Ecology and Resilient Infrastructure

응용생태공학회 (Korean Society of Ecology and Infrastructure Engineering)
권호 표지
DOI QR코드

DOI QR Code

용수 및 폐수 처리를 위한 오존 마이크로버블 적용

Application of Ozone Microbubbles in the Field of Water and Wastewater Treatment

  • 남귀웅 (고려대학교 환경생태공학과) ;
  • 정진호 (고려대학교 환경생태공학과)
  • Nam, Gwiwoong (Department of Environmental Science and Ecological Engineering, Korea University) ;
  • Jung, Jinho (Department of Environmental Science and Ecological Engineering, Korea University)
  • 투고 : 2016.12.10
  • 심사 : 2016.12.20
  • 발행 : 2016.12.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

급격한 산업화와 인구증가로 인한 화학물질 사용량의 증가는 기존의 수 처리 방식의 대부분을 차지하는 생물학적 공정의 한계를 불러온다. 이와 같은 문제를 해결하기 위한 방법으로 고급산화공정의 하나인 오존 마이크로버블 기술이 최근 주목을 받고 있다. 본 논문에서는 마이크로버블의 물리학적 및 화학적 특성에 대해 논하고, 다양한 독성 오염물질의 제거를 중심으로 마이크로버블 오존산화공정을 분석하였다. 또한 다른 처리 기술과 결합한 오존 마이크로버블 기술의 용수 및 폐수처리 전망을 논하였다.

Rapid industrialization and a significant population growth has led to an increased use of chemicals, which has limited the biological processes that account for most of the existing water and wastewater treatment methods. Ozone microbubble technology, which is one of advanced oxidation processes, has recently attracted attention as a method to solve these issues. In this paper, we reviewed both the physical and the chemical characteristics of microbubbles, and evaluated microbubble-based ozone oxidation processes focusing on the removal of various toxic contaminants. In addition, we discussed the potential of an ozone microbubble process as water and wastewater treatment processes by combining it with other treatment technologies.

키워드

참고문헌

  1. Agarwal, A., Ng, W.J. and Liu, Y. 2011. Principle and applications of microbubble and nanobubble technology for water treatment. Chemosphere 84(9): 1175-1180. https://doi.org/10.1016/j.chemosphere.2011.05.054
  2. Ali, U., Syed, J.H., Malik, R.N., Katsoyiannis, A., Li, J., Zhang, G. and Jones, K.C. 2014. Organochlorine pesticides (OCPs) in South Asian region: a review. Science of the Total Environment 476: 705-717.
  3. Arslan, I. and Balcioglu, I.A. 2001. Advanced oxidation of raw and biotreated textile industry wastewater with $O_3$, $H_2O_2/UV-C$ and their sequential application. Journal of Chemical Technology and Biotechnology 76(1): 53-60. https://doi.org/10.1002/1097-4660(200101)76:1<53::AID-JCTB346>3.0.CO;2-T
  4. Camel, V. and Bermond, A. 1998. The use of ozone and associated oxidation processes in drinking water treatment. Water Research 32(11): 3208-3222. https://doi.org/10.1016/S0043-1354(98)00130-4
  5. Chu, L.B., Xing, X.H., Yu, A.F., Zhou, Y.N., Sun, X.L. and Jurcik, B. 2007. Enhanced ozonation of simulated dyestuff wastewater by microbubbles. Chemosphere 68(10): 18541860. https://doi.org/10.1016/j.chemosphere.2007.03.014
  6. Chu, L.B., Xing, X.H., Yu, A.F., Sun, X.L. and Jurcik, B. 2008. Enhanced treatment of practical textile wastewater by microbubble ozonation. Process Safety and Environmental Protection 86(5): 389-393. https://doi.org/10.1016/j.psep.2008.02.005
  7. Corona-Vasquez, B., Samuelson, A., Rennecker, J.L. and Marinas, B.J. 2002. Inactivation of Cryptosporidium parvum oocysts with ozone and free chlorine. Water Research 36(16): 4053-4063. https://doi.org/10.1016/S0043-1354(02)00092-1
  8. Facile, N., Barbeau, B., Prevost, M. and Koudjonou, B. 2000. Evaluating bacterial aerobic spores as a surrogate for Giardia and Cryptosporidium inactivation by ozone. Water Research 34(12): 3238-3246. https://doi.org/10.1016/S0043-1354(00)00086-5
  9. Ghosh, P. 2009. Colloid and Interface Science. PHI Learning Private. Ltd, New Delhi, India.
  10. Gracia, R., Aragues, J. L. and Ovelleiro, J.L. 1996. Study of the catalytic ozonation of humic substances in water and their ozonation byproducts. Ozone: Science & Engineering 18(3): 195-208. https://doi.org/10.1080/01919519608547326
  11. Ikeura, H., Kobayashi, F. and Tamaki, M. 2011. Removal of residual pesticide, fenitrothion, in vegetables by using ozone microbubbles generated by different methods. Journal of Food Engineering 103(3): 345-349. https://doi.org/10.1016/j.jfoodeng.2010.11.002
  12. Jabesa, A. and Ghosh, P. 2016a. Removal of dimethyl phthalate from water by ozone microbubbles. Environmental Technology 27: 1-11.
  13. Jabesa, A. and Ghosh, P. 2016b. Removal of diethyl phthalate from water by ozone microbubbles in a pilot plant. Journal of Environmental Management 180: 476-484. https://doi.org/10.1016/j.jenvman.2016.05.072
  14. Kerfoot, W.B. and McGrath, A. 2001. Microbubble oxidation smokes MTBE and BTEX. Contaminated Soil Sediment and Water Spring (Special Issue): 77-78.
  15. Kerfoot, W.B. and LeCheminant, P. 2003. Ozone microbubble sparging at a California site. In, Moyer, E.E. and Kostecki, P.T. (eds.), MTBE Remediation Handbook. Springer, Amherst, Massachusetts, USA. pp. 455-472.
  16. Kerfoot, W.B., Ehleringer, B. and Muncy, J. 2008. Ozone sparging closure of an industrial VOC spill site adjacent to a water supply well site. Ozone: Science & Engineering 30(1): 88-92. https://doi.org/10.1080/01919510701813400
  17. Khadhraoui, M., Trabelsi, H., Ksibi, M., Bouguerra, S. and Elleuch, B. 2009. Discoloration and detoxicification of a Congo red dye solution by means of ozone treatment for a possible water reuse. Journal of Hazardous Materials 161(2): 974-981. https://doi.org/10.1016/j.jhazmat.2008.04.060
  18. Khuntia, S., Majumder, S.K. and Ghosh, P. 2012. Removal of ammonia from water by ozone microbubbles. Industrial & Engineering Chemistry Research 52(1): 318-326. https://doi.org/10.1021/ie302212p
  19. Khuntia, S., Majumder, S.K. and Ghosh, P. 2015. A pilot plant study of the degradation of Brilliant Green dye using ozone microbubbles: mechanism and kinetics of reaction. Environmental Technology 36(3): 336-347. https://doi.org/10.1080/09593330.2014.946971
  20. Khuntia, S., Majumder, S.K. and Ghosh, P. 2016. Catalytic ozonation of dye in a microbubble system: hydroxyl radical contribution and effect of salt. Journal of Environmental Chemical Engineering 4(2): 2250-2258. https://doi.org/10.1016/j.jece.2016.04.005
  21. Kim, C.S., Yu, S.Y., Lee, G.I., Kim, S.H., Lee, J.W. and Song, J.K. 2014. Sterilizing effect of plant pathogenic fungi using ozone microbubble. Protected Horticulture and Plant Factory 23(3): 250-255. (in Korean) https://doi.org/10.12791/KSBEC.2014.23.3.250
  22. Lee, I., Lee, E., Lee, H. and Lee, K. 2011. Removal of COD and color from anaerobic digestion effluent of livestock wastewater by advanced oxidation using microbubbled ozone. Applied Chemistry for Engineering 22(6): 617-622.
  23. Lopez-Lopez, A., Pic, J.S. and Debellefontaine, H. 2007. Ozonation of azo dye in a semi-batch reactor: a determination of the molecular and radical contributions. Chemosphere 66(11): 2120-2126. https://doi.org/10.1016/j.chemosphere.2006.09.025
  24. Lucas, M.S., Peres, J.A. and Puma, G.L. 2010. Treatment of winery wastewater by ozone-based advanced oxidation processes ($O_3$, $O_3/UV$ and $O_3/UV/H_2O_2$) in a pilot-scale bubble column reactor and process economics. Separation and Purification Technology 72(3): 235-241. https://doi.org/10.1016/j.seppur.2010.01.016
  25. Mestankova, H., Parker, A.M., Bramaz, N., Canonica, S., Schirmer, K., von Gunten, U. and Linden, K.G. 2016. Transformation of contaminant candidate list (CCL3) compounds during ozonation and advanced oxidation processes in drinking water: assessment of biological effects. Water Research 93: 110-120. https://doi.org/10.1016/j.watres.2015.12.048
  26. Osbeck, S., Bradley, R.H., Liu, C., Idriss, H. and Ward, S. 2011. Effect of an ultraviolet/ozone treatment on the surface texture and functional groups on polyacrylonitrile carbon fibres. Carbon 49(13): 4322-4330. https://doi.org/10.1016/j.carbon.2011.06.005
  27. Suty, H., De Traversay, C. and Cost, M. 2004. Applications of advanced oxidation processes: present and future. Water Science and Technology 49(4): 227-233.
  28. Takahashi, M. 2005. $\zeta$ potential of microbubbles in aqueous solutions: electrical properties of the gas-water interface. The Journal of Physical Chemistry B 109(46): 21858-21864. https://doi.org/10.1021/jp0445270
  29. Takahashi, M., Chiba, K. and Li, P. 2007. Free-radical generation from collapsing microbubbles in the absence of a dynamic stimulus. The Journal of Physical Chemistry B 111(6): 1343-1347. https://doi.org/10.1021/jp0669254
  30. Tambosi, J.L., De Sena, R.F., Gebhardt, W., Moreira, R.F.P.M., Jose, H.J. and Schroder, H.F. 2009. Physicochemical and advanced oxidation processes-a comparison of elimination results of antibiotic compounds following an MBR treatment. Ozone: Science & Engineering 31(6): 428-435. https://doi.org/10.1080/01919510903324420
  31. Vandevivere, P.C., Bianchi, R. and Verstraete, W. 1998. Review: treatment and reuse of wastewater from the textile wet-processing industry: review of emerging technologies. Journal of Chemical Technology and Biotechnology 72(4): 289-302. https://doi.org/10.1002/(SICI)1097-4660(199808)72:4<289::AID-JCTB905>3.0.CO;2-#
  32. Walker, A.B., Tsouris, C., DePaoli, D.W. and Thomas Klasson, K. 2001. Ozonation of soluble organics in aqueous solutions using microbubbles. Ozone: Science & Engineering 23(1): 77-87. https://doi.org/10.1080/01919510108961990
  33. Wang, C., Yediler, A., Lienert, D., Wang, Z. and Kettrup, A. 2003. Ozonation of an azo dye CI Remazol Black 5 and toxicological assessment of its oxidation products. Chemosphere 52(7): 1225-1232. https://doi.org/10.1016/S0045-6535(03)00331-X
  34. Wu, C.H., Kuo, C.Y. and Chang, C.L. 2008. Homogeneous catalytic ozonation of CI Reactive Red 2 by metallic ions in a bubble column reactor. Journal of Hazardous Materials 154(1): 748-755. https://doi.org/10.1016/j.jhazmat.2007.10.087
  35. Xia, Z. and Hu, L. 2016. Remediation of organics contaminated groundwater by ozone micro-nano bubble. Japanese Geotechnical Society Special Publication 2(57): 1978-1981. https://doi.org/10.3208/jgssp.TC215-06
  36. Xu, P., Janex, M.L., Savoye, P., Cockx, A. and Lazarova, V. 2002. Wastewater disinfection by ozone: main parameters for process design. Water Research 36(4): 1043-1055. https://doi.org/10.1016/S0043-1354(01)00298-6
  37. Xu, Z., Mochida, K., Naito, T. and Yasuda, K. 2012. Effects of operational conditions on 1, 4-dioxane degradation by combined use of ultrasound and ozone microbubbles. Japanese Journal of Applied Physics 51(7S): 07GD08. https://doi.org/10.7567/JJAP.51.07GD08
  38. Zhang, F., Xi, J., Huang, J.J. and Hu, H.Y. 2013. Effect of inlet ozone concentration on the performance of a micro-bubble ozonation system for inactivation of Bacillus subtilis spores. Separation and Purification Technology 114: 126-133. https://doi.org/10.1016/j.seppur.2013.04.034
  39. Zheng, T., Wang, Q., Zhang, T., Shi, Z., Tian, Y., Shi, S., Smale, N. and Wang, J. 2015a. Microbubble enhanced ozonation process for advanced treatment of wastewater produced in acrylic fiber manufacturing industry. Journal of Hazardous Materials 287: 412-420. https://doi.org/10.1016/j.jhazmat.2015.01.069
  40. Zheng, T., Zhang, T., Wang, Q., Tian, Y., Shi, Z., Smale, N. and Xu, B. 2015b. Advanced treatment of acrylic fiber manufacturing wastewater with a combined microbubble-ozonation/ultraviolet irradiation process. RSC Advances 5(95): 77601-77609. https://doi.org/10.1039/C5RA14575A
  41. Zhu, X.F. and Xu, X.H. 2004. The mechanism of Fe (III)-catalyzed ozonation of phenol. Journal of Zhejiang University Science 5(12): 1543-1547. https://doi.org/10.1631/jzus.2004.1543

피인용 문헌

  1. Development of Natural Purification Technology Considering Material Cycle in River Reaches vol.3, pp.4, 2016, https://doi.org/10.17820/eri.2016.3.4.213