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Studies on the aqueous ammonia alternatives in the wet scrubbing method

습식 세정법에서 암모니아 대체물질에 관한 연구

  • Received : 2016.01.29
  • Accepted : 2016.03.22
  • Published : 2016.03.30

Abstract

In the existing research, the ammonia aqueous solution was used in order to remove the Nitrogen dioxide using the scrubber. However, ammonia is poisonous and stench is extreme. So, the system application follows the difficulty. Experiments were conducted to find a substitute material ammonia. The sodium hydroxide(NaOH), sodium thiosulfate ($Na_2S_2O_3$), and urea were used with the substitute substance. The experimental condition proceeded as the optimum conditions in the existing ammonia use. The experimental result NaOH and $Na_2S_2O_3$ was available. NaOH showed the efficiency which is the highest in 2.5%. And $Na_2S_2O_3$ showed the efficiency which is the highest in 5.0%. The efficiency was not fixed and the urea was inappropriate with the substitute substance.

기존 연구에서는 스크러버를 이용한 $NO_2$ 를 제거하기 위해 암모니아 수용액을 적용한다. 하지만 암모니아는 독성 및 악취가 강해 실선 적용에 어려움이 따를 수 있어, 암모니아를 대체할 수 있는 물질을 찾기 위해 이 연구를 진행하였다. 대체 물질로는 수산화나트륨(NaOH), 티오황산나트륨($Na_2S_2O_3$), 요소(Urea)를 사용하였다. 세정액을 제외한 모든 부분은 기존 암모니아를 적용한 실험의 최적 조건과 동일하게 진행하였다. 그 결과 실험에 사용된 세 가지 물질 중 두 물질은 암모니아 용액과 대체가 가능한 것으로 사료되었으며, 최적조건은 각각 NaOH 2.5 %, $Na_2S_2O_3$ 5.0 % 에서 가장 높은 효율을 나타냈다. Urea는 효율이 일정하게 지속되지 않아 대체 물질로는 적합하지 않음을 확인 할 수 있었다.

Keywords

References

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  1. 선박 배가스내 SOX/NOX 처리용 습식 스크러버에 대한 연구 vol.34, pp.1, 2016, https://doi.org/10.12925/jkocs.2017.34.1.183