DOI QR코드

DOI QR Code

Iodide/Iodine용액에서 CPU chip 분쇄물의 금 침출특성

Leaching Behavior of Gold from CPU chip Grinding Products in Iodide/Iodine Solution

  • Jung, Insang (Department of Earth Resources and Environmental Engineering, Hanyang University) ;
  • Joe, Aram (Department of Earth Resources and Environmental Engineering, Hanyang University) ;
  • Choi, Joonchul (Department of Earth Resources and Environmental Engineering, Hanyang University) ;
  • Song, Youjin (Global Resources & Materials Co., Ltd.) ;
  • Park, Poongwon (Global Resources & Materials Co., Ltd.) ;
  • Park, Kyungho (Mineral Resource Research Division, Korea Institute of Geoscience and Mineral Resources) ;
  • Lee, Sujeong (Mineral Resource Research Division, Korea Institute of Geoscience and Mineral Resources) ;
  • Park, Jaikoo (Department of Earth Resources and Environmental Engineering, Hanyang University)
  • 투고 : 2015.05.26
  • 심사 : 2016.01.29
  • 발행 : 2016.02.29

초록

요오드용액을 사용하여 노트북 인쇄회로기판 CPU chip 중에 함유된 금을 침출하는 연구를 진행하였다. 150 mesh 이하로 분쇄된 CPU chip을 Iodide/Iodine용액에서 처리한 결과 금의 침출율은 20%로 매우 낮게 나타났다. 이와 같이 낮은 침출율의 원인은 CPU chip 분쇄과정에서 금 입자 표면에 생성된 구리 피막이 침출액과 금의 접촉을 방해하기 때문인 것으로 판단되었다. 한편, CPU chip 분쇄물을 질산용액을 사용하여 전처리 한 후 Iodide/Iodine 용액으로 침출하였을 때 금의 침출율은 약 90%으로 크게 증가하였다. 이 현상을 설명하기 위하여 침출 잔사를 EDS 및 ICP 분석을 통해 관찰한 결과, 금 입자표면에 피복되어 있는 구리의 약 80%가 질산에 의해 제거되었으며 이로 인해 금의 침출율이 향상된 것을 확인할 수 있었다.

The leaching behavior of gold from waste CPU chip using Iodide/Iodine solution was studied. The direct leaching of gold with Iodide/Iodine solution for CPU chip under the size of 150 mesh showed leaching ratio of 20%. It was assumed that the copper film was produced on the gold particle during grinding process and the copper film prevents lodine/Iodide solution from contacting with leachable gold. Meanwhile, the extraction of gold was improved to 90% by pretreatment process with $HNO_3$ solution. In order to explain the result, EDS and ICP analysis for the leaching residue were conducted. It was found that the copper coated on the surface of the gold particle was removed about 80% by $HNO_3$, resulting in the increment of gold leaching rate.

키워드

참고문헌

  1. Huang, K., J. Guo, Z. Xu, 2009: Recycling of waste printed circuit boards: A review of current technologies and treatment status in China, Journal of hazardous materials, 164(2), pp. 399-408. https://doi.org/10.1016/j.jhazmat.2008.08.051
  2. Jha, M.K., et al., 2012: Leaching studies for tin recovery from waste e-scrap, Waste management, 32(10), pp. 1919-1925. https://doi.org/10.1016/j.wasman.2012.05.006
  3. Duan, C., et al., 2009: Recovery of metals from waste printed circuit boards by a mechanical method using a water medium, Journal of Hazardous Materials, 166(1), pp. 478-482. https://doi.org/10.1016/j.jhazmat.2008.11.060
  4. Behnamfard, A., M.M. Salarirad, F. Veglio, 2013: Process development for recovery of copper and precious metals from waste printed circuit boards with emphasize on palladium and gold leaching and precipitation, Waste management, 33(11), pp. 2354-2363. https://doi.org/10.1016/j.wasman.2013.07.017
  5. Wen, X., et al., 2005: Study on metals recovery from discarded printed circuit boards by physical methods, IEEE,
  6. Kim, Y.-S., 2010: Recovery of Waste Back Board and Gold from the Process of Printed Circuit Board, Journal of the Korean Institute of Resources Recycling, 19(1), pp. 57-65.
  7. Crundwell, F., 2013: The dissolution and leaching of minerals: Mechanisms, myths and misunderstandings, Hydrometallurgy, 139(132-148). https://doi.org/10.1016/j.hydromet.2013.08.003
  8. Rodriguez, F., et al., 2009: Adsorption of a gold-iodide complex (AuI2-) onto cellulose acetate-polyaniline membranes: Equilibrium experiments, Journal of applied polymer science, 113(4), pp. 2670-2674. https://doi.org/10.1002/app.30337
  9. Zhang, H., C.A. Jeffery, M.I. Jeffrey, 2012: Ion exchange recovery of gold from iodine-iodide solutions, Hydrometallurgy, 125(69-75).
  10. Kumar, V., et al., 2013: Novel physical separation process for eco-friendly recycling of rare and valuable metals from end-of-life DVD-PCBA, Separation and Purification Technology, 111(145-154). https://doi.org/10.1016/j.seppur.2013.03.039
  11. Choi, J., W. Lee, 1995: Dissolution kinetics of palladium in iodide solutions, Journal of the Korean Institute of Metals and Materials(South Korea), 33(10), pp. 1368-1373.
  12. Park, H., K. Han, 1996: Dissolution behavior of nickel in Iodine/Iodide solutions, Journal of the Korean Institute of Metals and Materials(South Korea), 34(5), pp. 615-621.