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Qualitative and Quantitative Analyses of Cashmere and Yak Fibers: MALDI-TOF Mass Spectrometry vs. Microscopic Method

캐시미어와 야크 섬유의 정량 정성분석: MALDI-TOF 질량분석법과 현미경법

  • Kim, Youngmi (Department of Organic Materials and Fiber Engineering) ;
  • Choi, Hyung-Min (Department of Organic Materials and Fiber Engineering)
  • 김영미 (숭실대학교 유기신소재파이버공학과) ;
  • 최형민 (숭실대학교 유기신소재파이버공학과)
  • Received : 2017.05.17
  • Accepted : 2017.06.18
  • Published : 2017.06.30

Abstract

Matrix-assisted laser desorption/ionization-time of flight mass spectrometry was employed for the qualitative and quantitative analyses of cashmere and yak fibers. Yak fibers have been a great concern for fraudulent labelling in the luxurious cashmere market. Species-specific ion peaks were identified qualitatively, and mass spectrometry was used for the first-time in an effort to quantitatively analyze these fibers. The results indicated that the identification of unknown compositions was quantitatively possible even in commercial samples. The technique exhibited important advantages over conventional microscopic analysis such as the possibility of analyzing a small size of sample and colored or chemically treated fibers, and greater reproducibility and objectivity.

Keywords

References

  1. S. Li, H. Yi, and S. Shang, "Measurement of Diameter and Scale of Cashmere Fibers by Computer Images Analysis", J. Fiber Bioeng Informatics, 2012, 5, 95−103. https://doi.org/10.3993/jfbi03201209
  2. K. Shimizu, "Proceedings of Exchange Opinions with Cashmere Trade (Manufacturing, Distribution and Marketing) & CCMI", Cashmere and Camel Hair Manufacturers Institute, Boston, MA, April 20th, 2007.
  3. C. Tonetti, C. Vineis, A. Aluigi, and C. Tonin, "Immunological Method for the Identification of Animal Hair Fibres", Text. Res. J., 2012, 82, 766−772. https://doi.org/10.1177/0040517511433146
  4. S. Paolella, M. Bencivenni, F. Lambertini, B. Prandi, A. Faccini, C. Tonetti, C. Vineis, and S. Sforza, "Identification and Quantification of Different Species in Animal Fibers by LC/ ESI-MS Analysis of Keratin-derived Proteolytic Peptides", J. Mass Spectrom., 2013, 48, 919−926. https://doi.org/10.1002/jms.3222
  5. H. Ma, X. Hong, and A. Gao, "Research and Discussion on the Identification Technique for Cashmere and Yak Fibers", Proceedings of 4th International Cashmere Inspection and Technique Conference, 2008, pp.261−276.
  6. W. Lu, J. Fei, J. Yang, M. Tang, Z. Dong, Z. Zhou, J. Ye, and H. Wu, "A Novel Method to Identify Yak Fiber in Textiles", Text. Res. J., 2013, 8, 773−779.
  7. AATCC Test Method 20A, "Fiber Analysis: Quantitative", Test Method of American Association of Textile Chemist and Colorists, AATCC, Research Triangle Park, NC, 2013.
  8. K. Hollyemeyer, W. Altmeyer, and E. Heinzle, "Species Origin Identification of Oetzi's Clothing by Maldi-Tof Mass Spectrometry Using Typtic Hair Digests", Spectrosc. Eur., 2009, 21, 7−14.
  9. E. Szajli, T. Feher, and K. F. Medzihradszky, "Investigating the Quantitative Nature of MALDI-TOF MS", Molecular Cellular Proteomics, 2008, 7, 2410−2418. https://doi.org/10.1074/mcp.M800108-MCP200
  10. M. Kang, A. Tholey, and E. Heinzle, "Application of Automated Matrix-assisted Laser Desorption/ionization Time-of-flight Mass Spectrometry for the Measurement of Enzyme Activities", Rapid Commun. Mass Spectrom., 2001, 15, 1327−1333. https://doi.org/10.1002/rcm.376
  11. Y. Kim, T. Kim, and H. M. Choi, "Qualitative Identification of Cashmere and Yak Fibers by Protein Fingerprint Analysis Using Matrix-assisted Laser Desorption/ionization Time-offlight Mass Spectrometry", Ind. Eng. Chem. Res., 2013, 52, 5563−5571. https://doi.org/10.1021/ie4003415
  12. ISO Test Method, "Textiles-Quantitative Analysis of Animal Fibres by Microscopy-Cashmere, Wool, Specialty Fibers and Their Blends", Test Method of International Standards Organization, ISO, Geneva, Switzerland, 2007.
  13. IWTO Test Method 58-00, "Scanning Electron Microscopic Analysis of Specialty Fibers and Sheep's Wool and Their Blends", Test Method of International Wool Textile Organization, IWTO, Brussels, Belgium, 2000.