• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.3
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• pp.25-31
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• 2016

This research investigated the manufacturing process and characteristics analysis of ZPP(Zirconium Potassium Perchlorate) as pyrotechnic are commonly found in the aerospace, defense, and automotive industries. A solid pyrotechnic mixture is composed of an oxidizing agent, fuel, and binder. Precipitation process was used to uniformly mix the raw material. Through the analysis of the material characteristics and thermal response is designed optimum ratio by NASA CEA program. It was compared by performing the evaluation of these size, shape and calorimetry characteristics.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.5
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• pp.15-21
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• 2015

The thermal decomposition characteristics of the ZPP(Zirconium/Potassium perchlorate), widely used as a primary charge of initiators, were investigated by differential scanning calorimetry(DSC). The DSC results with different heating rates were elaborated with AKTS-Thermokinetics software for the determination of the kinetic parameters of the thermal decomposition of ZPP. There was good agreement between the experimental and the simulation curves, based on the determined kinetic parameters, which indicates the validity of the kinetic description of the thermal decomposition process of ZPP.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.6
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• pp.39-48
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• 2017

In this study, combustion modeling of ZPP and $BKNO_3$ mainly used in the PMD industries has been performed. Saint Robert's law, energy conservation equation, and the Noble-Abel equation of the state have been used for governing equations. The results of pressure obtained from established combustion models and actual CBT have been compared. In the case of ZPP, the model has predicted a pressure curve similar to that of the experimental results, but $BKNO_3$ has showed that the maximum pressure of the model is greater than the experiment at small chamber volume. For these gaps, the probability of $BKNO_3$ unburning has been considered.