Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Synthesis, Photophysical and Aggregation Properties of Novel Phenanthrene and Pyrene Substituted Phthalocyanines

  • Kumar, Rangaraju Satish (Department of Advanced Organic Materials Engineering, Chungnam National University) ;
  • Son, Young-A (Department of Advanced Organic Materials Engineering, Chungnam National University)
  • Received : 2018.09.28
  • Accepted : 2018.10.12
  • Published : 2018.12.01
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Abstract

We have explained the synthesis of novel phenanthrene and pyrene substituted phthalocyanines (PC-PHE and PC-PYR) and fully confirmed the structures by its spectral, photo physical and elemental analysis. For these phthalocyanines we checked the UV-Visible absorbance in PGMEA and chloroform and transmittance checked in PGMEA. The transmittance results suggested that these phthalocyanines are showing more than 90% transmittance at the 450-550 nm region. These synthesized molecules are nicely soluble in almost all industrial solvents. We checked the aggregation property of these phthalocyanines in PGMEA, and the results suggested no any aggregation for these molecules in PGMEA. The thermogravimetric analysis results concluded that PC-PHE and PC-PYR had high thermal stability. All studies explain that these new phthalocyanines are more suitable for LCD green color filter application.

Keywords

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Fig. 1. Structures of new phenanthrene and pyrene substituted phthalocyanines.

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Scheme 1. Synthesis of phenanthrene substituted phthalocyanine.

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Scheme 2. Synthesis of pyrene substituted phthalocyanine.

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Fig. 2. UV-Visible absorption spectra of PC-PHE and PC-PYR in PGMEA (1 × 10-5 M).

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Fig. 3. UV-Visible absorption spectra of PC-PHE and PC-PYR in CHCl3 (1 × 10-5 M).

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Fig. 4. Transmittance spectra of PC-PHE and PC-PYR in PGMEA (1 × 10-5 M).

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Fig. 5. Aggregation behavior of PC-PHE in PGMEA at different concentrations (1 × 10-6 M to 1 × 10-5 M).

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Fig. 6. Aggregation behavior of PC-PYR in PGMEA at different concentrations (1 × 10-6 M to 1 × 10-5 M).

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Fig. 7. TGA spectra of PC-PHE and PC-PYR.

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