Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
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Optimization of Pretreatment Conditions for Ti Surface in the Low Voltage PEO Anodization Process

저전압 PEO 양극산화 공정을 위한 Ti 전처리 조건의 최적화 연구

  • Ha, Dongheun (Department of Chemistry and Chemical Engineering, Inha University) ;
  • Choi, Jinsub (Department of Chemistry and Chemical Engineering, Inha University)
  • 하동흔 (인하대학교 화학.화공융합학과) ;
  • 최진섭 (인하대학교 화학.화공융합학과)
  • Received : 2017.12.06
  • Accepted : 2017.12.22
  • Published : 2017.12.31
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Abstract

Plasma electrolyte oxidation (PEO) is a kind of anodization, in which a very high voltage or current is applied to a metal substrate in various electrolytes, allowing distinctly thick thickness of the oxide film with outstanding film properties, such as a good corrosion resistance, mechanical strength, thermal stability, and excellent adhesion to a substrate. Herein, we tried to find the optimal pretreatment conditions among commercially available solutions in order to produce PEO anodizing at relatively low voltage. We characterized the surface morphologies of the sample by scanning electron microscope (SEM), atomic force microscopy (AFM), and investigated color parameters of the pretreated surface of Ti by spectrophotometer.

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References

  1. Shokouhfar, M., Dehghanian, C., Montazeri, M., Baradaran, A., Preparation of ceramic coating on Ti substrate by plasma electrolytic oxidation in different electrolytes and evaluation of its corrosion resistance: Part II, Appl. Surf. Sci. 258 (2012) 2416-2423. https://doi.org/10.1016/j.apsusc.2011.10.064
  2. Curran, J., Clyne, T., Thermo-physical properties of plasma electrolytic oxide coatings on aluminium, Surface and Coatings Technology 199 (2005) 168- 176. https://doi.org/10.1016/j.surfcoat.2004.09.037
  3. Khorasanian, M., Dehghan, A., Shariat, M., Bahrololoom, M., Javadpour, S., Microstructure and wear resistance of oxide coatings on Ti-6Al- 4V produced by plasma electrolytic oxidation in an inexpensive electrolyte, Surface and coatings Technology 206 (2011) 1495-1502. https://doi.org/10.1016/j.surfcoat.2011.09.038
  4. Hussein, R., Nie, X., Northwood, D., Yerokhin, A., Matthews, A., Spectroscopic study of electrolytic plasma and discharging behaviour during the plasma electrolytic oxidation (PEO) process, J. Phys. D 43 (2010) 105203. https://doi.org/10.1088/0022-3727/43/10/105203
  5. Han, Y., Hong, S., Xu, K., Porous nanocrystalline titania films by plasma electrolytic oxidation, Surface and Coatings Technology 154 (2002) 314- 318. https://doi.org/10.1016/S0257-8972(02)00036-1
  6. Matykina, E., Arrabal, R., Skeldon, P., Thompson, G., Transmission electron microscopy of coatings formed by plasma electrolytic oxidation of titanium, Acta biomaterialia 5 (2009) 1356-1366. https://doi.org/10.1016/j.actbio.2008.10.007
  7. Stojadinovic, S., Vasilic, R., Petkovic, M., Zekovic, L., Plasma electrolytic oxidation of titanium in heteropolytungstate acids, Surface and Coatings Technology 206 (2011) 575-581. https://doi.org/10.1016/j.surfcoat.2011.07.090
  8. Baszkiewicz, J., Krupa, D., Mizera, J., Sobczak, J., Bilinski, A., Corrosion resistance of the surface layers formed on titanium by plasma electrolytic oxidation and hydrothermal treatment, Vacuum 78 (2005) 143-147. https://doi.org/10.1016/j.vacuum.2005.01.017
  9. Khan, R. H., Yerokhin, A., Matthews, A., Structural characteristics and residual stresses in oxide films produced on Ti by pulsed unipolar plasma electrolytic oxidation, Philosophical Magazine 88 (2008) 795-807. https://doi.org/10.1080/14786430801968603
  10. de Hazan, Y., Zimmermann, D., Z'graggen, M., Roos, S., Aneziris, C., Bollier, H., Fehr, P., Graule, T., Homogeneous electroless Ni-P/SiO 2 nanocomposite coatings with improved wear resistance and modified wear behavior, Surface and Coatings Technology 204 (2010) 3464-3470. https://doi.org/10.1016/j.surfcoat.2010.04.007
  11. Jiang, Y., Zhou, H., Zeng, S., Microstructure and properties of oxalate conversion coating on AZ91D magnesium alloy, Transactions of nonferrous metals society of china 19 (2009) 1416-1422. https://doi.org/10.1016/S1003-6326(09)60043-1
  12. Rafieerad, A., Ashra, M., Mahmoodian, R., Bushroa, A., Surface characterization and corrosion behavior of calcium phosphate-base composite layer on titanium and its alloys via plasma electrolytic oxidation: A review paper, Materials Science and Engineering: C 57 (2015) 397-413. https://doi.org/10.1016/j.msec.2015.07.058
  13. Ou, J., Liu, M., Li, W., Wang, F., Xue, M., Li, C., Corrosion behavior of superhydrophobic surfaces of Ti alloys in NaCl solutions, Appl. Surf. Sci. 258 (2012) 4724-4728. https://doi.org/10.1016/j.apsusc.2012.01.066
  14. Ghasemi, A., Raja, V., Blawert, C., Dietzel, W., Kainer, K., The role of anions in the formation and corrosion resistance of the plasma electrolytic oxidation coatings, Surface and Coatings Technology 204 (2010) 1469-1478. https://doi.org/10.1016/j.surfcoat.2009.09.069
  15. Alves, S., Bayon, R., Igartua, A., Saenz de Viteri, V., Rocha, L., Tribocorrosion behaviour of anodic titanium oxide films produced by plasma electrolytic oxidation for dental implants, Lubr Sci 26 (2014) 500-513. https://doi.org/10.1002/ls.1234
  16. Venkateswarlu, K., Rameshbabu, N., Sreekanth, D., Bose, A., Muthupandi, V., Subramanian, S., Fabrication and characterization of micro-arc oxidized fluoride containing titania films on Cp Ti, Ceram. Int. 39 (2013) 801-812. https://doi.org/10.1016/j.ceramint.2012.07.001
  17. Aliasghari, S., Skeldon, P., Thompson, G., Plasma electrolytic oxidation of titanium in a phosphate/ silicate electrolyte and tribological performance of the coatings, Appl. Surf. Sci. 316 (2014) 463-476. https://doi.org/10.1016/j.apsusc.2014.08.037
  18. Lu, X., Mohedano, M., Blawert, C., Matykina, E., Arrabal, R., Kainer, K. U., Zheludkevich, M. L., Plasma electrolytic oxidation coatings with particle additions-A review, Surface and Coatings Technology 307 (2016) 1165-1182. https://doi.org/10.1016/j.surfcoat.2016.08.055
  19. Yao, Z., Jia, F., Tian, S., Li, C., Jiang, Z., Bai, X., Microporous Ni-doped TiO2 film photocatalyst by plasma electrolytic oxidation, ACS applied materials & interfaces 2 (2010) 2617-2622. https://doi.org/10.1021/am100450h
  20. Abu Ghalwa, N. M., Zaggout, F. R., Electrodegradation of methylene blue dye in water and wastewater using lead oxide/titanium modified electrode, Journal of Environmental Science and Health Part A 41 (2006) 2271-2282. https://doi.org/10.1080/10934520600872888
  21. Lu, X., Blawert, C., Huang, Y., Ovri, H., Zheludkevich, M. L., Kainer, K. U., Plasma electrolytic oxidation coatings on Mg alloy with addition of SiO 2 particles, Electrochim. Acta 187 (2016) 20-33. https://doi.org/10.1016/j.electacta.2015.11.033
  22. Klokkevold, P. R., Nishimura, R. D., Adachi, M., Caputo, A., Osseointegration enhanced by chemical etching of the titanium surface. A torque removal study in the rabbit., Clin. Oral Implants Res. 8 (1997) 442-447. https://doi.org/10.1034/j.1600-0501.1997.080601.x
  23. Jonasova, L., Müller, F. A., Helebrant, A., Strnad, J., Greil, P., Biomimetic apatite formation on chemically treated titanium, Biomaterials 25 (2004) 1187-1194. https://doi.org/10.1016/j.biomaterials.2003.08.009
  24. Wang, Y., Yu, H., Chen, C., Zhao, Z., Review of the biocompatibility of micro-arc oxidation coated titanium alloys, Mater Des 85 (2015) 640-652. https://doi.org/10.1016/j.matdes.2015.07.086
  25. Matykina, E., Skeldon, P., Thompson, G., Fundamental and practical evaluation of plasma electrolytic oxidation coatings of titanium, Surface Engineering 23 (2007) 412-418. https://doi.org/10.1179/174329407X247154
  26. Huang, P., Wang, F., Xu, K., Han, Y., Mechanical properties of titania prepared by plasma electrolytic oxidation at different voltages, Surface and Coatings Technology 201 (2007) 5168-5171. https://doi.org/10.1016/j.surfcoat.2006.07.137
  27. Simka, W., Sadkowski, A., Warczak, M., Iwaniak, A., Dercz, G., Michalska, J., Maciej, A., Characterization of passive films formed on titanium during anodic oxidation, Electrochim. Acta 56 (2011) 8962-8968. https://doi.org/10.1016/j.electacta.2011.07.129
  28. Li, Q.; Liang, J.; Wang, Q. In Plasma electrolytic oxidation coatings on lightweight metals; Modern Surface Engineering Treatments; Intech: 2013;.
  29. Wang, H., Zhu, R., Lu, Y., Xiao, G., Zhao, X., He, K., Yuan, Y., Li, Y., Ma, X., Preparation and properties of plasma electrolytic oxidation coating on sandblasted pure titanium by a combination treatment, Materials Science and Engineering: C 42 (2014) 657-664. https://doi.org/10.1016/j.msec.2014.06.005
  30. El Achhab, M., Erbe, A., Koschek, G., Hamouich, R., Schierbaum, K., A microstructural study of the structure of plasma electrolytically oxidized titanium foils, Applied Physics A 116 (2014) 2039- 2044. https://doi.org/10.1007/s00339-014-8392-5