Korean Chemical Engineering Research

  • 제56권1호
  • /
  • Pages.139-142
  • /
  • 2018
  • /
  • 0304-128X(pISSN)
  • /
  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
권호 표지
DOI QR코드

DOI QR Code

Preparation of Si/C Anode with PVA Nanocomposite for Lithium-ion Battery Using Electrospinning Method

  • Choi, Sung Il (Department of Chemical Engineering, Pukyong National University) ;
  • Lee, Ye Min (Department of Chemical Engineering, Pukyong National University) ;
  • Jeong, Hui Cheol (Department of Chemical Engineering, Pukyong National University) ;
  • Jung, Eun-Jin (Metallic Materials Research Group, Research Institute of Industrial Science & Technology) ;
  • Lee, Mi Sun (Metallic Materials Research Group, Research Institute of Industrial Science & Technology) ;
  • Kim, Jinyoung (Metallic Materials Research Group, Research Institute of Industrial Science & Technology) ;
  • Kim, Yong Ha (Department of Chemical Engineering, Pukyong National University) ;
  • Won, Yong Sun (Department of Chemical Engineering, Pukyong National University)
  • 투고 : 2017.09.05
  • 심사 : 2017.10.16
  • 발행 : 2018.02.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Silicon (Si) is a promising anode material for next-generation lithium ion batteries (LIBs) because of its high capacity of 4,200 mAh/g ($Li_{4.4}Si$ phase). However, the large volume expansion of Si during lithiation leads to electrical failure of electrode and rapid capacity decrease. Generally, a binder is homogeneously mixed with active materials to maintain electrical contact, so that Si needs a particular binding system due to its large volume expansion. Polyvinyl alcohol (PVA) is known to form a hydrogen bond with partially hydrolyzed silicon oxide layer on Si nanoparticles. However, the decrease of its cohesiveness followed by the repeated volume change of Si still remains unsolved. To overcome this problem, we have introduced the electrospinning method to weave active materials in a stable nanofibrous PVA structure, where stresses from the large volume change of Si can be contained. We have confirmed that the capacity retention of Si-based LIBs using electrospun PVA matrix is higher compared to the conservative method (only dissolving in the slurry); the $25^{th}$ cycle capacity retention ratio based on the $2^{nd}$ cycle was 37% for the electrode with electrospun PVA matrix, compared to 27% and 8% for the electrodes with PVdF and PVA binders.

키워드

참고문헌

  1. Scrosati, B. and Garche, J., "Lithium Batteries: Status, Prospects and Future," J. Power Sources, 195, 2419-2430(2010). https://doi.org/10.1016/j.jpowsour.2009.11.048
  2. Namiki, F., Maeshima, T., Inoue, K., Kawai, H., Saibara, S. and Nanto, T., "Lithium-ion Battery for HEVs, PHEVs, and EVs," Hitachi Review, 63, 103-108(2014).
  3. Tarascon, J. -M. and Armand, M., "Issues and Challenges Facing Rechargeable Lithium Batteries," Nature, 414, 359-367(2001). https://doi.org/10.1038/35104644
  4. Huggins, R. A., "Lithium Alloy Negative Electrodes," J. Power Sources, 81, 13-19(1999).
  5. Chan, C. K., Zhang, X. F. and Cui, Y., "High Capacity Li Ion Battery Anodes Using Ge Nanowires," Nano Lett., 8, 307-309(2008). https://doi.org/10.1021/nl0727157
  6. Zhang, W. J., "A Review of the Electrochemical Performance of Alloy Anodes for Lithium-ion Batteries," J. Power Sources, 196, 13-24(2011). https://doi.org/10.1016/j.jpowsour.2010.07.020
  7. Szczech, J. R. and Jin, S., "Nanostructured Silicon for High Capacity Lithium Battery Anodes," Energy & Environ. Sci., 4, 56-72(2011). https://doi.org/10.1039/C0EE00281J
  8. Kasavajjula, U., Wang, C. S. and Appleby, A. J., "Nano-and Bulksilicon-based Insertion Anodes for Lithium-ion Secondary Cells," J. Power Sources, 163, 1003-1039(2007). https://doi.org/10.1016/j.jpowsour.2006.09.084
  9. Beaulieu, L. Y., Eberman, K. W., Turner, R. L., Krause, L. J. and Dahn, J. R., "Colossal Reversible Volume Changes in Lithium Alloys," Electrochem. Solid-State Lett., 4, A137-A140(2001). https://doi.org/10.1149/1.1388178
  10. Beaulieu, L. Y., Hatchard, T. D., Bonakdarpour, A., Fleischauer, M. D. and Dahn, J. R., "Reaction of Li with Alloy Thin Films Studied by In Situ AFM," J. Electrochem. Soc., 150, A1457-A1464(2003). https://doi.org/10.1149/1.1613668
  11. Hertzberg, B., Alexeev, A. and Yushin, G., "Deformations in Si-Li Anodes Upon Electrochemical Alloying in Nano-Confined Space," J. Am. Chem. Soc., 132, 8548-8549(2010). https://doi.org/10.1021/ja1031997
  12. Graetz, J., Ahn, C. C., Yazami, R. and Fultz, B., "Highly Reversible Lithium Storage in Nanostructured Silicon," Electrochem. Solid-State Lett., 6, A194-A197(2003). https://doi.org/10.1149/1.1596917
  13. Liu, X. H., Huang, L. S., Mao, S. X., Zhu, T. and Huang, J. Y., "Size-Dependent Fracture of Silicon Nanoparticles during Lithiation," ACS Nano., 6, 1522-1531(2012). https://doi.org/10.1021/nn204476h
  14. Liu, X. H., Zheng, H., Zhong, L., Huang, S., Karki, K., Zhang, L. Q. and Cho, J. H., "Anisotropic Swelling and Fracture of Silicon Nanowires During Lithiation," Nano Lett., 11, 3312-3318(2011). https://doi.org/10.1021/nl201684d
  15. Lee, S. W., Lee, H. W., Nix, W. D., Gao, H. and Cui, Y., "Kinetics and Fracture Resistance of Lithiated Silicon Nanostructure Pairs Controlled by Their Mechanical Interaction," Nature Comm., 6(2015).
  16. Chen, J., Liu, J., Qi, Y., Sun, T. and Li, X., "Unveiling the Roles of Binder in the Mechanical Integrity of Electrodes for Lithium-Ion Batteries," J. Electrochem. Soc., 160, A1502-A1509(2013). https://doi.org/10.1149/2.088309jes
  17. Chen, Z., Christensen, L. and Dahn, J. R., "Comparison of PVDF and PVDF-TFE-P as Binders for Electrode Materials Showing Large Volume Changes in Lithium-Ion Batteries," J. Electrochem. Soc., 150, A1073-A1078(2003). https://doi.org/10.1149/1.1586922
  18. Chen, Z., Christensen, L. and Dahn, J. R., "A Study of the Mechanical and Electrical Properties of a Polymer/carbon Black Binder System Used in Battery Electrodes," J. Appl. Polym. Sci., 90, 1891-1899(2003). https://doi.org/10.1002/app.12863
  19. Munao, D., Van Erven, J. W. M., Valvo, M., Garcia-Tamayo, E. and Kelder, E. M. "Role of the Binder on the Failure Mechanism of Si Nano-composite Electrodes for Li-ion Batteries," J. Power Sources., 196, 6695-6702(2011). https://doi.org/10.1016/j.jpowsour.2010.11.072
  20. Park, H. K., Kong, B. S. and Oh, E. S., "Effect of High Adhesive Polyvinyl Alcohol Binder on the Anodes of Lithium Ion Batteries," Electrochem. Comm., 13, 1051-1053(2011). https://doi.org/10.1016/j.elecom.2011.06.034
  21. Bridel, J. S., Azais, T., Morcrette, M., Tarascon, J. M. and Larcher, D., "Key Parameters Governing the Reversibility of Si/Carbon/CMC Electrodes for Li-Ion Batteries," Chem. Mater., 22, 1229-1241(2009).
  22. Jankovic, B., Pelipenko, J., Skarabot, M., Musevic, I. and Kristl, J., "The Design Trend in Tissue-engineering Scaffolds based on Nanomechanical Properties of Individual Electrospun Nanofibers," Inter. J. pharm., 455, 338-347(2013). https://doi.org/10.1016/j.ijpharm.2013.06.083
  23. Andre, D., Meiler, M., Steiner, K., Wimmer, C., Soczka-Guth, T. and Sauer, D. U., "Characterization of High-power Lithium-ion Batteries by Electrochemical Impedance Spectroscopy. I. Experimental Investigation," J. Power Sources., 196, 5334-5341(2011). https://doi.org/10.1016/j.jpowsour.2010.12.102
  24. Prabhakaran, M. P., Ghasemi-Mobarakeh, L., Jin, G. and Ramakrishna, S., "Electrospun Conducting Polymer Nanofibers and Electrical Stimulation of Nerve Stem Cells," J. Biosci. Bioeng., 112, 501-507(2011). https://doi.org/10.1016/j.jbiosc.2011.07.010
  25. Zhang, Y. and Rutledge, G. C., "Electrical Conductivity of Electrospun Polyaniline and Polyaniline-Blend Fibers and Mats," Macromolecules, 45, 4238-4246(2012). https://doi.org/10.1021/ma3005982
  26. Panapoy, M., Dankeaw, A. and Ksapabutr, B., "Electrical Conductivity of PAN-based Carbon Nanofibers Prepared by Electrospinning Method," Thammasat Int. J. Sc. Tech., 13, 11-17(2008).
  27. Wang, W., Li, Z., Xu, X., Dong, B., Zhang, H., Wang, Z. and Fang, S., "Au-Doped Polyacrylonitrile-Polyaniline Core-Shell Electrospun Nanofibers Having High Field-Effect Mobilities," Small, 7, 597-600(2011). https://doi.org/10.1002/smll.201001716
  28. Heikkilä, P. and Harlin, A., "Electrospinning of Polyacrylonitrile (PAN) Solution: Effect of Conductive Additive and Filler on the Process," Express Polym. Lett., 3, 437-445(2009). https://doi.org/10.3144/expresspolymlett.2009.53

피인용 문헌

  1. Confronting the Challenges of Next‐Generation Silicon Anode‐Based Lithium‐Ion Batteries: Role of Designer Electrolyte Additives and Polymeric Binders vol.12, pp.12, 2019, https://doi.org/10.1002/cssc.201900209
  2. Preparation of Highly Porous PAN-LATP Membranes as Separators for Lithium Ion Batteries vol.9, pp.11, 2018, https://doi.org/10.3390/nano9111581
  3. Towards efficient binders for silicon based lithium-ion battery anodes vol.406, pp.None, 2018, https://doi.org/10.1016/j.cej.2020.126807
  4. Dual Cross-Linked Polymer Networks Derived from the Hyperbranched Poly(ethyleneimine) and Poly(acrylic acid) as Efficient Binders for Silicon Anodes in Lithium-Ion Batteries vol.4, pp.2, 2018, https://doi.org/10.1021/acsaem.0c02802