한국재료학회지 (Korean Journal of Materials Research)

  • 제28권5호
  • /
  • Pages.273-278
  • /
  • 2018
  • /
  • 1225-0562(pISSN)
  • /
  • 2287-7258(eISSN)
한국재료학회 (Materials Research Society of Korea)
권호 표지
DOI QR코드

DOI QR Code

칼슘 도핑을 통한 고 에너지 밀도를 가지는 Ni-rich 층상 구조형 양극 소재의 안정화

Stabilization of Nickel-Rich Layered Cathode Materials of High Energy Density by Ca Doping

  • 강범희 (충남대학교 신소재공학부) ;
  • 홍순현 (충남대학교 신소재공학부) ;
  • 윤홍관 (충남대학교 신소재공학부) ;
  • 김도진 (충남대학교 신소재공학부) ;
  • 김천중 (충남대학교 신소재공학부)
  • Kang, Beomhee (Department of Materials Science and Engineering, Chungnam National University) ;
  • Hong, Soonhyun (Department of Materials Science and Engineering, Chungnam National University) ;
  • Yoon, Hongkwan (Department of Materials Science and Engineering, Chungnam National University) ;
  • Kim, Dojin (Department of Materials Science and Engineering, Chungnam National University) ;
  • Kim, Chunjoong (Department of Materials Science and Engineering, Chungnam National University)
  • 투고 : 2018.03.29
  • 심사 : 2018.04.17
  • 발행 : 2018.05.27
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Lithium-ion batteries have been considered the most important devices to power mobile or small-sized devices due to their high energy density. $LixCoO_2$ has been studied as a cathode material for the Li-ion battery. However, the limitation of its capacity impedes the development of high capacity cathode materials with Ni, Mn, etc. in them. The substitution of Mn and Ni for Co leads to the formation of solid solution phase $LiNi_xMn_yCo_{1-x-y}O_2$ (NMC, both x and y < 1), which shows better battery performance than unsubstituted $LiCoO_2$. However, despite a high discharge capacity in the Ni-rich compound (Ni > 0.8 in the metal site), poor cycle retention capability still remains to be overcome. In this study, aiming to improve the stability of the physical and chemical bonding, we investigate the stabilization effect of Ca in the Ni-rich layered compound $Li(Ni_{0.83}Co_{0.12}Mn_{0.05})O_2$, and then Ca is added to the modified secondary particles to lower the degree of cationic mixing of the final particles. For the optimization of the final grains added with Ca, the Ca content (x = 0, 2.5, 5.0, 10.0 at.%) versus Li is analyzed.

키워드

참고문헌

  1. M. H. Lee and Y. Kang, S. T. Myung, and Y. K. Sun, Electrochim. Acta., 50, 939 (2004). https://doi.org/10.1016/j.electacta.2004.07.038
  2. H. J. Noh, S. Youn, C. S. Yoon, and Y. K. Sun, J. Power Sources, 233, 121 (2013). https://doi.org/10.1016/j.jpowsour.2013.01.063
  3. L. J. Li, X. H. Li, Z. X. Wang, L. Wu, J. C. Zheng and J. H. Li, Trans. Nonferrous Met. Soc. China, 20, S279 (2010). https://doi.org/10.1016/S1003-6326(10)60056-8
  4. J. M. Zheng, W. H. Kan and A. Manthiram, ACS Appl. Mater. Interfaces, 7, 6926 (2015). https://doi.org/10.1021/acsami.5b00788
  5. W. Liu, P. Oh, X. Liu, M. J. Lee, W. Cho, S. Chae, Y. Kim and J. Cho, Angew. Chem. Int. Ed., 54, 4440 (2015). https://doi.org/10.1002/anie.201409262
  6. S. T. Myung, F. Maglia, K. J. Park, C. S. Yoon, P. Lamp, S. J. Kim and Y. K. Sun, ACS Energy Lett., 2, 196 (2017). https://doi.org/10.1021/acsenergylett.6b00594
  7. K. J. Park, B. B. Lim, M. H. Choi, H. G. Jung, Y. K. Sun, M. Haro, N. Vicente, J. Bisquert and G. Garcia- Belmonte, J. Mater. Chem. A, 3, 22183 (2015). https://doi.org/10.1039/C5TA05657H
  8. B. B. Lim, S. T. Myung, C. S. Yoon and Y. K. Sun, ACS Energy Lett., 1, 283 (2016). https://doi.org/10.1021/acsenergylett.6b00150
  9. S. W. Woo, S. T. Myung, H. Bang, D. W. Kim and Y. K. Sun, Electrochim. Acta., 54, 3851 (2009). https://doi.org/10.1016/j.electacta.2009.01.048
  10. K. Amine, Z. Chen, Z. Zhang, J. Liu, W. Lu, Y. Qin, J. Lu, L. Curtis and Y. K. Sun, J. Mater. Chem., 21, 17754 (2011). https://doi.org/10.1039/c1jm11584g
  11. Y. Cho, P. Oh and J. Cho, Nano Lett., 13, 1145 (2013). https://doi.org/10.1021/nl304558t
  12. M. H. Kim, H. S. Shin, D. Shin and Y. K. Sun, J. Power Sources, 159, 1328 (2006). https://doi.org/10.1016/j.jpowsour.2005.11.083
  13. Y. Huang, Z. X. Wang, X. H. Li, H. J. Guo and J. X. Wang, Trans. Nonferrous Met. Soc. China, 25, 2253 (2015). https://doi.org/10.1016/S1003-6326(15)63838-9
  14. D. P. Wang, I. Belharouak, G. W. Zhou and K. Amine, J. Electrochem. Soc., 160, A3108 (2013). https://doi.org/10.1149/2.016305jes
  15. F. Schipper, E. M. Erickson, C. Erk, J. Y. Shin, F. F. Chesneau and D. Aurbach, J. Electrochem. Soc., 164, A6220 (2017). https://doi.org/10.1149/2.0351701jes
  16. J. M. Zheng, M. Gu, J. Xiao, P. J. Zuo, C. M. Wang and J. G. Zhang, Nano Lett., 13, 3824 (2013). https://doi.org/10.1021/nl401849t
  17. A. v. Bommel, J. R. Dahn, Chem. Mater., 21, 1500 (2009). https://doi.org/10.1021/cm803144d
  18. K. Park, J. H. Park, S. G. Hong, B. Choi, S. Heo, S. W. Seo, K. Min and J. H. Park, Sci. Rep., 7, 44557 (2017). https://doi.org/10.1038/srep44557
  19. S. K. Jung, H. Gwon, J. Hong, K. Y. Park, D. H. Seo, H. Kim, J. Hyun, W. Yang and K. Kang, Adv. Energy Mater., 4, 1300787 (2014). https://doi.org/10.1002/aenm.201300787
  20. A. Manthiram, J. C. Knight, S. T. Myung, S. M. Oh and Y. K. Sun, Adv. Energy Mater., 6, 1501010 (2016). https://doi.org/10.1002/aenm.201501010
  21. Y. K. Sun, B. R. Lee, H. J. Noh, H. Wu, S. T. Myung and K. Amine, J. Mater. Chem., 21, 10108 (2011). https://doi.org/10.1039/c0jm04242k
  22. J. Y. Liao and A. Manthiram, J. Power Sources, 282, 429 (2015). https://doi.org/10.1016/j.jpowsour.2015.02.078
  23. W. Cho, S. M. Kim, J. H. Song, T. Yim, S. G. Woo, K. W. Lee, J. S. Kim and Y. J. Kim, J. Power Sources, 282, 45 (2015). https://doi.org/10.1016/j.jpowsour.2014.12.128
  24. C. W. Wang, X.L. Ma, J. G. Cheng, L. Q. Zhou, J. T. Sun and Y. H. Zhou, Solid State Ionics, 177, 1027 (2006). https://doi.org/10.1016/j.ssi.2006.03.030
  25. F. Lin, I. M. Markus, D. Nordlund, T. C. Weng, M. D. Asta, H. L. Xin and M. M. Doeff, Nat. Commun., 5, 3529 (2014). https://doi.org/10.1038/ncomms4529
  26. H. B. Xie, K. Du, G. R. Hu, J. G. Duan, Z. D. Peng, Z. J. Zhang and Y. B. Cao, J. Mater. Chem. A, 3 20236 (2015). https://doi.org/10.1039/C5TA05266A
  27. D. Kang, N. Arailym, J. E. Chae and S. S. Kim, J. Korean Electrochem. Soc., 16, 191 (2013). https://doi.org/10.5229/JKES.2013.16.4.191
  28. K. K. Cheralathan, N. Y. Kang, H. S. Park, Y. J. Lee, W. C. Choi, Y. S. Ko and Y. K. Park, J. Power Sources, 195, 1486 (2010). https://doi.org/10.1016/j.jpowsour.2009.08.101
  29. C. Deng, S. Zhang, B. L. Fu, S. Y. Yang and L. Ma, J. Alloys Compd., 496, 521 (2010). https://doi.org/10.1016/j.jallcom.2010.02.094