청정기술 (Clean Technology)

  • 제24권1호
  • /
  • Pages.63-69
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  • 2018
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  • 1598-9712(pISSN)
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  • 2288-0690(eISSN)
한국청정기술학회 (The Korean Society of Clean Technology)
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기포유동층에서 케미컬루핑 연소시스템을 위한 최적 산소전달입자 선정

Selection of the Best Oxygen Carrier for Chemical Looping Combustion in a Bubbling Fluidized Bed Reactor

  • 투고 : 2017.10.02
  • 심사 : 2017.11.04
  • 발행 : 2018.03.30
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초록

순산소 연소 기술 중 $CO_2$ 회수 비용 절감 효과가 가장 우수한 케미컬루핑연소(chemical looping combustion, CLC) 기술의 핵심인 산소전달입자의 선정을 위해 환원반응 특성 및 물리화학적 특성에 대한 연구를 진행하였다. 세 종류의 산소전달입자(SDN70, N018-R2, N016-R4)를 대상으로 기포유동층 반응기에서 환원반응기체의 농도 및 환원 반응 온도 변화에 따른 산소전달입자의 연료전화율(fuel conversion)과 $CO_2$ 선택도($CO_2$ selectivity)를 측정 및 비교 분석하였다. 또한 산소전달입자의 마모손실 정도 및 입자의 표면 특성을 분석하기 위해 내마모도(Attrition Index, AI) 및 BET surface area를 측정하였다. 결과적으로 세 종류의 산소전달입자 모두 케미컬루핑연소 시스템에 활용하기 적합함을 확인하였으며, 가장 우수한 입자는 N016-R4로 판단되었다.

The reduction reaction characteristics and physicochemical properties were studied for the selection of oxygen carrier, which is the core of the chemical looping combustion (CLC) technology. Fuel conversion and $CO_2$ selectivity of oxygen carrier according to the concentration of reducing gas and the reduction temperature using three kinds of oxygen carrier (SDN70, N018-R2, N016-R4) were measured and compared. In addition, Attrition Index (AI) and BET surface area were measured to analyze the attrition resistance and the surface characteristics of the oxygen carrier. As a result, it was confirmed that all three kinds of oxygen carrier were suitable for use in chemical roofing combustion system, and the best particle was determined to be N016-R4.

키워드

참고문헌

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