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Effects of the Rheological Properties of UV Cured Acrylic Pressure Sensitive Adhesive with Nano-particles on the Silk Screen Printing and Adhesion

실크 스크린 인쇄 및 점착력에 나노 입자가 포함된 UV 경화형 아크릴계 감압 점착제의 유변학적 특성

  • Cho, Min-Jeong (Center for Photofunctional Energy Materials, Dept. of Polymer Science and Engineering, Dankook University) ;
  • Kang, Ho-Jong (Center for Photofunctional Energy Materials, Dept. of Polymer Science and Engineering, Dankook University) ;
  • Kim, Dong-Bok (Center for Photofunctional Energy Materials, Dept. of Polymer Science and Engineering, Dankook University)
  • 조민정 (광에너지소재연구센터, 단국대학교 고분자공학과) ;
  • 강호종 (광에너지소재연구센터, 단국대학교 고분자공학과) ;
  • 김동복 (광에너지소재연구센터, 단국대학교 고분자공학과)
  • Received : 2017.02.17
  • Accepted : 2017.03.08
  • Published : 2017.03.30

Abstract

For application to display module junction process, the silk screen printing based on UV curable acrylic pressure sensitive adhesive(PSA) with silica nano-particles and the rheological properties were studied to investigate the effect on printability and adhesion. The monomers for PSA were based on 2-ethylhexyl acrylate(2-EHA) and acrylic acid(AA) 93:7, butyl acylate(BA), 2-hydroxyethyl acrylate(2-HEA) and tetrahydrofurfuryl acrylate(THFA) were added. Additionally, hydrophobic and hydrophilic nano-particles AEROSIL R974 and AEROSIL 200 were added, respectively. When the ratio of nano-particle was used above 4 or 7 phr, G' and ${\eta}^*$ were increased significantly. When the ratio of AEROSIL 200 was used above 7 phr, the penetration property was decreased during the silk screen printing. We found that the adhesion was decreased with increasing the nano-particle content, and it was decreased in the case of the hydrophilic nano-particle AEROSIL 200.

본 연구는 디스플레이 모듈 접합 공정에 적용하기 위해 자외선 경화형 아크릴계 점착제(PSA)에 실리카 나노 입자를 함량별로 첨가하여 실크 스크린 인쇄성 평가를 실시하였고, 유변학적 성질이 인쇄성 및 점착력에 미치는 영향을 고찰하고자 하였다. 점착제(PSA) 중합을 위한 기본 처방으로 2-ethylhexyl acrylate(2-EHA)와 acrylic acid(AA)를 93:7 비율로 고정하고 butyl acylate(BA), 2-hydroxyethyl acrylate(2-HEA)를 첨가하였다. 추가로 나노 입자는 친수성 및 소수성을 가지는 AEROSIL R974 및 AEROSIL 200을 각각 사용하였다. 나노 입자 함량이 4 또는 7 phr 이상 사용함에 따라 G', ${\eta}^*$ 값이 급격히 증가하였으며, 친수성 나노 입자 AEROSIL 200을 7 phr 이상 첨가했을 때에는 스크린 인쇄 시 투과성이 저하되었다. 점착력은 나노 입자 함량이 증가할수록 감소되는 경향을 보였으며, 친수성인 AEROSIL 200의 경우 점착력이 더욱 저하됨을 알 수 있었다.

Keywords

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