Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Cempedak Durian (Artocarpus sp.) Peel as a Biosorbent for the Removal of Toxic Methyl Violet 2B from Aqueous Solution

  • Dahri, Muhammad Khairud (Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam) ;
  • Chieng, Hei Ing (Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam) ;
  • Lim, Linda B.L. (Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam) ;
  • Priyantha, Namal (Department of Chemistry, Faculty of Science, University of Peradeniya) ;
  • Mei, Chan Chin (Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam)
  • Received : 2014.12.24
  • Accepted : 2015.02.03
  • Published : 2015.10.01
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Abstract

This paper aims to investigate the potential use of cempedak durian peel (CDP) from Negara Brunei Darussalam, which is low-cost, locally available, eco-friendly and highly efficient to remove methyl violet (MV) dye from aqueous solutions. The time required for equilibrium to be reached is 2.0 h with no adjustment of pH necessary. FTIR analysis was indicative of the involvement of -COOH and C=O functional groups in adsorption process. The Langmuir model provided the best fit with maximum adsorption capacity of $0.606mmol\;g^{-1}$. Thermodynamics data indicate that the adsorption is spontaneous, feasible and endothermic in nature. Best regeneration of CDP's adsorption ability is achieved by base solution, showing about 95% removal efficiency of MV even after 5 cycles, indicating that CDP can be regenerated and reused. This, together with its high adsorption capacity, makes CDP a potential adsorbent for the removal of MV in wastewater.

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