한국지반환경공학회 논문집 (Journal of the Korean GEO-environmental Society)

한국지반환경공학회 (Korean Geo-Environmental Society)
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고칼슘 플라이애쉬를 이용한 알칼리 활성화제 무첨가 저강도 유동화 채움재 특성 평가

The Characterization of Controlled Low Strength Material (CLSM) Using High CaO Fly Ash without Chemical Alkaline Activator

  • Lim, Sanghyeong (School of Civil, Environtmental and Architectural Engineering, Korea University) ;
  • Choo, Hyunwook (School of Civil, Environtmental and Architectural Engineering, Korea University) ;
  • Lee, Woojin (School of Civil, Environtmental and Architectural Engineering, Korea University) ;
  • Lee, Changho (Department of Marine and Civil Engineering, Chonnam National University)
  • 투고 : 2016.07.25
  • 심사 : 2016.10.31
  • 발행 : 2016.12.01
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초록

본 연구에서는 등급 외 플라이애쉬 중 산화칼슘 함량이 높은 플라이애쉬를 저강도 유동화 채움재(controlled low strength material, CLSM)의 바인더로써 활용 가능성을 알아보았다. 사용된 플라이애쉬는 상대적으로 산화칼슘 함량이 높은 플라이애쉬를 배출하는 유동층형 보일러(circulating fluidized bed combustion boiler, CFBC)에서 시료를 채집하여 사용하였다. 배합한 시료의 유동성, 일축압축강도, 단위중량 등을 파악하여 CLSM 시료의 공학적 특징을 알아보았으며, 미세구조관찰과 X선 회절분석을 통한 CLSM 시료의 경화 메커니즘을 파악하였다. 실험 수행 결과 유동성을 만족하는 함수비는 42에서 85%의 범위를 보였으며, 유동성 시험 결과 골재의 종류와 관계없이 골재율이 증가함에 따라 유동성이 증가하는 것으로 나타났다. 일축압축강도는 0.3MPa에서 1.9MPa의 분포를 보였다. 규사를 골재로 사용한 경우 골재율이 증가함에 따라 일축압축강도는 증가하였으나, 바텀애쉬를 골재로 사용한 경우 골재율이 증가함에 따라 일축압축강도는 감소하였다. 미세구조관찰 결과와 X선 회절분석을 통해 CLSM 시료는 고분자 중합반응과 시멘트 수화반응을 통해 강도를 발현하는 것으로 확인하였다. 본 연구의 결과로부터 산화칼슘 함량이 높은 플라이애쉬의 자체 경화성을 이용하여 저강도 유동화 채움재로써 활용이 가능하다고 판단된다.

The experimental investigation aims at developing controlled low strength materials (CLSM) using a self-cementitious fly ash (FA) as a binder and a bottom ash (BA) as a aggregate. The fly ash and bottom ash used in this study were obtained from a circulating fluidized bed combustion boiler (CFBC) which produces relatively high CaO containing fly ash. To find the optimum mixing condition satisfying flow consistency and unconfined compression strength (UCS), the CLSM specimens were prepared under various mixing conditions, including two types of aggregate and different weight fractions between fly ash and aggregate. Additionally, the prepared specimens were evaluated using a scanning electron microscope (SEM) and X-ray diffraction (XRD). The results of this study demonstrate that the water content satisfying flow consistency ranges from 42% to 85% and the flowability is improved with increasing the fraction of aggregate in whole mixture. The USC ranges from 0.3 MPa to 1.9 MPa. The results of UCS increases with increasing the fraction of aggregate in FA-sand mixtures, but decreases with increasing the fraction of aggregate in FA-BA mixtures. SEM images and XRD patterns reveal that the occurrence of both geopolymerization and hydration. The results of this study demonstrate that CFBC fly ash could be used as an alternative binder of CLSM mixtures.

키워드

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