Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Application of Silica-supported Ionic Liquid Catalysts to Cycloaddition of CO2

CO2 부가반응에 적용된 Silica 담지 이온성 액체 촉매

  • Kim, Dong-Woo (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Kim, Hyeon-Gook (Chemical Industry Development Center, Korea Research Institute of Chemical Technology) ;
  • Cho, Deug-Hee (Chemical Industry Development Center, Korea Research Institute of Chemical Technology)
  • 김동우 (화학산업고도화센터, 한국화학연구원) ;
  • 김현국 (화학산업고도화센터, 한국화학연구원) ;
  • 조득희 (화학산업고도화센터, 한국화학연구원)
  • Received : 2016.04.05
  • Accepted : 2016.05.10
  • Published : 2016.06.10
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Abstract

The catalytic applicability of various ionic liquids immobilized on different silica-supports such as amorphous, SBA, MCM and commercial silica for the cycloaddition of $CO_2$ and epoxides is reviewed in this work. The effects of different structures of supported ionic liquids and silica supports in the synthesis cyclic carbonate by the cycloaddition of $CO_2$ have been remarked. The studies revealed that ionic liquids possessing functional groups or metals exhibited increased catalytic performance towards cyclic carbonate synthesis. Moreover, the reusability of SSIL catalyst and mechanism for the cycloaddition of $CO_2$ were studied.

본 총설에서는 $CO_2$와 에폭시 화합물의 부가반응에서 무정형, SBA, MCM 또는 상업적으로 쉽게 이용 가능한 다양한 silica 지지체에 담지된 이온성 액체의 촉매적 적용가능성에 대하여 검토하였다. $CO_2$ 부가반응에 의한 5원환 카보네이트의 합성에 대하여 담지된 이온성 액체의 구조적인 영향과 silica 지지체의 종류에 따른 촉매 활성을 검토한 바, 관능기 또는 금속을 보유한 이온성 액체인 경우에 촉매 성능이 개선됨을 알 수 있었다. 또한 silica에 담지된 이온성 액체(SSIL) 촉매의 재사용성과 반응메커니즘을 조사하여 제시하였다.

Keywords

References

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