Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Synthesis and Characterization of Polyurethane for Artificial Leather Using Bio Polyol

바이오 폴리올을 이용한 인공피혁 코팅용 폴리우레탄의 합성 및 특성

  • Sur, Suk-Hun (Korea Institute of Footwear and Leather Technology) ;
  • Choi, Pil-Jun (Korea Institute of Footwear and Leather Technology) ;
  • Ko, Jae-Wang (Korea Institute of Footwear and Leather Technology) ;
  • Lee, Jae-Yeon (Korea Institute of Footwear and Leather Technology)
  • Received : 2018.10.18
  • Accepted : 2018.12.04
  • Published : 2018.12.27
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Abstract

Wet polyurethane resin was synthesized by using polytrimethylene ether glycol prepared from 1,3-propanediol produced by fermentation from corn sugar as bio polyol and polyether-polyol(PTMG). Physical properties and cell characteristics by wet coagulation were investigated using the synthesized wet polyurethane resin. The tensile strength of wet polyurethane resin decreased with increasing content of bio polyol as copolymer polyol, but it tended to increase elongation at break and tear strength. As a result of thermal characteristic analysis, it was found that the glass transition temperature was slightly increased as the content of bio polyol increased. As a result of comparing the cell characteristics by the wet coagulation method, it was found that the shape of the cell was good when the ether polyol and the bio polyol were used alone.

Keywords

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Scheme 1. Preparation process of DMF based polyurethanes.

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Figure 1. Viscosity of polyurethanes.

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Figure 2. FT-IR spectra of polyurethanes.

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Figure 3. DSC thermograms of polyurethane films.

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Figure 4. Tan delta of polyurethane films.

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Figure 5. TGA curve of polyurethane films.

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Figure 6. Stress-strain curves of polyurethane films.

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Figure 7. SEM micrographs of wet-type artificial leather based on nonwoven fabrics coated with DMF based polyurethanes.

Table 1. Macroglycols used in this study

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Table 2. Sample designation and composition of Wet-PU containing bio polyol

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Table 3. Thermal and mechanical properties of polyurethane films

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References

  1. C. Hepbrn, "Polyurethane Elastomers", Elsevier, New York, p.187, 1991.
  2. G. Woods, "The ICI Polyurethane Book", ICI Polyurethanes, New Jersey, pp.88-100, 1987.
  3. G. Oertel, "Polyurethane Handbook", Carl Hanser Verlag, Munich, pp.555-564, 1993.
  4. Y. Xiu, D. Wang, C. Hu, S. Ying, and J. Li, Morphology-Property Relationship of Segmented Polyurethaneurea: Influences of Soft-Segment Structure and Molecular Weight, J. Appl. Polym. Sci., 48, 867(1993). https://doi.org/10.1002/app.1993.070480511
  5. C. T. Chen, R. F. Eaton, Y. J. Chang, and A. V. Tobolsky, Synthesis, Characterization, and Permeation Properties of Polyether-Based Polyurethanes, J. Appl. Polym. Sci., 16, 2105(1972). https://doi.org/10.1002/app.1972.070160821
  6. P. Krol, Synthesis Methods, Chemical Structures and Phase Structures of Linear Polyurethanes, Properties and Applications of Linear Polyurethanes in Polyurethane Elastomers, Copolymers and Ionomers, Progress in Materials Science, 52, 915(2007). https://doi.org/10.1016/j.pmatsci.2006.11.001
  7. R. J. Zdrahala and I. J. Zdrahala, Biomedical Applications of Polyurethanes: A Reviewof Past Promises, Present Realities, and a Vibrant Future, J. of Biomaterials Applications, 14, 67(1999). https://doi.org/10.1177/088532829901400104
  8. D. P. Pfister, Y. Xia, and R. C. Larock, Recent Advances in Vegetable Oil-Based Polyurethanes, ChemSusChem, 4(6), 703(2011). https://doi.org/10.1002/cssc.201000378
  9. E. Glowinska and J. Datta, A Mathematical Model of Rheological Behavior of Novel Bio-based Isocyanateterminated Polyurethane Prepolymers, Ind. Crops Prod., 60, 123(2014). https://doi.org/10.1016/j.indcrop.2014.06.016
  10. L. Shen, J. Haufe, and M. K. Patel, "Product Overview and Market Projection of Emerging Bio-based Plastics", Report for EPNOE and European Bioplastics, France, p.243, 2009.
  11. D. Dieterich, W. Webele, and H. Witt, Polyurethane Ionomers a New Class of Block Polymers, J. of the Gesellschaft Deutcher Chemiker, 9, 40(1970).
  12. J. R. Fried, "Polymer Science and Technology", Prentice Hall PTR, New Jersey, pp.180-182, 2003.
  13. W. W. Wendlandt, "Thermoanalytical Techniques", Vol. 2, Marcel Dekker Inc., New York, p.264, 1974.
  14. J. Kesslmeier and M. Staudt, Biogenic Volatile Organic Compounds(VOC): An Overview on Emission, Physiology and Ecology, J. of Atmospheric Chemistry, 33, 23(1999). https://doi.org/10.1023/A:1006127516791
  15. S. Wang, H. M. Ang, and M. O. Tade, Volatile Organic Compounds in Indoor Environment and Photocatalytic Oxidation: State of the Art, Environment International, 33, 694(2007). https://doi.org/10.1016/j.envint.2007.02.011
  16. G. Oertel, "Polyurethane Handbook", Carl Hanser Verlag, Munich, p.578, 1993.