Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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A study on production of dry oxidant by decomposition of H2O2 on K-Mn/Fe2O3 catalyst and NO oxidation process according to simulated flue gas flow

K-Mn/Fe2O3 촉매 상 H2O2 분해에 의한 건식산화제 생성 및 모사 배가스 유량에 따른 NO 산화공정

  • Choi, Hee Young (Plant Engineering Center, Institute for Advanced Engineering) ;
  • Shin, Woo Jin (Plant Engineering Center, Institute for Advanced Engineering) ;
  • Jang, Jung Hee (Plant Engineering Center, Institute for Advanced Engineering) ;
  • Han, Gi Bo (Plant Engineering Center, Institute for Advanced Engineering)
  • 최희영 (고등기술연구원 플랜트엔지니어링센터) ;
  • 신우진 (고등기술연구원 플랜트엔지니어링센터) ;
  • 장정희 (고등기술연구원 플랜트엔지니어링센터) ;
  • 한기보 (고등기술연구원 플랜트엔지니어링센터)
  • Received : 2017.05.29
  • Accepted : 2017.06.28
  • Published : 2017.06.30
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Abstract

In this study, NO oxidation process was studied to increase the NO treatment efficiency of pollutant present in exhaust gas. $H_2O_2$ catalytic cracking was introduced as a method of producing dry oxidizing agents with strong oxidizing power. The $K-Mn/Fe_2O_3$ heterogeneous catalysts applicable to the $H_2O_2$ decomposition process were prepared and their physico-chemical properties were investigated. The prepared dry oxidant was applied to the NO oxidation process to treat the simulated exhaust gas containing NO, NO conversion rates close to 100% were confirmed at various flow rates (5, 10, 20 L/min) of the simulated flue gas.

본 연구에서는 배가스 내 존재하는 오염물질인 NO의 처리효율을 증대시키기 위하여 NO 산화공정을 연구하였으며, 강력한 산화력의 건식산화제를 제조하는 방법으로 $H_2O_2$ 촉매분해가 도입되었다. $H_2O_2$ 분해공정 상에서 적용 가능한 $K-Mn/Fe_2O_3$ 불균일계 촉매가 제조되었으며, 이들이 가지는 물리화학적 특성이 $H_2O_2$ 분해반응에 미치는 영향이 조사되었다. 제조된 건식산화제는 NO가 포함된 모사 배가스를 처리하기 위한 NO 산화공정에 적용되었으며, 다양한 모사 배가스의 유량(5, 10, 20 L/min)에서 약 100% 가까운 NO 전환율을 확인 하였다.

Keywords

References

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