Journal of the Korean Society of Propulsion Engineers (한국추진공학회지)

The Korean Society of Propulsion Engineers (한국추진공학회)
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The Characteristics Analysis and Manufacture of Metal Explosive(ZPP) on PMD

PMD용 금속화약(ZPP) 제조 및 특성분석

  • Shim, Jungseob (Energetic Materials & Pyrotechnics Department, Hanwha Corporation R&D Institute) ;
  • Kim, Sangbaek (Energetic Materials & Pyrotechnics Department, Hanwha Corporation R&D Institute) ;
  • Ahn, Gilhwan (Energetic Materials & Pyrotechnics Department, Hanwha Corporation R&D Institute) ;
  • Kim, Junhyung (The 4th R&D Institute - 1st Directorate, Agency for Defense Development)
  • Received : 2016.02.18
  • Accepted : 2016.05.16
  • Published : 2016.06.01
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Abstract

This research investigated the manufacturing process and characteristics analysis of ZPP(Zirconium Potassium Perchlorate) as pyrotechnic are commonly found in the aerospace, defense, and automotive industries. A solid pyrotechnic mixture is composed of an oxidizing agent, fuel, and binder. Precipitation process was used to uniformly mix the raw material. Through the analysis of the material characteristics and thermal response is designed optimum ratio by NASA CEA program. It was compared by performing the evaluation of these size, shape and calorimetry characteristics.

본 연구에서는 항공우주, 유도탄, 자동화 산업에 널리 적용되는 금속복합화약 ZPP(Zirconium Potassium Perchlorate)의 제조공정 과 특성평가를 고찰하였다. 기본적으로 PMD에 사용되는 고체 점화제는 금속연료와 산화제 그리고 유기 고분자물질(결합재)로 구성되며, 이들 원료들을 균질하게 혼합하기 위하여 precipitation process를 사용하였다. 원료 물질의 특성 및 열적 반응 해석을 통한 최적 조성비를 설계하였으며, 이들의 입도, 형상, 열량 분석 등의 특성 평가를 수행하여 결과를 비교하였다.

Keywords

References

  1. Jackson, C.H., "Zirconium Composition with Potassium Perchlorate and Graphite," US Patent No. 3291665, Dec. 1966.
  2. Lee, J. S. and Hsu, C. K., "The effect of different zirconium on thermal behaviors for $Zr/KClO_4$ Priming composition," Thermochimica Acta, Vol. 367-368, pp. 375, 2001. https://doi.org/10.1016/S0040-6031(00)00688-2
  3. Durgapal, U.C., Dixit, A.S. and Sarawadekar, R.G., "Study of Zirconium-Potassium Perchlorate Pyrotechnic System", Proceedings of the 11th International Pyrotechnics Seminars, Grand Junction, C.O., U.S.A., pp. 209, 1988.
  4. Hohmann, C. and Tipton, B.Jr., "Propellant for the NASA Standard Initiator," NASATP-2000-210186.
  5. Gordon, S. and McBride, B.J., "Computer Program for Calculation of Complex Chemical Equilibrium Compositions and Applications," NASA Reference Publication 1311, Oct. 1994.
  6. Nakamura, H and Hara, Y., "The Reaction of Titanium Hydride-Boron-Potassium Perchlorate Mixtures," Proceedings of the 20th International Pyrotechnics Seminars, Colorado Springs, C.O., U.S.A., pp. 743, Jul. 1994.
  7. Poulsen, B.L. and Rink, K.K., "Modeling the Energy Release and Burn Rate Characteristics of ZPP Based Initiators," 49th AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition, Orlando, F.L., U.S.A., AIAA 2011-271, Jan. 2011.
  8. Kim, J.Y., Seo, T.S., Ko, S.W. and Ryu, B.T., "Thermal Decomposition Kinetics of ZPP as a Primary Charge of Initiators", Journal of the Korean Society of Propulsion Engineers, Vol. 19, No. 5, pp. 15-21, 2015. https://doi.org/10.6108/KSPE.2015.19.5.015