Advances in nano research

  • 제3권2호
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  • Pages.55-66
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  • 2015
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  • 2287-237X(pISSN)
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  • 2287-2388(eISSN)
테크노프레스 (Techno-Press)
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DOI QR코드

DOI QR Code

Ce3+ sensitize RE3+ (RE=Dy, Tb, Eu, Sm) doped LaPO4 nanophosphor with white emission tunability

  • Phaomei, G. (Department of Chemistry, Berhampur University) ;
  • Yaiphaba, N. (Department of Chemistry, D.M. College of Science)
  • 투고 : 2014.05.05
  • 심사 : 2015.06.30
  • 발행 : 2015.06.25
⟨ 이전 논문 다음 논문 ⟩

초록

Crystalline $Ce^{3+}$ co-doped $LaPO_4$:RE ($RE=Dy^{3+}$, $Tb^{3+}$, $Eu^{3+}$, $Sm^{3+}$) and mix doped rare earth ions of $Dy^{3+}$, $Tb^{3+}$ and $Eu^{3+}$ were prepared by the polyol method at $150^{\circ}C$. Strongly enhance luminescence intensity is obtained with the co-doping of $Ce^{3+}$ with $LaPO_4$:$Dy^{3+}$ and $LaPO_4$:$Tb^{3+}$ due to charge transfer (CT) occurring from $Ce^{3+}$ to $Dy^{3+}$ and $Ce^{3+}$ to $Tb^{3+}$, where as there is no significant changes in luminescence intensity of $Ce^{3+}$ co-doped $Eu^{3+}$ and $Sm^{3+}$ doped $LaPO_4$ samples. The luminescence color can be tuned from green to white by varying the excitation wavelength for the mix ions $Ce^{3+}$, $Dy^{3+}$, $Tb^{3+}$ and $Eu^{3+}$ doped with $LaPO_4$.

키워드

참고문헌

  1. Blasse, G. and Grabmaier, B.C. (1994), Luminescent Materials, Springer, Berlin.
  2. Dexter, D.L. (1953), "A theory of sensitized luminescence in solids", J. Chem. Phys., 21, 836. https://doi.org/10.1063/1.1699044
  3. Fang, Y.P., Xu, A.W., Song, R.Q., Zhang, H.X., You, L.P., Yu, J.C. and Liu H.Q. (2003), "Systematic synthesis and chanracterization of single-crystal lanthanide orthophosphate nanowires", J.Am.Chem. Soc., 125, 16025-16034. https://doi.org/10.1021/ja037280d
  4. Ferhi, M., Horchani-Naifer, K. and Ferid, M. (2009), "Combustion synthesis and luminescence properties of $LaPO_4$: Eu (5%)", J. Rare Earths., 27(2), 182-186. https://doi.org/10.1016/S1002-0721(08)60216-1
  5. Gautam, A. and van Veggel F.C.J.M. (2011), "Blue electroluminescence from $Eu^{2+}$-doped GaN @ $SiO_2$ nanostructures tuned to industrial standards", Chem. Mater., 23, 4817-4823. https://doi.org/10.1021/cm202139u
  6. Gallini, S., Jurado, J.R. and Colomer, M.T. (2005), "Combustion synthesis of nanometric powders of $LaPO_4$ and Sr-substituted $LaPO_4$", Chem. Mater., 17, 4154-4161. https://doi.org/10.1021/cm047945q
  7. Goldys, E.M., Tomsia, K.D., Jinjun S., Dosev, D., Kennedy, I.M., Yatsunenko, S. and Godlewski, M. (2003), "Optical characterization of Eu-doped and undoped $Gd_2O_3$ nanoparticles synthesized by the hydrogen flame pyrolysis method", J. Am. Chem. Soc., 128, 14498-14505.
  8. Li, Q. and Yam, V.W.W. (2007), "Redox luminescence switch based on energy transfer in CePO4: $Tb^{3+}$Nanowires", Angewandte Chemie, 119(19), 3556-3559. https://doi.org/10.1002/ange.200604973
  9. Li, C., Hou, Z., Zhang, C., Yang, P., Li, G., Xu, Z., Fan, Y. and Lin, J. (2009), "Controlled synthesis of $Ln^{3+}$ (Ln=Tb, Eu, Dy) and $V^{5+}$ ion-doped $YPO_4$ nano-/microstructures with tunable luminescent colors", Chem. Mater., 21, 4598-4607. https://doi.org/10.1021/cm901658k
  10. Li, F., Wang, M., Mi, C., Yi, K. and Xu, S. (2009), "Polyol-mediated synthesis and luminescence properties of CePO4:Tb3+ nanospindles", J. Alloy. Comp., 486, 137-139.
  11. Lin, Y.S., Cheng, T.C., Tsai C.C., Hsu K.Y., Jheng, D.Y., Lo, C.Y., Yeh P.H.S. and Huang, S.L. (2010), "High-luminance white-light point source using Ce, Sm:YAG double-clad crystal fiber", IEEE Photon. Techn. Lett., 22, 1494-1496. https://doi.org/10.1109/LPT.2010.2064293
  12. Liu, S., Zhao, G., Lin, X., Ying, H., Liu, J., Wang, J. and Han, G. (2008), "White luminescence of Tm-Dy ions co-doped aluminoborosilicate glasses under UV light excitation", J. Solid. State. Chem., 181(10), 2725-2730. https://doi.org/10.1016/j.jssc.2008.06.027
  13. Nakamoto, K. (1986), Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th Edition, Wiley, New York.
  14. Niu, N., Yang, P., He, F., Zhang, X., Gai, S., Li, C. and Lin, J. (2012), "Tunable multicolor and bright white emission on one dimensional $NaLuF_4$:$Yb^{3+}$, $Ln^{3+}$ (Ln=Er, Tm, Ho, Er/Tm, Tm/Ho) microstructures", J. Mater. Chem., 22, 10889-10899. https://doi.org/10.1039/c2jm31256e
  15. Ningthoujam, R.S. (2012), Enhancement of Luminescence by Rare Earth Ions doping in semiconductor host, Eds. Rai, S.B. and Dwivedi, Y., Nova Science Publishers Inc., USA.
  16. Ningthoujam, R.S., Gajbhiye, N.S., Ahmed, A., Umre, S.S. and Sharma, S.J. (2008), "Re-dispersible $Li^+$ and $Eu^{3+}$ Co-Doped nanocrystalline ZnO: luminescence and EPR studies", J. Nanosci. Nanotech., 8(6), 1-4. https://doi.org/10.1166/jnn.2008.N03
  17. Phaomei, G., Ningthoujam, R.S., Singh, W.R., Laoitongbam, R.S., Singh, N.S., Rath, A., Juluri, R.R. and Vatsa, R.K. (2011), "Luminescence switching behaviour through redox recation in $Ce^{3+}$ co-doped $LaPO_4$:Tb nanorods: Re-dispersible and polymer film", Dalton Tran., 40, 11571-11580. https://doi.org/10.1039/c1dt11264c
  18. Riwotzki, K., Meyssamy, H., Kornowski, A. and Haase, M. (2001), "Liquid-phase synthesis of colloids and redispersible powders of strongly luminescing $LaPO_4$: Ce,Tb nanocrystals", Angew. Chem., Int. Ed., 40, 573-576. https://doi.org/10.1002/1521-3773(20010202)40:3<573::AID-ANIE573>3.0.CO;2-0
  19. Silverstein, R.M. and Wester, F.X. (2007), Spectrometric Identification of Organic Com-pounds, Wiley, India.
  20. Sahu, N.K., Ningthoujam, R.S. and Bahadur, D. (2012), "Disappearance and recovery of luminescence in $GdPO_4$:$Eu^{3+}$ nanorods: propose to water/ $OH{\cdot}$ release under near infrared and gamma irradiations", J. Appl. Phys., 112, 014306. https://doi.org/10.1063/1.4731644
  21. Shannon, R.D. (1976), "Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides", Acta Crystallogr. A, 32, 751-767. https://doi.org/10.1107/S0567739476001551
  22. Vetrone, F., Naccache, R., Mahalingam, V., Morgan, C.G. and Capobianco, J.A. (2009), "The activecore/active-shell approach: a strategy to enhance the upconversion luminescence in lanthanide-doped nanoparticles", Adv. Funct. Mater., 19, 2924-2929. https://doi.org/10.1002/adfm.200900234
  23. Wang, F., Xue, X. and Liu, X. (2008,) "Multicolor tuning of (Ln, P)-doped $YVO_4$ nanoparticles by singlewavelegth excitation", Angew. Chem. Int. Ed., 47, 906-909. https://doi.org/10.1002/anie.200704520
  24. Wang, F., Wang, J. and Liu, X. (2010), "Direct evidence of a surface quenching effect on size-dependent luminescence of upconversion nanoparticles", Angew. Chem., Int. Ed., 49, 7456-7460. https://doi.org/10.1002/anie.201003959
  25. William, K. (1975), Organic spectroscopy, 2nd Edition, Macmillan, Hampshire.
  26. Xu, Z., Kang, X., Li, C., Hou, Z., Zhang, C., Yang, D., Li, G. and Lin, J. (2010), "$Ln^{3+}$ (Ln=Eu, Dy, Sm, and Er) ion-doped $YVO_4$ nano/microcrystals with multiform morphologies: Hydrothermal synthesis, growing mechanism, and luminescent properties", Inorg. Chem., 49, 6706-6715. https://doi.org/10.1021/ic100953m
  27. Yaiphaba, N., Ningthoujam, R.S., Vatsa, R.K. and Rajmuhon, N.S. (2010) "Luminescence properties of Re dispersible $Tb^{3+}$-doped $GdPO_4$ nanoparticles prepared by an ethylene glycol route", Eur. J. Inorg. Chem., 18, 2682-2687.
  28. Yu, Y., Liu, Z., Dai, N., Sheng, Y., Luan, H., Peng, J., Jiang, Z., Li, H., Li, J. and Yang, L. (2011), "Ce- Tb- Mn co-doped white light emitting glasses suitable for long-wavelength UV excitation", Opt. Exp., 19, 19473-19479. https://doi.org/10.1364/OE.19.019473
  29. Zheng, H., Gao, D., Fu, Z., Wang, E., Lei, Y., Tuan, Y. and Cui, M. (2011), "Fluorescence enhancement of $Ln^{3+}$ doped nanoparticles", J. Lumin., 131, 423-428. https://doi.org/10.1016/j.jlumin.2010.09.026

피인용 문헌

  1. Silica-modified luminescent LaPO4 :Eu@LaPO4 @SiO2 core/shell nanorods: Synthesis, structural and luminescent properties vol.33, pp.1, 2018, https://doi.org/10.1002/bio.3379
  2. Effect of Ce3+ Co-doping on GdPO4:Tb3+ Nanoparticles: Photoluminescence and Energy Transfer Studies vol.33, pp.4, 2015, https://doi.org/10.14233/ajchem.2021.23106