminants ('10).
  33. National Institute of Environmental Research (NIER), 2011, Assessment of soil contamination by new soil contaminants ('11).
  34. Pueyo, M., Mateu, J., Rigol, A., Vidal, M., Lopez-Sanchez, J.F., and Rauret, G., 2008, Use of the modified BCR three-step sequential extraction procedure for the study of trace element dynamics in contaminated soils, Environ. Pollut., 152(2), 330-341. https://doi.org/10.1016/j.envpol.2007.06.020
  35. Rauret, G., Lopez-Sanchez, J.F., Sahuquillo, A., Rubio, R., Davidson, C., Ure, A., and Quevauviller, P., 1999, Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials, J. Environ. Monit., 1(1), 57-61. https://doi.org/10.1039/a807854h
  36. Ray, G.E. and Webster, I.C.L., 1997, Skarns in British Columbia (Bulletin 101), Victoria, British Columbia, Canada, p.19-20.
  37. Teng, Y., Yang, J., Wang, J., and Song, L., 2011, Bioavailability of vanadium extracted by EDTA, HCl, HOAc, and $NaNO_{3}$ in topsoil in the Panzhihua urban park, located in Southwest China, Biol. Trace Elem. Res., 144, 1394-1404. https://doi.org/10.1007/s12011-011-9082-1
  38. Tiller, K.G., Honeysett, J.L., and Hallsworth, E.G., 1969, The isotopically exchangeable form of native and applied cobalt in soils, Aust. J. Soil Res., 7(1), 43-56. https://doi.org/10.1071/SR9690043
  39. Tomlinson, D.L., Wilson, J.G., Harris, C.R., and Jeffrey, D.W., 1980, Problems in the assessment of heavy-metal levels in estuaries and the formation of a pollution index, Helgol. Mar. Res., 33(1-4), 566-575.
  40. Wedepohl, K.H., 1969, Handbook of geochemistry, Vol. II/1, Springer, New York.
  41. USEPA, Soil screening guidance: Technical background document, Appendix A: Generic SSLs, https://www.epa.gov/superfund/superfund-soil-screening-guidance
  42. USEPA, Regional sScreening levels(RSLs) - Generic tables, Table as of: May, 2018, https://www.epa.gov/risk/regionalscreening-levels-rsls-generic-tables
  43. Zhang, J. and Liu, C.L., 2002, Riverine composition and estuarine geochemistry of particulate metals in China - weathering features, anthropogenic impact and chemical fluxes, Estuar. Coast. Shelf Sci., 54(6), 1051-1070. https://doi.org/10.1006/ecss.2001.0879